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1. WO2019050335 - NICKEL-BASED CATALYST, AND SYNTHETIC GAS PRODUCTION SYSTEM EMPLOYING SAME

Publication Number WO/2019/050335
Publication Date 14.03.2019
International Application No. PCT/KR2018/010505
International Filing Date 07.09.2018
IPC
B01J 23/78 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
70of the iron group metals or copper
76combined with metals, oxides or hydroxides provided for in groups B01J23/02-B01J23/36118
78with alkali- or alkaline earth metals or beryllium
B01J 23/755 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
70of the iron group metals or copper
74Iron group metals
755Nickel
B01J 21/10 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
10Magnesium; Oxides or hydroxides thereof
B01J 21/02 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
02Boron or aluminium; Oxides or hydroxides thereof
B01J 35/00 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35Catalysts, in general, characterised by their form or physical properties
B01J 35/10 2006.01
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35Catalysts, in general, characterised by their form or physical properties
02Solids
10characterised by their surface properties or porosity
CPC
B01J 21/02
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
02Boron or aluminium; Oxides or hydroxides thereof
B01J 21/10
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21Catalysts comprising the elements, oxides, or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium, or hafnium
10Magnesium; Oxides or hydroxides thereof
B01J 23/755
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
70of the iron group metals or copper
74Iron group metals
755Nickel
B01J 23/78
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/00
70of the iron group metals or copper
76combined with metals, oxides or hydroxides provided for in groups B01J23/02 - B01J23/36
78with alkali- or alkaline earth metals
B01J 35/00
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35Catalysts, in general, characterised by their form or physical properties
B01J 35/10
BPERFORMING OPERATIONS; TRANSPORTING
01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
JCHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS OR COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35Catalysts, in general, characterised by their form or physical properties
02Solids
10characterised by their surface properties or porosity
Applicants
  • 한국화학연구원 KOREA RESEARCH INSTITUTE OF CHEMICAL TECHNOLOGY [KR]/[KR]
Inventors
  • 김용태 KIM, Yong Tae
  • 전기원 JUN, Ki Won
  • 박해구 PARK, Hae Gu
  • 곽근재 KWAK, Geun Jae
  • 이윤조 LEE, Yun Jo
  • 민지은 MIN, Ji Eun
Agents
  • 특허법인 태웅 TW INTERNATIONAL PATENT AND LAWFIRM
Priority Data
10-2017-011424507.09.2017KR
Publication Language Korean (KO)
Filing Language Korean (KO)
Designated States
Title
(EN) NICKEL-BASED CATALYST, AND SYNTHETIC GAS PRODUCTION SYSTEM EMPLOYING SAME
(FR) CATALYSEUR À BASE DE NICKEL ET SYSTÈME DE PRODUCTION DE GAZ DE SYNTHÈSE L'UTILISANT
(KO) 니켈계 촉매 및 이를 이용한 합성가스 제조 시스템
Abstract
(EN)
The present invention is a synthetic gas production system for turning a natural gas into a synthetic gas, and can provide a synthetic gas production system comprising: a supply part for supplying a natural gas; and a reforming reactor which accommodates a catalyst for producing a synthetic gas, and in which steam reforming of methane and carbon dioxide reforming of methane occur simultaneously, wherein the catalyst is formed to include two or more holes and comprises: a support material comprising at least magnesium (Mg) and aluminum (Al); an activity promoting material comprising at least cerium (Ce); and an active material comprising at least nickel (Ni), wherein the O2 storage amount of a metal, which is the active material exposed on the surface of the catalyst, and of an oxide of the activity promoting material exposed on the surface of the catalyst is 60 to 70 μmol O2/gcat.
(FR)
La présente invention concerne un système de production de gaz de synthèse pour transformer un gaz naturel en gaz de synthèse, et peut fournir un système de production de gaz de synthèse comprenant : une partie d'alimentation pour fournir un gaz naturel; et un réacteur de reformage qui reçoit un catalyseur pour produire un gaz de synthèse, et dans lequel le reformage à la vapeur du méthane et le reformage au dioxyde de carbone du méthane se produisent simultanément, le catalyseur étant formé pour inclure au moins deux trous et comprenant : un matériau de support comprenant au moins du magnésium (Mg) et de l'aluminium (Al); un matériau favorisant l'activité comprenant au moins du cérium (Ce); et un matériau actif comprenant au moins du nickel (Ni), la quantité de stockage d'O2 d'un métal, qui est le matériau actif exposé sur la surface du catalyseur, et d'un oxyde du matériau favorisant l'activité exposé sur la surface du catalyseur étant de 60 à 70 μmol O2/gcat.
(KO)
본 발명은 천연가스를 합성가스로 전환하는 합성가스 제조 시스템으로서, 상기 천연가스를 공급하는 공급부; 및 적어도 마그네슘(Mg) 및 알루미늄(Al)을 포함하는 지지물질, 적어도 세륨(Ce)을 포함하는 활성촉진물질 및 적어도 니켈(Ni)을 포함하는 활성물질을 포함하고, 촉매의 표면에 노출된 활성물질인 금속 및 활성촉진물질의 산화물의 O2 저장량이 60 내지 70 μmol O2/gcat 인 것을 특징으로 하는 적어도 2이상의 홀을 포함하는 형태로 성형된 합성가스 제조용 촉매를 수용하여, 메탄의 수증기 개질반응과 메탄의 이산화탄소 개질반응이 동시에 진행되는 개질반응기;를 포함하는 합성가스 제조 시스템을 제공할 수 있다.
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