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1. WO2020117119 - A PROCESS FOR CONVERTING GLYCEROL TO PROPANE

Publication Number WO/2020/117119
Publication Date 11.06.2020
International Application No. PCT/SE2019/051231
International Filing Date 05.12.2019
IPC
C10G 3/00 2006.01
CCHEMISTRY; METALLURGY
10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
3Production of liquid hydrocarbon mixtures from oxygen-containing organic materials, e.g. fatty oils, fatty acids
B01J 35/10 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35Catalysts, in general, characterised by their form or physical properties
02Solids
10characterised by their surface properties or porosity
C10G 45/00 2006.01
CCHEMISTRY; METALLURGY
10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
45Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
C10G 47/00 2006.01
CCHEMISTRY; METALLURGY
10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
47Cracking of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, to obtain lower boiling fractions
C10G 49/00 2006.01
CCHEMISTRY; METALLURGY
10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
49Treatment of hydrocarbon oils, in the presence of hydrogen or hydrogen-generating compounds, not provided for in a single one of groups C10G45/02, C10G45/32, C10G45/44, C10G45/58, or C10G47/287
CPC
B01J 21/04
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
02Boron or aluminium; Oxides or hydroxides thereof
04Alumina
B01J 23/882
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
70of the iron group metals or copper
76combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
84with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
85Chromium, molybdenum or tungsten
88Molybdenum
882and cobalt
B01J 23/883
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
70of the iron group metals or copper
76combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
84with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
85Chromium, molybdenum or tungsten
88Molybdenum
883and nickel
B01J 35/023
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35Catalysts, in general, characterised by their form or physical properties
02Solids
023Catalysts characterised by dimensions, e.g. grain size
B01J 35/1019
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35Catalysts, in general, characterised by their form or physical properties
02Solids
10characterised by their surface properties or porosity
1004Surface area
1019100-500 m2/g
B01J 35/1042
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35Catalysts, in general, characterised by their form or physical properties
02Solids
10characterised by their surface properties or porosity
1033Pore volume
10420.5-1.0 ml/g
Applicants
  • BIOFUEL-SOLUTION I MALMÖ AB [SE]/[SE]
Inventors
  • HULTEBERG, Christian
Agents
  • STRÖM & GULLIKSSON AB
Priority Data
1851509-805.12.2018SE
Publication Language English (EN)
Filing Language English (EN)
Designated States
Title
(EN) A PROCESS FOR CONVERTING GLYCEROL TO PROPANE
(FR) PROCÉDÉ DE CONVERSION DE GLYCÉROL EN PROPANE
Abstract
(EN)
A process for converting glycerol to propane in a petroleum refinery. In the process, glycerol is mixed with a petroleum refinery intermediate stream, such as vacuum gas oil and/or light gas oil, to provide a mixed stream comprising glycerol. The mixed stream comprising glycerol is refined by hydrotreatment in a reactor in the petroleum refinery with hydrogen over a porous catalyst, the hydrotreatment reducing glycerol to propane, to provide a refined, mixed stream having an increased relative content of propane. Subsequently, a fraction comprising propane from is separated from the refined, mixed stream.
(FR)
L'invention concerne un procédé de conversion de glycérol en propane dans une raffinerie de pétrole. Dans le procédé, du glycérol est mélangé avec un courant intermédiaire de raffinerie de pétrole, tel que du gazole sous vide et/ou du gazole léger, pour fournir un courant mixte comprenant du glycérol. Le courant mixte comprenant du glycérol est raffiné par hydrotraitement dans un réacteur dans la raffinerie de pétrole avec de l'hydrogène sur un catalyseur poreux, l'hydrotraitement réduisant le glycérol en propane, pour fournir un courant mixte raffiné ayant une teneur relative accrue en propane. Ensuite, une fraction comprenant du propane est séparée du courant mixte raffiné.
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