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1. WO2020135427 - FLUORINE-CONTAINING CATIONIC POLYMERIZED MONOMER AND SYNTHESIS AND APPLICATION THEREOF

Publication Number WO/2020/135427
Publication Date 02.07.2020
International Application No. PCT/CN2019/127973
International Filing Date 24.12.2019
IPC
C07D 305/06 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
305Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
02not condensed with other rings
04having no double bonds between ring members or between ring members and non-ring members
06with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring atoms
C07D 303/04 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
303Compounds containing three-membered rings having one oxygen atom as the only ring hetero atom
02Compounds containing oxirane rings
04containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
C07D 407/12 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
407Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/183
02containing two hetero rings
12linked by a chain containing hetero atoms as chain links
C08G 65/22 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
65Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
02from cyclic ethers by opening of the heterocyclic ring
04from cyclic ethers only
22Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
CPC
C07D 301/00
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
301Preparation of oxiranes
C07D 303/04
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
303Compounds containing three-membered rings having one oxygen atom as the only ring heteroatom
02Compounds containing oxirane rings
04containing only hydrogen and carbon atoms in addition to the ring oxygen atoms
C07D 303/30
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
303Compounds containing three-membered rings having one oxygen atom as the only ring heteroatom
02Compounds containing oxirane rings
12with hydrocarbon radicals substituted by singly or doubly bound oxygen atoms
18by etherified hydroxyl radicals
28Ethers with hydroxy compounds containing oxirane rings
30Ethers of oxirane-containing polyhydroxy compounds in which all hydroxyl radicals are etherified with oxirane-containing hydroxy compounds
C07D 305/06
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
305Heterocyclic compounds containing four-membered rings having one oxygen atoms as the only ring hetero atoms
02not condensed with other rings
04having no double bonds between ring members or between ring members and non-ring members
06with only hydrogen atoms, hydrocarbon or substituted hydrocarbon radicals, directly attached to the ring atoms
C07D 407/12
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
DHETEROCYCLIC COMPOUNDS
407Heterocyclic compounds containing two or more hetero rings, at least one ring having oxygen atoms as the only ring hetero atoms, not provided for by group C07D405/00
02containing two hetero rings
12linked by a chain containing hetero atoms as chain links
C08G 65/22
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
65Macromolecular compounds obtained by reactions forming an ether link in the main chain of the macromolecule
02from cyclic ethers by opening of the heterocyclic ring
04from cyclic ethers only
22Cyclic ethers having at least one atom other than carbon and hydrogen outside the ring
Applicants
  • 湖北固润科技股份有限公司 HUBEI GURUN TECHNOLOGY CO., LTD [CN]/[CN]
Inventors
  • 邹应全 ZOU, Yingquan
  • 邓宇飞 DENG, Yufei
Agents
  • 北京市中咨律师事务所 ZHONGZI LAW OFFICE
Priority Data
201811593284.425.12.2018CN
Publication Language Chinese (ZH)
Filing Language Chinese (ZH)
Designated States
Title
(EN) FLUORINE-CONTAINING CATIONIC POLYMERIZED MONOMER AND SYNTHESIS AND APPLICATION THEREOF
(FR) MONOMÈRE POLYMÉRISÉ CATIONIQUE CONTENANT DU FLUOR, SYNTHÈSE ET UTILISATION ASSOCIÉES
(ZH) 含氟阳离子聚合单体及其合成和应用
Abstract
(EN)
The present invention relates to a monomer compound represented by formula (I), wherein each variable is as defined in the description. The described monomer is quickly synthesized at a high yield by means of a click chemistry reaction between a thiol and an olefin; in addition, a substantially perfluorinated alkane chain is introduced into an oxacycloalkane monomer by means of a linker containing a glyceryl ether moiety such that the surface hardness of a photocured film obtained by photocuring obtained monomer cations is high, while the surface energy thereof is low, and the hydrophobic and oleophobic properties are excellent, having good resistance to oil stains in particular. The present invention also relates to a preparation method for the described monomer, a polymer obtained by means of the ring-opening polymerization of the described monomer, a photocurable composition containing the described monomer, and a photocured material obtained by means of photocuring the described photocurable composition.
(FR)
La présente invention concerne un composé monomère représenté par la formule (I), dans laquelle chaque variable est tel que défini dans la description. Le monomère selon l'invention est rapidement synthétisé à un rendement élevé au moyen d'une réaction de chimie click entre un thiol et une oléfine ; en outre, une chaîne alcane sensiblement perfluorée est introduite dans un monomère oxacycloalcane au moyen d'un lieur contenant une fraction éther de glycéryle de telle sorte que la dureté de surface d'un film photodurci obtenu par photopolymérisation de cations monomères obtenus est élevée, tandis que son énergie de surface est faible, et les propriétés hydrophobes et oléophobes sont excellentes, ayant une bonne résistance aux taches d'huile en particulier. La présente invention concerne également un procédé de préparation du monomère selon l'invention, un polymère obtenu au moyen de la polymérisation par ouverture de cycle dudit monomère, une composition photodurcissable contenant celui-ci, et un matériau photodurci obtenu au moyen de la photopolymérisation de la composition photodurcissable selon l'invention.
(ZH)
本发明涉及式(I)单体化合物,其中各变量如说明书中所定义。该单体通过硫醇与烯烃之间的点击化学反应以高产率、快速合成,而且将基本上全氟化的烷烃链借助于包含甘油醚结构部分的连接基引入到氧杂环烷烃类单体中,使得由所得单体阳离子光固化得到的光固化薄膜表面硬度高,表面能低,疏水疏油性能优良,尤其是抗油性沾污非常好。本发明还涉及所述单体的制备方法,该单体开环聚合得到的聚合物,包含该单体的可光固化组合物和由该可光固化组合物光固化得到的光固化材料。
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