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Chemically different cyclic ester oligomers can be copolymerized to form copolyesters whose properties can be tailored by the choice of cyclic ester oligomers used. The copolyesters formed are especially useful as encapsulants and as coatings. In many instances the copolyesters, assuming they are not randomized in later transesterification reactions, have unique microstructures related to the sequencing of repeat units the their polymer chains.