Processing

Please wait...

Settings

Settings

Goto Application

1. WO2022164840 - DIRECT CATALYTIC CONVERSION OF ALCOHOLS TO OLEFINS OF HIGHER CARBON NUMBER WITH REDUCED ETHYLENE PRODUCTION

Publication Number WO/2022/164840
Publication Date 04.08.2022
International Application No. PCT/US2022/013801
International Filing Date 26.01.2022
IPC
C07C 1/24 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
1Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
20starting from organic compounds containing only oxygen atoms as hetero atoms
24by elimination of water
C07C 253/26 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
253Preparation of carboxylic acid nitriles
24by ammoxidation of hydrocarbons or substituted hydrocarbons
26containing carbon-to-carbon multiple bonds, e.g. unsaturated aldehydes
C07C 319/18 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
319Preparation of thiols, sulfides, hydropolysulfides or polysulfides
14of sulfides
18by addition of thiols to unsaturated compounds
CPC
B01J 21/08
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
08Silica
B01J 23/894
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
70of the iron group metals or copper
89combined with noble metals
8933also combined with metals, or metal oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
894with rare earths or actinides
B01J 29/7615
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29Catalysts comprising molecular sieves
04having base-exchange properties, e.g. crystalline zeolites
06Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
70of types characterised by their specific structure not provided for in groups B01J29/08 - B01J29/65
72containing iron group metals, noble metals or copper
76Iron group metals or copper
7615Zeolite Beta
C07C 1/24
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
1Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
20starting from organic compounds containing only oxygen atoms as heteroatoms
24by elimination of water
C07C 2521/08
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
2521Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
08Silica
C07C 2523/83
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
2523Catalysts comprising metals or metal oxides or hydroxides, not provided for in group C07C2521/00
70of the iron group metals or copper
76combined with metals, oxides or hydroxides provided for in groups C07C2523/02 - C07C2523/36
83with rare earths or actinides
Applicants
  • UT-BATTELLE, LLC [US]/[US]
  • LI, Zhenglong [US]/[US]
  • DAVISON, Brian H. [US]/[US]
  • ZHANG, Junyan [US]/[US]
Inventors
  • LI, Zhenglong
  • DAVISON, Brian H.
  • ZHANG, Junyan
Agents
  • GROLZ, Edward W.
Priority Data
63/141,99627.01.2021US
Publication Language English (en)
Filing Language English (EN)
Designated States
Title
(EN) DIRECT CATALYTIC CONVERSION OF ALCOHOLS TO OLEFINS OF HIGHER CARBON NUMBER WITH REDUCED ETHYLENE PRODUCTION
(FR) CONVERSION CATALYTIQUE DIRECTE D'ALCOOLS EN OLÉFINES DE PLUS GRAND NOMBRE DE CARBONE AVEC UNE PRODUCTION RÉDUITE D'ÉTHYLÈNE
Abstract
(EN) A catalyst composition for converting an alcohol to olefins, the catalyst composition comprising the following components: (a) a support (e.g., particles) comprising silicon and oxygen; (b) at least one of copper and silver residing on and/or incorporated into said support; and (c) at least one lanthanide element residing on and/or incorporated into said support. The catalyst may also further include component (d), which is zinc. Also described herein is a method for converting an alcohol to one or more olefinic compounds (an olefin fraction) by contacting the alcohol with a catalyst at a temperature of at least 100°C and up to 500°C to result in direct conversion of the alcohol to an olefin fraction containing one or more olefinic compounds containing at least three carbon atoms; wherein ethylene and propylene are produced in a minor proportion of the olefin fraction, and butenes and higher olefins are produced in major proportion.
(FR) L'invention concerne une composition de catalyseur servant à convertir un alcool en oléfines, la composition de catalyseur comprenant les constituants suivants : (a) un support (par exemple, des particules) comprenant du silicium et de l'oxygène ; (b) au moins un élément entre le cuivre et l'argent se trouvant sur ledit support et/ou étant incorporé dans ce dernier ; et (c) au moins un élément lanthanide se trouvant sur ledit support et/ou étant incorporé dans ce dernier. Le catalyseur peut également en outre comprendre un constituant (d), qui est le zinc. L'invention concerne également un procédé de conversion d'un alcool en un ou plusieurs composés oléfiniques (une fraction d'oléfine) par une mise en contact de l'alcool avec un catalyseur à une température d'au moins 100 °C et jusqu'à 500 °C pour conduire à une conversion directe de l'alcool en une fraction d'oléfine contenant un ou plusieurs composés oléfiniques contenant au moins trois atomes de carbone ; l'éthylène et le propylène étant produits en une proportion mineure de la fraction d'oléfine, et les butènes et les oléfines supérieures étant produits en une proportion majoritaire.
Latest bibliographic data on file with the International Bureau