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1. WO2022114032 - MULTILAYER STRUCTURE, METHOD FOR SEPARATING SAME, AND RECYCLING METHOD

Publication Number WO/2022/114032
Publication Date 02.06.2022
International Application No. PCT/JP2021/043077
International Filing Date 24.11.2021
IPC
B32B 27/00 2006.1
BPERFORMING OPERATIONS; TRANSPORTING
32LAYERED PRODUCTS
BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
27Layered products essentially comprising synthetic resin
B29B 17/02 2006.1
BPERFORMING OPERATIONS; TRANSPORTING
29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
17Recovery of plastics or other constituents of waste material containing plastics
02Separating plastics from other materials
C08K 5/053 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUSE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5Use of organic ingredients
04Oxygen-containing compounds
05Alcohols; Metal alcoholates
053Polyhydroxylic alcohols
C08K 5/098 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUSE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5Use of organic ingredients
04Oxygen-containing compounds
09Carboxylic acids; Metal salts thereof; Anhydrides thereof
098Metal salts of carboxylic acids
C08L 29/04 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
29Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
02Homopolymers or copolymers of unsaturated alcohols
04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
C08L 101/14 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
101Compositions of unspecified macromolecular compounds
12characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity
14the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels
CPC
B29B 17/02
BPERFORMING OPERATIONS; TRANSPORTING
29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
BPREPARATION OR PRETREATMENT OF THE MATERIAL TO BE SHAPED; MAKING GRANULES OR PREFORMS; RECOVERY OF PLASTICS OR OTHER CONSTITUENTS OF WASTE MATERIAL CONTAINING PLASTICS
17Recovery of plastics or other constituents of waste material containing plastics;
02Separating plastics from other materials
B32B 27/00
BPERFORMING OPERATIONS; TRANSPORTING
32LAYERED PRODUCTS
BLAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
27Layered products comprising ; a layer of; synthetic resin
C08K 5/053
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUse of inorganic or non-macromolecular organic substances as compounding ingredients
5Use of organic ingredients
04Oxygen-containing compounds
05Alcohols; Metal alcoholates
053Polyhydroxylic alcohols
C08K 5/098
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUse of inorganic or non-macromolecular organic substances as compounding ingredients
5Use of organic ingredients
04Oxygen-containing compounds
09Carboxylic acids; Metal salts thereof; Anhydrides thereof
098Metal salts of carboxylic acids
C08L 101/14
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
101Compositions of unspecified macromolecular compounds
12characterised by physical features, e.g. anisotropy, viscosity or electrical conductivity
14the macromolecular compounds being water soluble or water swellable, e.g. aqueous gels
C08L 29/04
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
29Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal or ketal radical; Compositions of hydrolysed polymers of esters of unsaturated alcohols with saturated carboxylic acids; Compositions of derivatives of such polymers
02Homopolymers or copolymers of unsaturated alcohols
04Polyvinyl alcohol; Partially hydrolysed homopolymers or copolymers of esters of unsaturated alcohols with saturated carboxylic acids
Applicants
  • 株式会社クラレ KURARAY CO., LTD. [JP]/[JP]
Inventors
  • 石内 聡史 ISHIUCHI Satoshi
  • 鈴木 真 SUZUKI Makoto
Agents
  • 天野 一規 AMANO Kazunori
Priority Data
2020-19622126.11.2020JP
Publication Language Japanese (ja)
Filing Language Japanese (JA)
Designated States
Title
(EN) MULTILAYER STRUCTURE, METHOD FOR SEPARATING SAME, AND RECYCLING METHOD
(FR) STRUCTURE MULTICOUCHE, PROCÉDÉ DE SÉPARATION D’UNE TELLE STRUCTURE, ET PROCÉDÉ DE RECYCLAGE
(JA) 多層構造体、その分離方法及びリサイクル方法
Abstract
(EN) Provided is a multilayer structure having excellent interlayer adhesiveness at high humidity, excellent barrier layer separation characteristics underwater, and excellent viscosity stability after separation and collection of resin constituting the barrier layer even if the barrier layer has been exposed to water during a separation and collection step. The multilayer structure according to the present invention includes a barrier layer (A), a water-soluble layer (B), and an adhesive layer (C), wherein the adhesive layer (C) is laminated on one or both surfaces of the barrier layer (A) with the water-soluble layer (B) interposed therebetween, the barrier layer (A) has, as a main component, a polyamide or ethylene-vinyl alcohol copolymer (a1), and the water-soluble layer (B) includes 100-2000 ppm of alkali metal ions (b1).
(FR) L'invention concerne une structure multicouche ayant une excellente propriété adhésive intercouche à humidité élevée, d'excellentes caractéristiques de séparation de couche barrière sous l'eau, et une excellente stabilité de viscosité après séparation et récupération de résine constituant la couche barrière même si la couche barrière a été exposée à l'eau pendant une étape de séparation et de récupération. La structure multicouche, selon la présente invention, comprend une couche barrière (A), une couche hydrosoluble (B), et une couche adhésive (C), la couche adhésive (C) étant stratifiée sur une ou les deux surfaces de la couche barrière (A), la couche hydrosoluble (B) interposée entre elles. La couche barrière (A) présente, en tant que constituant principal, un polyamide ou un copolymère d'éthylène-alcool vinylique (a1), et la couche hydrosoluble (B) comprend 100 à 2 000 ppm d'ions de métal alcalin (b1).
(JA) 高湿下での層間の接着性及び水中でのバリア層の分離性に優れ、かつ分離回収工程においてバリア層が水中にさらされた場合も、そのバリア層を構成する樹脂の分離回収後の粘度安定性に優れる多層構造体等を提供する。本発明の多層構造体は、バリア層(A)、水溶性層(B)及び接着層(C)を含む多層構造体であって、バリア層(A)の一方又は両方の面に水溶性層(B)を介して接着層(C)が積層され、バリア層(A)がポリアミド又はエチレン-ビニルアルコール共重合体(a1)を主成分として有し、水溶性層(B)がアルカリ金属イオン(b1)を100ppm以上2000ppm以下含有する、多層構造体である。
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