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1. WO2020136919 - COMPOSITION FOR OPTICAL THREE-DIMENSIONAL SHAPING, THREE-DIMENSIONALLY SHAPED ARTICLE, AND METHOD FOR PRODUCING SAME

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Publication Number WO/2020/136919
Publication Date 02.07.2020
International Application No. PCT/JP2019/001720
International Filing Date 21.01.2019
IPC
C08F 290/06 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
290Macromolecular compounds obtained by polymerising monomers on to polymers modified by introduction of aliphatic unsaturated end or side groups
02on to polymers modified by introduction of unsaturated end groups
06Polymers provided for in subclass C08G52
B29C 64/124 2017.01
BPERFORMING OPERATIONS; TRANSPORTING
29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
64Additive manufacturing, i.e. manufacturing of three-dimensional objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
10Processes of additive manufacturing
106using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
124using layers of liquid which are selectively solidified
B29C 64/129 2017.01
BPERFORMING OPERATIONS; TRANSPORTING
29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
64Additive manufacturing, i.e. manufacturing of three-dimensional objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
10Processes of additive manufacturing
106using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
124using layers of liquid which are selectively solidified
129characterised by the energy source therefor, e.g. by global irradiation combined with a mask
C08F 2/50 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2Processes of polymerisation
46Polymerisation initiated by wave energy or particle radiation
48by ultra-violet or visible light
50with sensitising agents
C08F 220/00 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
C08F 220/28 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10Esters
26Esters containing oxygen in addition to the carboxy oxygen
28containing no aromatic rings in the alcohol moiety
CPC
B29C 64/106
BPERFORMING OPERATIONS; TRANSPORTING
29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
64Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
10Processes of additive manufacturing
106using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
B29C 64/124
BPERFORMING OPERATIONS; TRANSPORTING
29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
64Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
10Processes of additive manufacturing
106using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
124using layers of liquid which are selectively solidified
B29C 64/129
BPERFORMING OPERATIONS; TRANSPORTING
29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
64Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
10Processes of additive manufacturing
106using only liquids or viscous materials, e.g. depositing a continuous bead of viscous material
124using layers of liquid which are selectively solidified
129characterised by the energy source therefor, e.g. by global irradiation combined with a mask
B29C 64/264
BPERFORMING OPERATIONS; TRANSPORTING
29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
64Additive manufacturing, i.e. manufacturing of three-dimensional [3D] objects by additive deposition, additive agglomeration or additive layering, e.g. by 3D printing, stereolithography or selective laser sintering
20Apparatus for additive manufacturing; Details thereof or accessories therefor
264Arrangements for irradiation
B33Y 10/00
BPERFORMING OPERATIONS; TRANSPORTING
33ADDITIVE MANUFACTURING TECHNOLOGY
YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
10Processes of additive manufacturing
B33Y 70/00
BPERFORMING OPERATIONS; TRANSPORTING
33ADDITIVE MANUFACTURING TECHNOLOGY
YADDITIVE MANUFACTURING, i.e. MANUFACTURING OF THREE-DIMENSIONAL [3-D] OBJECTS BY ADDITIVE DEPOSITION, ADDITIVE AGGLOMERATION OR ADDITIVE LAYERING, e.g. BY 3-D PRINTING, STEREOLITHOGRAPHY OR SELECTIVE LASER SINTERING
70Materials specially adapted for additive manufacturing
Applicants
  • 岡本化学工業株式会社 OKAMOTO CHEMICAL INDUSTRY CO., LTD. [JP]/[JP]
Inventors
  • 岡本　博明 OKAMOTO, Hiroaki
  • 中塚　雅郎 NAKATSUKA, Masaro
Agents
  • 奥山　尚一 OKUYAMA, Shoichi
  • 松島　鉄男 MATSUSHIMA, Tetsuo
  • 中村　綾子 NAKAMURA, Ayako
  • 森本　聡二 MORIMOTO, Toshiji
Priority Data
2018-24132725.12.2018JP
Publication Language Japanese (JA)
Filing Language Japanese (JA)
Designated States
Title
(EN) COMPOSITION FOR OPTICAL THREE-DIMENSIONAL SHAPING, THREE-DIMENSIONALLY SHAPED ARTICLE, AND METHOD FOR PRODUCING SAME
(FR) COMPOSITION POUR FORMAGE OPTIQUE EN TROIS DIMENSIONS, ARTICLE RÉSULTANT D'UN FORMAGE EN TROIS DIMENSIONS ET SON PROCÉDÉ DE PRODUCTION
(JA) 光学的立体造形用組成物、並びに立体造形物、及びその製造方法
Abstract
(EN)
Provided is a composition for optical three-dimensional shaping which can be optically shaped (photocured) within a shorter period of time and gives a three-dimensionally shaped article having excellent strength (for example, durability against fracture, etc. upon impact or dropping and durability against repeated folding). The composition for optical three-dimensional shaping according to the present invention at least comprises: (A) as radical-polymerizable compounds, (A1) 2-40 mass% of a dioxane (meth)acrylate radical-polymerizable compound, (A2) 5-40 mass% of a bifunctional polyester type urethane (meth)acrylate radical-polymerizable compound, (A3) 5-40 mass% of a bifunctional polyether type urethane (meth)acrylate radical-polymerizable compound, and (A4) 20-87 weight% of a radical-polymerizable compound other than (A1), (A2) and (A3); (B) 0.1-5 mass% of a photopolymerization initiator; and (C) 0.1-5 mass% of a sensitizer.
(FR)
L'invention concerne une composition pour formage optique en trois dimensions, laquelle composition peut faire l'objet d'un formage optique (photodurcie) dans un laps de temps plus court et donne un article résultant d'un formage en trois dimensions présentant une excellente résistance (par exemple, résistance à la casse, etc. suite à un impact ou une chute et résistance en cas de pliage répété). La composition pour formage optique en trois dimensions selon la présente invention comprend au moins : (A) en tant que composés polymérisables par voie radicalaire, (A1) 2 à 40 % en masse d'un composé polymérisable par voie radicalaire à base de (méth)acrylate de dioxane, (A2) 5 à 40 % en masse d'un composé polymérisable par voie radicalaire à base de (méth)acrylate d'uréthane de type polyester bifonctionnel, (A3) 5 à 40 % en masse d'un composé polymérisable par voie radicalaire à base de (méth)acrylate d'uréthane de type polyéther bifonctionnel et (A4) 20 à 87 % en poids d'un composé polymérisable par voie radicalaire autre que (A1), (A2) et (A3) ; (B) 0,1 à 5 % en masse d'un initiateur de photopolymérisation ; et (C) 0,1 à 5 % en masse d'un sensibilisateur.
(JA)
より短時間で光造形（光硬化）が完了し、優れた強度（例えば、衝撃を受けたとき、落下したとき、割れ等の発生を防ぐ強度、繰り返しの折り曲げに耐えられる強度）を有する立体造形物が得られる光学的立体造形用組成物を提供する。本発明の光学的立体造形用組成物は、（Ａ）ラジカル重合性化合物として、（Ａ１）ジオキサン（メタ）アクリレートのラジカル重合性化合物を２～４０質量％と、（Ａ２）２官能ポリエステル系ウレタン（メタ）アクリレートのラジカル重合性化合物を５～４０質量％と、（Ａ３）２官能ポリエーテル系ウレタン（メタ）アクリレートのラジカル重合性化合物を５～４０質量％と、（Ａ４）前記（Ａ１）、前記（Ａ２）及び前記（Ａ３）以外のラジカル重合性化合物を２０～８７重量％と、（Ｂ）光重合開始剤を０．１～５質量％と、（Ｃ）増感剤を０．１～５質量％とを少なくとも含む。
Also published as
JP2020100107
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