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1. WO2022068621 - HALOGEN-FREE FLAME-RETARDANT REINFORCED PET COMPOSITE MATERIAL AND PREPARATION METHOD THEREFOR

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Publication Number WO/2022/068621
Publication Date 07.04.2022
International Application No. PCT/CN2021/119219
International Filing Date 18.09.2021
IPC
C08L 67/02 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
67Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
02Polyesters derived from dicarboxylic acids and dihydroxy compounds
C08L 51/06 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
51Compositions of graft polymers in which the grafted component is obtained by reactions only involving carbon-to-carbon unsaturated bonds; Compositions of derivatives of such polymers
06grafted on to homopolymers or copolymers of aliphatic hydrocarbons containing only one carbon-to-carbon double bond
C08L 79/00 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
79Compositions of macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen with or without oxygen, or carbon only, not provided for in groups C08L61/-C08L77/259
C08L 23/06 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
23Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
02not modified by chemical after-treatment
04Homopolymers or copolymers of ethene
06Polyethene
C08K 13/06 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUSE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
13Use of mixtures of ingredients not covered by any single one of main groups C08K3/-C08K11/128
06Pretreated ingredients and ingredients covered by the main groups C08K3/-C08K7/118
C08K 5/3492 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUSE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5Use of organic ingredients
16Nitrogen-containing compounds
34Heterocyclic compounds having nitrogen in the ring
3467having more than two nitrogen atoms in the ring
3477Six-membered rings
3492Triazines
CPC
C08L 2201/02
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
2201Properties
02Flame or fire retardant/resistant
C08L 2201/22
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
2201Properties
22Halogen free composition
C08L 2205/035
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
2205Polymer mixtures characterised by other features
03containing three or more polymers in a blend
035containing four or more polymers in a blend
C08L 67/02
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
67Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain
02Polyesters derived from dicarboxylic acids and dihydroxy compounds
Applicants
  • 黎明职业大学 LIMING VOCATIONAL UNIVERSITY [CN]/[CN]
Inventors
  • 陈婷 CHEN, Ting
  • 张青海 ZHANG, Qinghai
  • 吕明旭 LV, Mingxu
  • 林鸿裕 LIN, Hongyu
  • 汪扬涛 WANG, Yangtao
Agents
  • 泉州市文华专利代理有限公司 QUANZHOU WENHUA PATENT AGENY CO., LTD.
Priority Data
202011061418.530.09.2020CN
Publication Language Chinese (zh)
Filing Language Chinese (ZH)
Designated States
Title
(EN) HALOGEN-FREE FLAME-RETARDANT REINFORCED PET COMPOSITE MATERIAL AND PREPARATION METHOD THEREFOR
(FR) MATÉRIAU COMPOSITE DE PET RENFORCÉ IGNIFUGEANT ET SANS HALOGÈNE ET SON PROCÉDÉ DE PRÉPARATION
(ZH) 一种无卤阻燃增强PET复合材料及其制备方法
Abstract
(EN) A halogen-free flame-retardant reinforced PET composite material, comprising the following raw materials in parts by weight: 70-80 parts of PET, 20-30 parts of a toughening agent, 15-20 parts of a modified halogen-free flame retardant, 3-8 parts of a modified flame-retardant synergist, 5-10 parts of modified carbon fibers, 0.1-0.5 part of an antioxidant, 0.2-1 part of a lubricant, and 0.1-0.5 part of an anti-hydrolysis agent. The modified halogen-free flame retardant is a compound of melamine phosphate and an organic carbon source; the modified flame-retardant synergist is PGMA graft modified montmorillonite; the modified carbon fibers are carbon fibers subjected to an oxidation treatment. Also disclosed is a preparation method for the halogen-free flame-retardant reinforced PET composite material. The preparation method is simple and convenient and is easy to implement.
(FR) Matériau composite de PET renforcé ignifugeant et sans halogène, comprenant les matières premières suivantes, en parties en poids : 70 à 80 parties de PET, 20 à 30 parties d’un agent de trempage, 15 à 20 parties d'un ignifugeant sans halogène modifié, 3 à 8 parties d'un synergiste ignifugeant modifié, 5 à 10 parties de fibres de carbone modifiées, 0,1 à 0,5 partie d'un anti-oxydant, 0,2 à 1 partie d'un lubrifiant et 0,1 à 0,5 partie d'un agent anti-hydrolyse. L'ignifugeant sans halogène modifié est un composé de phosphate de mélamine et d'une source de carbone organique ; le synergiste ignifugeant modifié est de la montmorillonite modifiée par greffage de PGMA ; les fibres de carbone modifiées sont des fibres de carbone soumises à un traitement d'oxydation. Un procédé de préparation d'un matériau composite de PET renforcé ignifugeant sans halogène, est également divulgué. Le procédé de préparation est simple et facile à mettre en œuvre.
(ZH) 一种无卤阻燃增强PET复合材料，包括如下重量份的原料：70～80份PET、20～30份增韧剂、15～20份改性无卤阻燃剂、3～8份改性阻燃协效剂、5～10份改性碳纤维、0.1～0.5份抗氧剂、0.2～1份润滑剂和0.1～0.5份抗水解剂，改性无卤阻燃剂为三聚氰胺磷酸盐与有机碳源的复配物，改性阻燃协效剂为PGMA接枝改性的蒙脱土，改性碳纤维为经过氧化处理的碳纤维。还公开一种无卤阻燃增强PET复合材料的制备方法，制备方法简单方便，易于实现。
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