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1. (WO2019050649) PROCESSES USING MULTIFUNCTIONAL CATALYSTS CONVERTING EPOXIDES AND CO; CATALYSTS
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Pub. No.: WO/2019/050649 International Application No.: PCT/US2018/045832
Publication Date: 14.03.2019 International Filing Date: 08.08.2018
IPC:
B01J 31/20 (2006.01) ,B01J 31/18 (2006.01) ,B01J 31/22 (2006.01) ,B01J 31/26 (2006.01) ,B01J 31/28 (2006.01) ,B01J 31/30 (2006.01) ,B01J 31/32 (2006.01) ,B01J 31/34 (2006.01) ,B01J 31/38 (2006.01) ,B01J 29/14 (2006.01) ,B01J 29/46 (2006.01) ,B01J 23/18 (2006.01) ,B01J 23/26 (2006.01) ,B01J 23/28 (2006.01) ,B01J 23/31 (2006.01) ,B01J 23/843 (2006.01) ,C08F 4/18 (2006.01) ,C08F 4/50 (2006.01) ,C08G 63/82 (2006.01) ,C08F 20/44 (2006.01) ,C07C 51/08 (2006.01) ,C07C 51/083 (2006.01) ,C07D 305/12 (2006.01) ,C08F 120/44 (2006.01) ,C07D 307/60 (2006.01) ,C07C 57/04 (2006.01) ,C08G 63/08 (2006.01) ,C07C 51/09 (2006.01)
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31
Catalysts comprising hydrides, coordination complexes or organic compounds
16
containing coordination complexes
20
Carbonyls
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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Catalysts comprising hydrides, coordination complexes or organic compounds
16
containing coordination complexes
18
containing nitrogen, phosphorus, arsenic or antimony
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31
Catalysts comprising hydrides, coordination complexes or organic compounds
16
containing coordination complexes
22
Organic complexes
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31
Catalysts comprising hydrides, coordination complexes or organic compounds
26
containing in addition, inorganic metal compounds not provided for in groups B01J31/02-B01J31/24129
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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Catalysts comprising hydrides, coordination complexes or organic compounds
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containing in addition, inorganic metal compounds not provided for in groups B01J31/02-B01J31/24129
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of the platinum group metals, iron group metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31
Catalysts comprising hydrides, coordination complexes or organic compounds
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containing in addition, inorganic metal compounds not provided for in groups B01J31/02-B01J31/24129
28
of the platinum group metals, iron group metals or copper
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Halides
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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Catalysts comprising hydrides, coordination complexes or organic compounds
26
containing in addition, inorganic metal compounds not provided for in groups B01J31/02-B01J31/24129
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of manganese, technetium or rhenium
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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Catalysts comprising hydrides, coordination complexes or organic compounds
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containing in addition, inorganic metal compounds not provided for in groups B01J31/02-B01J31/24129
34
of chromium, molybdenum or tungsten
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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Catalysts comprising hydrides, coordination complexes or organic compounds
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containing in addition, inorganic metal compounds not provided for in groups B01J31/02-B01J31/24129
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of titanium, zirconium or hafnium
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
08
of the faujasite type, e.g. type X or Y
10
containing iron group metals, noble metals or copper
14
Iron group metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
40
of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
42
containing iron group metals, noble metals or copper
46
Iron group metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
16
of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
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Arsenic, antimony or bismuth
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
16
of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
24
Chromium, molybdenum or tungsten
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Chromium
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
16
of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
24
Chromium, molybdenum or tungsten
28
Molybdenum
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
16
of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
24
Chromium, molybdenum or tungsten
31
combined with bismuth
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
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Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
70
of the iron group metals or copper
76
combined with metals, oxides or hydroxides provided for in groups B01J23/02-B01J23/36118
84
with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
843
Arsenic, antimony or bismuth
C CHEMISTRY; METALLURGY
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ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
4
Polymerisation catalysts
06
Metallic compounds other than hydrides and other than metallo-organic compounds; Boron halide or aluminium halide complexes with organic compounds containing oxygen
16
of silicon, germanium, tin, lead, titanium, zirconium or hafnium
18
Oxides
C CHEMISTRY; METALLURGY
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ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
4
Polymerisation catalysts
42
Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
44
selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides
50
selected from alkaline earth metals, zinc, cadmium, mercury, copper, or silver
C CHEMISTRY; METALLURGY
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ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
63
Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
78
Preparation processes
82
characterised by the catalyst used
C CHEMISTRY; METALLURGY
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ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
20
Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
02
Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
42
Nitriles
44
Acrylonitrile
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
51
Preparation of carboxylic acids or their salts, halides, or anhydrides
08
from nitriles
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
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ACYCLIC OR CARBOCYCLIC COMPOUNDS
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Preparation of carboxylic acids or their salts, halides, or anhydrides
083
from carboxylic acid anhydrides
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
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HETEROCYCLIC COMPOUNDS
305
Heterocyclic compounds containing four-membered rings having one oxygen atom as the only ring hetero atoms
02
not condensed with other rings
10
having one or more double bonds between ring members or between ring members and non-ring members
12
Beta-lactones
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
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MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
120
Homopolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
02
Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
42
Nitriles
44
Acrylonitrile
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
D
HETEROCYCLIC COMPOUNDS
307
Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
02
not condensed with other rings
34
having two or three double bonds between ring members or between ring members and non-ring members
56
with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
60
Two oxygen atoms, e.g. succinic anhydride
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
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ACYCLIC OR CARBOCYCLIC COMPOUNDS
57
Unsaturated compounds having carboxyl groups bound to acyclic carbon atoms
02
with only carbon-to-carbon double bonds as unsaturation
03
Monocarboxylic acids
04
Acrylic acid; Methacrylic acid
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
63
Macromolecular compounds obtained by reactions forming a carboxylic ester link in the main chain of the macromolecule
02
Polyesters derived from hydroxy carboxylic acids or from polycarboxylic acids and polyhydroxy compounds
06
derived from hydroxy carboxylic acids
08
Lactones or lactides
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
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ACYCLIC OR CARBOCYCLIC COMPOUNDS
51
Preparation of carboxylic acids or their salts, halides, or anhydrides
09
from carboxylic acid esters or lactones
Applicants:
NOVOMER, INC. [US/US]; 1 Bowdoin Square, Suite 300 Boston, Massachusetts 02114, US
Inventors:
SOOKRAJ, Sadesh; US
Agent:
TOLOMEI, John G.; US
Priority Data:
15/701,41011.09.2017US
Title (EN) PROCESSES USING MULTIFUNCTIONAL CATALYSTS CONVERTING EPOXIDES AND CO; CATALYSTS
(FR) PROCÉDÉS UTILISANT DES ÉPOXYDES DE CONVERSION CATALYSEURS MULTIFONCTIONNELS ET DES COCATALYSEURS
Abstract:
(EN) The present invention is directed to catalysts and processes for catalyzing two or more chemical reactions with a multifunctional catalyst in a reaction vessel. The processes include steps for introducing one or more reagents to a reaction vessel containing a multifunctional catalyst; contacting the one or more reagents with a first portion of the multifunctional catalyst to produce an intermediate; contacting the intermediate with a second portion of the multifunctional catalyst to produce a product; and removing the product from the reaction vessel. In certain embodiments, the multifunctional catalyst may have a first portion with carbonylation functionality for catalyzing the production of a beta-lactone intermediate from an epoxide reagent and a carbon monoxide reagent. In certain embodiments, the multifunctional catalyst may have a second portion with a functionality suitable for polymerization, co-polymerization, and/or modification of a beta-lactone intermediate. In preferred embodiments, the first portion and second portion are bonded to a heterogenous support.
(FR) La présente invention concerne des catalyseurs et des procédés pour catalyser deux réactions chimiques ou plus avec un catalyseur multifonctionnel dans une cuve de réaction. Les procédés comprennent des étapes consistant à introduire un ou plusieurs réactifs dans une cuve de réaction contenant un catalyseur multifonctionnel; à mettre en contact le ou les réactifs avec une première partie du catalyseur multifonctionnel pour créer un intermédiaire; la mise en contact de l'intermédiaire avec une seconde partie du catalyseur multifonctionnel pour créer un produit; et l'élimination du produit de la cuve de réaction. Dans certains modes de réalisation, le catalyseur multifonctionnel peut comporter une première partie avec une fonctionnalité de carbonylation pour catalyser la production d'un intermédiaire de bêta-lactone à partir d'un réactif époxyde et d'un réactif de monoxyde de carbone. Dans certains modes de réalisation, le catalyseur multifonctionnel peut comporter une seconde partie ayant une fonctionnalité appropriée pour la polymérisation, la copolymérisation ou la modification d'un intermédiaire de bêta-lactone. Dans des modes de réalisation privilégiés, la première et la seconde partie sont liées à un support hétérogène.
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)