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1. WO2020222168 - Base Oil Synthesis via Ionic Catalyst Oligomerization and Waterless Separation of the Oligomerization Catalyst

Publication Number WO/2020/222168
Publication Date 05.11.2020
International Application No. PCT/IB2020/054104
International Filing Date 30.04.2020
IPC
C07C 2/22 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
2Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
02by addition between unsaturated hydrocarbons
04by oligomerisation of well-defined unsaturated hydrocarbons without ring formation
06of alkenes, i.e. acyclic hydrocarbons having only one carbon-to-carbon double bond
08Catalytic processes
14with inorganic acids; with salts or anhydrides of acids
20Acids of halogen; Salts thereof
22Metal halides; Complexes thereof with organic compounds
C07C 7/12 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
7Purification, separation or stabilisation of hydrocarbons; Use of additives
12by adsorption, i.e. purification or separation of hydrocarbons with the aid of solids, e.g. with ion-exchangers
C07C 11/02 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
11Acyclic unsaturated hydrocarbons
02Alkenes
C07C 5/13 2006.1
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
5Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
02by hydrogenation
13with simultaneous isomerisation
B01J 31/00 2006.1
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31Catalysts comprising hydrides, coordination complexes or organic compounds
C10M 175/00 2006.1
CCHEMISTRY; METALLURGY
10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
MLUBRICATING COMPOSITIONS; USE OF CHEMICAL SUBSTANCES EITHER ALONE OR AS LUBRICATING INGREDIENTS IN A LUBRICATING COMPOSITION
175Working-up used lubricants to recover useful products
CPC
B01J 20/103
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
02comprising inorganic material
10comprising silica or silicate
103comprising silica
B01J 20/28061
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
28characterised by their form or physical properties
28054characterised by their surface properties or porosity
28057Surface area, e.g. B.E.T specific surface area
28061being in the range 100-500 m2/g
B01J 20/28071
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
28characterised by their form or physical properties
28054characterised by their surface properties or porosity
28069Pore volume, e.g. total pore volume, mesopore volume, micropore volume
28071being less than 0.5 ml/g
B01J 20/28083
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
20Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
28characterised by their form or physical properties
28054characterised by their surface properties or porosity
28078Pore diameter
28083being in the range 2-50 nm, i.e. mesopores
B01J 2231/20
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2231Catalytic reactions performed with catalysts classified in B01J31/00
20Olefin oligomerisation or telomerisation
B01J 2231/52
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2231Catalytic reactions performed with catalysts classified in B01J31/00
50Redistribution or isomerisation reactions of C-C, C=C or C-C triple bonds
52Isomerisation reactions
Applicants
  • CHEVRON U.S.A. INC. [US]/[US]
Inventors
  • LACHEEN, Howard Steven
  • TIMKEN, Hye-Kyung Cho
Agents
  • OWENS, Howard V.
  • FLAHERTY, Terrence M.
  • ANDERSON, Parul P.
  • CLAPP, Marie L.
  • JAQUEZ, Ana C.
  • NORTHCUTT, Christopher N.
  • PATANGIA, Melissa J.
  • PIO, Michael Sungjoon
  • THOMSON, Paige J.
  • VIRASSAMMY, Carlton
  • WARZEL, Mark L.
  • JONES, Josetta I.
  • TURNER, Frank C.
  • LEACH, Nicholas N.
Priority Data
62/841,33101.05.2019US
Publication Language English (en)
Filing Language English (EN)
Designated States
Title
(EN) Base Oil Synthesis via Ionic Catalyst Oligomerization and Waterless Separation of the Oligomerization Catalyst
(FR) SYNTHÈSE D'HUILE DE BASE PAR OLIGOMÉRISATION DE CATALYSEUR IONIQUE ET SÉPARATION SANS EAU DU CATALYSEUR D'OLIGOMÉRISATION
Abstract
(EN) Described herein is a base oil synthesis via ionic catalyst oligomerization further utilizing a hydrophobic process for removing an ionic catalyst from a reaction mixture with a silica gel composition, specifically a reaction mixture comprising an oligomerization reaction to produce PAO utilizing an ionic catalyst wherein the ionic catalyst is removed post reaction.
(FR) L'invention concerne une synthèse d'huile de base par oligomérisation de catalyseur ionique utilisant en outre un procédé hydrophobe pour éliminer un catalyseur ionique d'un mélange réactionnel avec une composition de gel de silice, en particulier un mélange réactionnel comprenant une réaction d'oligomérisation pour produire de la PAO à l'aide d'un catalyseur ionique, le catalyseur ionique étant retiré après réaction.
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