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1. (WO2018183261) MACRO-RAFT CHAIN TRANSFER AGENTS AS ANIONIC POLYMERIZATION TERMINATORS

Pub. No.:    WO/2018/183261    International Application No.:    PCT/US2018/024472
Publication Date: Fri Oct 05 01:59:59 CEST 2018 International Filing Date: Wed Mar 28 01:59:59 CEST 2018
IPC: C07C 327/36
C07D 207/327
Applicants: IOWA STATE UNIVERSITY RESEARCH FOUNDATION, INC.
Inventors: HERNANDEZ, Nacu
COCHRAN, Eric
WILLIAMS, Ronald, Christopher
FORRESTER, Michael, John
BRADLEY, William
KRAUS, George
Title: MACRO-RAFT CHAIN TRANSFER AGENTS AS ANIONIC POLYMERIZATION TERMINATORS
Abstract:
The present invention relates to a compound of Formula (I): where ℗ R, R1, R2, R3, and Z are as described herein and to a process for preparing a compound of Formula (I). This invention also relates to a process for the synthesis of a polymer which includes providing a monomer composition, providing a compound of Formula (I), and polymerizing monomers within the monomer composition through controlled free radical polymerization with the compound of Formula (I) to form the polymer.