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1. KR1020030095046 - 2-ALKOXYALKYL-2-ADAMANTYL (METH)ACRYLATE AND PREPARATION METHOD THEREOF

Office
République de Corée
Numéro de la demande 1020020032554
Date de la demande 11.06.2002
Numéro de publication 1020030095046
Date de publication 18.12.2003
Type de publication A
CIB
C07C 69/54
CCHIMIE; MÉTALLURGIE
07CHIMIE ORGANIQUE
CCOMPOSÉS ACYCLIQUES OU CARBOCYCLIQUES
69Esters d'acides carboxyliques; Esters de l'acide carbonique ou de l'acide formique halogéné
52Esters d'acides acycliques carboxyliques non saturés dont le groupe carboxyle estérifié est lié à un atome de carbone acyclique
533Esters d'acides monocarboxyliques avec une seule liaison double carbone-carbone
54Esters d'acide acrylique; Esters d'acide méthacrylique
CPC
C07C 69/54
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
69Esters of carboxylic acids; Esters of carbonic or haloformic acids
52Esters of acyclic unsaturated carboxylic acids having the esterified carboxyl group bound to an acyclic carbon atom
533Monocarboxylic acid esters having only one carbon-to-carbon double bond
54Acrylic acid esters; Methacrylic acid esters
C07C 67/14
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
67Preparation of carboxylic acid esters
14from carboxylic acid halides
C07C2103/74
G03F 7/0397
GPHYSICS
03PHOTOGRAPHY; CINEMATOGRAPHY; ANALOGOUS TECHNIQUES USING WAVES OTHER THAN OPTICAL WAVES; ELECTROGRAPHY; HOLOGRAPHY
FPHOTOMECHANICAL PRODUCTION OF TEXTURED OR PATTERNED SURFACES, e.g. FOR PRINTING, FOR PROCESSING OF SEMICONDUCTOR DEVICES; MATERIALS THEREFOR; ORIGINALS THEREFOR; APPARATUS SPECIALLY ADAPTED THEREFOR;
7Photomechanical, e.g. photolithographic, production of textured or patterned surfaces, e.g. printing surfaces; Materials therefor, e.g. comprising photoresists; Apparatus specially adapted therefor
004Photosensitive materials
039Macromolecular compounds which are photodegradable, e.g. positive electron resists
0392the macromolecular compound being present in a chemically amplified positive photoresist composition
0397the macromolecular compound having an alicyclic moiety in a side chain
Déposants ENF TECHNOLOGY CO., LTD.
주식회사 이엔에프테크놀로지
Inventeurs BAE, EUN HYEONG
배은형
OH, DONG JU
송영배
SONG, YEONG BAE
오동주
Mandataires 위정호
장성구
Titre
(EN) 2-ALKOXYALKYL-2-ADAMANTYL (METH)ACRYLATE AND PREPARATION METHOD THEREOF
(KO) 2-알콕시알킬-2-아다만틸 (메타)아크릴레이트 및 그제조방법
Abrégé
(EN)

PURPOSE: Provided are novel adamantane derivatives represented by the formula 1 and the preparation method thereof. The adamantane derivatives are used as a coating material with excellent optical and mechanical properties, a monomer for producing a photocurable resin, a photosensitive resin, a coating agent for the optical fiber, a monomer for resist resin or intermediates of drugs.

CONSTITUTION: The preparation comprises the steps of: preparing a Grignard reagent by reacting alkoxyalkyl halide with magnesium according to reaction equation 1; reacting the Grignard reagent with adamantane to prepare 2-alkoxyalkyl-2-adamantanol according to reaction equation 2; and reacting the 2-alkoxyalkyl-2-adamantanol with methacryloyl chloride to make the 2-alkoxyalkyl-2-adamantyl (meth)acrylate of formula 1 according to reaction equation 3. In the reaction equations, R1 is hydrogen, C1-C4 alkyl or cycloalkyl; R2 is hydrogen or C1-C4 alkyl; X is Cl or Br; n is an integer of more than 0. In the formula 1, R1 and n are the same as above; R2 is hydrogen or methyl.

© KIPO 2004


(KO) 본 발명은 신규한 아다만탄 유도체 및 그 제조방법에 관한 것으로서, 하기 화학식 1로 표시되는 2-알콕시알킬-2-아다만틸 (메타)아크릴레이트 및 그 제조방법을 제공한다.
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