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1. WO1997041122 - PHENANTHROLINES 3-SUBSTITUEES ET 3,8-SUBSTITUEES ET LEUR UTILISATION DANS DES PROCEDES DE TRANSFERT D'ELECTRONS ET D'ENERGIE

Note: Texte fondé sur des processus automatiques de reconnaissance optique de caractères. Seule la version PDF a une valeur juridique

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CLAIMS
We claim

1 A method for making derivatives of phenathrolines comprising reacting a 3,8 brominated phenanthroline with an acetylene to form an acetylene derivative of phenanthroline

2 The method of claim 1 wherein said acetylene is an aromatic acetylene

3 The method of claim 1 further comprising hydrogenatmg said acetylene derivative of
phenanthroline to form an alkene derivative of phenanthroline

4 The method of claim 1 further comprising hydrogenatmg said acetylene derivative of
phenanthroline to form an alkane derivative of phenanthroline

5 The method of claim 1 wherein said 3,8 brominated phenathroline further comprises a
transition metal atom

6 The method of claim 1 wherein said 3,8 brominated phenathroline further comprises a
chelated transition metal atom

7 A compound having the formula comprising



wherein
A and B are selected from carbon or nitrogen such that Y is a bond selected from the group consisting of acetylene, alkene, alkane, azo or imine, and
Z is alkyl, substituted alkyl, aromatic or substituted aromatic group,

8 A compound having the formula comprising

wherein


D is a linker and
Z is alkyl, substituted alkyl, aromatic or substituted aromatic group A compound according to claim 6 which is a polymer having the formula


10 A compound according to claim 7, 8 or 9 further comprising a transition metal ion and at
least one co-ligand

11 A compound according to claim 9 having the formula


12 A compound according to claim 7, 8 or 9 wherein Z comprises the base of a nucleoside

13 A compound according to claim 7, 8 or 9 wherein Z comprises the base of a nucleotide

14 A compound according to claim 7, 8 or 9 wherein Z comprises the phosphoramidite form of the nucleotide

15 A nucleic acid comprising the compounc - ording to claim 7, 8 or 9