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1. WO2022005257 - OLEFIN-BASED POLYMER

Publication Number WO/2022/005257
Publication Date 06.01.2022
International Application No. PCT/KR2021/008450
International Filing Date 02.07.2021
IPC
C08F 210/16 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
210Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
C08F 210/08 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
210Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
04Monomers containing three or four carbon atoms
08Butenes
C08F 4/6592 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
4Polymerisation catalysts
42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
44selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides
60together with refractory metals, iron group metals, platinum group metals, manganese, technetium, rhenium, or compounds thereof
62Refractory metals or compounds thereof
64Titanium, zirconium, hafnium, or compounds thereof
659Component covered by group C08F4/6455
6592containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
C08F 2/01 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2Processes of polymerisation
01characterised by special features of the polymerisation apparatus used
C08F 2/04 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2Processes of polymerisation
04Polymerisation in solution
CPC
C08F 2/01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2Processes of polymerisation
01characterised by special features of the polymerisation apparatus used
C08F 2/04
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2Processes of polymerisation
04Polymerisation in solution
C08F 210/08
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
210Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
04Monomers containing three or four carbon atoms
08Butenes
C08F 210/16
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
210Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
16Copolymers of ethene with alpha-alkenes, e.g. EP rubbers
C08F 2500/12
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2500Characteristics or properties of obtained polyolefins; Use thereof
12Melt flow index or melt flow ratio
C08F 4/6592
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
4Polymerisation catalysts
42Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
44selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths or actinides
60together with refractory metals, iron group metals, platinum group metals, manganese, rhenium ; technetium; or compounds thereof
62Refractory metals or compounds thereof
64Titanium, zirconium, hafnium or compounds thereof
659Component covered by group C08F4/64 containing a transition metal-carbon bond
6592containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Applicants
  • 주식회사 엘지화학 LG CHEM, LTD. [KR]/[KR]
Inventors
  • 박인성 PARK, In Sung
  • 우지윤 WOO, Ji Yoon
  • 박상은 PARK, Sang Eun
  • 김기은 KIM, Ki Eun
  • 한상욱 HAN, Sang Wook
Agents
  • 특허법인 태평양 BAE, KIM & LEE IP
Priority Data
10-2020-008213503.07.2020KR
Publication Language Korean (ko)
Filing Language Korean (KO)
Designated States
Title
(EN) OLEFIN-BASED POLYMER
(FR) POLYMÈRE À BASE D'OLÉFINE
(KO) 올레핀계 중합체
Abstract
(EN) The present invention relates to an olefin-based polymer satisfying the requirements of: (1) a melt index (MI, 190 °C and 2.16 kg load conditions) of 1.0-10.0 g/10 min; (2) a density (d) of 0.875-0.895 g/cc; (3) 0.5 J/g≤dH(100)≤3.0 J/g and 1.0 J/g≤dH(90)≤6.0 J/g as measured by a differential scanning calorimetry precision measurement method (SSA); (4) 15≤T(90)-T(50)≤30 and 50 °C≤T(50)≤75 °C as measured by a differential scanning calorimetry precision measurement method (SSA); and (5) the melting point (Tm), as measured using a differential scanning calorimeter (DSC), satisfies 55 °C≤Tm≤80 °C. The olefin-based polymer according to the present invention, which is a low-density olefin-based polymer, exhibits high mechanical rigidity due to the introduction of high-crystalline regions.
(FR) La présente invention se rapporte à un polymère à base d'oléfine satisfaisant les exigences suivantes : (1) un indice de fluidité (MI, conditions de 190 °C et charge de 2,16 kg) compris entre 1,0 et 10,0 g/10 min ; (2) une masse volumique (d) comprise entre 0,875 et 0,895 g/cc ; (3) 0,5 J/g ≤ dH(100) ≤ 3,0 J/g et 1,0 J/g ≤ dH(90) ≤ 6,0 J/g tel que mesuré par un procédé de mesure de précision de calorimétrie différentielle à balayage (SSA) ; (4) 15 ≤ T(90)-T(50) ≤ 30 et 50 °C ≤ T(50) ≤ 75 °C tel que mesuré par un procédé de mesure de précision de calorimétrie différentielle à balayage (SSA) ; et (5) le point de fusion (Tm), tel que mesuré à l'aide d'un calorimètre à balayage différentiel (DSC), satisfait à 55 °C ≤ Tm ≤ 80 °C. Le polymère à base d'oléfine selon la présente invention, qui est un polymère à base d'oléfine de faible densité, présente une rigidité mécanique élevée en raison de l'introduction de régions hautement cristallines.
(KO) 본 발명은 (1) 용융지수(MI, 190 ℃, 2.16 kg 하중 조건): 1.0 내지 10.0g/10분; (2) 밀도(d): 0.875 내지 0.895 g/cc; (3) 시차 주사 열량계 정밀 측정법(SSA) 측정시 0.5 J/g≤dH(100)≤3.0 J/g이고, 1.0 J/g≤dH(90)≤ 6.0 J/g; (4) 시차 주사 열량계 정밀 측정법(SSA) 측정시 15≤T(90)-T(50)≤30이고, 50℃≤T(50)≤75℃; (5) 시차 주사 열량계(DSC)로 측정한 용융점(Tm)이 55℃≤Tm≤80℃인 요건을 만족하는 올레핀계 중합체에 관한 것으로, 본 발명에 따른 올레핀계 중합체는 저밀도 올레핀계 중합체로서 고결정성 영역이 도입되어 높은 기계적 강성을 나타낸다.
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