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1. WO2020064929 - FISCHER-TROPSCH PROCESS

Publication Number WO/2020/064929
Publication Date 02.04.2020
International Application No. PCT/EP2019/076034
International Filing Date 26.09.2019
IPC
C10G 2/00 2006.01
CCHEMISTRY; METALLURGY
10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
2Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
B01J 23/889 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
70of the iron group metals or copper
76combined with metals, oxides or hydroxides provided for in groups B01J23/02-B01J23/36118
84with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
889Manganese, technetium or rhenium
B01J 23/75 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
70of the iron group metals or copper
74Iron group metals
75Cobalt
B01J 21/06 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
C07C 29/156 2006.01
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
29Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
15by reduction of oxides of carbon exclusively
151with hydrogen or hydrogen-containing gases
153characterised by the catalyst used
156containing iron group metals, platinum group metals, or compounds thereof
CPC
B01J 21/063
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
06Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
063Titanium; Oxides or hydroxides thereof
B01J 23/8892
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
70of the iron group metals or copper
76combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
84with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
889Manganese, technetium or rhenium
8892Manganese
C07C 29/156
CCHEMISTRY; METALLURGY
07ORGANIC CHEMISTRY
CACYCLIC OR CARBOCYCLIC COMPOUNDS
29Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
15by reduction of oxides of carbon exclusively
151with hydrogen or hydrogen-containing gases
153characterised by the catalyst used
156containing iron group metals, platinum group metals or compounds thereof
C10G 2/332
CCHEMISTRY; METALLURGY
10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION
2Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
30from carbon monoxide with hydrogen
32with the use of catalysts
33characterised by the catalyst used
331containing group VIII-metals
332of the iron-group
C10G 2/50
CCHEMISTRY; METALLURGY
10PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
GCRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION
2Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
50from carbon dioxide with hydrogen
Applicants
  • BP P.L.C. [GB]/[GB]
Inventors
  • SUNLEY, John, Glenn
  • PATERSON, Alexander, James
Agents
  • HILL, Simon Stephen
Priority Data
18197717.428.09.2018EP
Publication Language English (EN)
Filing Language English (EN)
Designated States
Title
(EN) FISCHER-TROPSCH PROCESS
(FR) PROCÉDÉ FISCHER-TROPSCH
Abstract
(EN)
A process for the preparation of a composition comprising oxygenates and hydrocarbons by means of a Fischer-Tropsch synthesis reaction, said process comprising contacting a mixture of hydrogen, carbon monoxide, and carbon dioxide gases with a supported Co-Mn Fischer-Tropsch synthesis catalyst, wherein the supported synthesis catalyst comprises at least 2.5 wt% of manganese, on an elemental basis, based on the total weight of the supported synthesis catalyst; the weight ratio of manganese to cobalt, on an elemental basis, is 0.2 or greater; and, wherein carbon dioxide is present in the Fischer-Tropsch synthesis reaction is at least 5 %v/v.
(FR)
L'invention concerne un procédé de préparation d'une composition comprenant des composés oxygénés et des hydrocarbures au moyen d'une réaction de synthèse de Fischer-Tropsch. Ledit procédé comprend la mise en contact d'un mélange d'hydrogène, de monoxyde de carbone et de gaz de dioxyde de carbone avec un catalyseur de synthèse de Fischer-Tropsch supporté à base de Co-Mn, le catalyseur de synthèse supporté comprenant au moins 2,5 % en poids de manganèse, sur une base élémentaire, sur la base du poids total du catalyseur de synthèse supporté. Le rapport pondéral du manganèse au cobalt, sur une base élémentaire, est de 0,2 ou plus; et le dioxyde de carbone présent dans la réaction de synthèse de Fischer-Tropsch est d'au moins 5 %v/v.
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