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1. WO2020132546 - METHODS AND SYSTEMS TO DECARBONIZE NATURAL GAS USING SULFUR TO PRODUCE HYDROGEN AND POLYMERS

Publication Number WO/2020/132546
Publication Date 25.06.2020
International Application No. PCT/US2019/068016
International Filing Date 20.12.2019
IPC
C07C 1/12 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
1Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
02from oxides of carbon
12from carbon dioxide with hydrogen
C07C 2/76 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
2Preparation of hydrocarbons from hydrocarbons containing a smaller number of carbon atoms
76by condensation of hydrocarbons with partial elimination of hydrogen
C10G 1/04 2006.01
CCHEMISTRY; METALLURGY
10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
1Production of liquid hydrocarbon mixtures from oil shale, oil-sand, or non-melting solid carbonaceous or similar materials, e.g. wood, coal
04by extraction
CPC
B01D 2257/108
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
DSEPARATION
2257Components to be removed
10Single element gases other than halogens
108Hydrogen
B01D 2257/30
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
DSEPARATION
2257Components to be removed
30Sulfur compounds
B01D 53/047
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
DSEPARATION
53Separation of gases or vapours; Recovering vapours of volatile solvents from gases; Chemical or biological purification of waste gases, e.g. engine exhaust gases, smoke, fumes, flue gases, aerosols,
02by adsorption, e.g. preparative gas chromatography
04with stationary adsorbents
047Pressure swing adsorption
B01J 2208/00274
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2208Processes carried out in the presence of solid particles; Reactors therefor
00008Controlling the process
00017Controlling the temperature
00106by indirect heat exchange
00265Part of all of the reactants being heated or cooled outside the reactor while recycling
00274involving reactant vapours
B01J 2208/00283
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
2208Processes carried out in the presence of solid particles; Reactors therefor
00008Controlling the process
00017Controlling the temperature
00106by indirect heat exchange
00265Part of all of the reactants being heated or cooled outside the reactor while recycling
00283involving reactant liquids
B01J 8/005
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
8Chemical or physical processes in general, conducted in the presence of fluids and solid particles; Apparatus for such processes
005Separating solid material from the gas/liquid stream
Applicants
  • GAS TECHNOLOGY INSTITUTE [US]/[US]
Inventors
  • STANIS, Ronald
Agents
  • ERICKSON, Kevin, D.
  • SWANSON, Mark, D.
  • KOTTIS, Nick, C.
  • PAULEY, Douglas, H.
  • WILLIS, Kaylee, M.
Priority Data
16/721,38819.12.2019US
62/782,78020.12.2018US
Publication Language English (EN)
Filing Language English (EN)
Designated States
Title
(EN) METHODS AND SYSTEMS TO DECARBONIZE NATURAL GAS USING SULFUR TO PRODUCE HYDROGEN AND POLYMERS
(FR) PROCÉDÉS ET SYSTÈMES DE DÉCARBONISATION DU GAZ NATUREL À L'AIDE DE SOUFRE POUR PRODUIRE DE L'HYDROGÈNE ET DES POLYMÈRES
Abstract
(EN)
Methods and systems to decarbonize natural gas using sulfur to produce hydrogen and polymers are provided. Sulfur can be introduced in elemental form or as hydrogen sulfide, as may be desired. Decarbonization of natural gas involves introducing natural gas and H2S to a first reactor to produce first reactor products including CS2 and H2. The CS2 can subsequently be polymerized and the H2 recovered in a purified form with little or no carbon emissions.
(FR)
L'invention concerne des procédés et des systèmes de décarbonisation du gaz naturel à l'aide de soufre pour produire de l'hydrogène et des polymères. Le soufre peut être introduit sous forme élémentaire ou en tant que sulfure d'hydrogène, comme souhaité. La décarbonisation du gaz naturel implique l'introduction de gaz naturel et de H2S dans un premier réacteur pour produire des premiers produits de réacteur comprenant CS2 et H2. Le CS2 peut être ensuite polymérisé et le H2 peut être récupéré sous une forme purifiée avec peu ou pas d'émissions de carbone.
Also published as
Latest bibliographic data on file with the International Bureau