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1. WO2019048312 - FLAME RETARDANT COMBINATIONS FOR POLYMER COMPOSITIONS AND USE THEREOF

Publication Number WO/2019/048312
Publication Date 14.03.2019
International Application No. PCT/EP2018/073235
International Filing Date 29.08.2018
Chapter 2 Demand Filed 17.01.2019
IPC
C08K 3/32 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUSE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
3Use of inorganic substances as compounding ingredients
32Phosphorus-containing compounds
C08K 5/3492 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUSE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5Use of organic ingredients
16Nitrogen-containing compounds
34Heterocyclic compounds having nitrogen in the ring
3467having more than two nitrogen atoms in the ring
3477Six-membered rings
3492Triazines
C08K 5/5313 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUSE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5Use of organic ingredients
49Phosphorus-containing compounds
51Phosphorus bound to oxygen
53bound to oxygen and to carbon only
5313Phosphinic compounds, e.g. R2=P(:O)OR'
C08K 5/5317 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUSE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5Use of organic ingredients
49Phosphorus-containing compounds
51Phosphorus bound to oxygen
53bound to oxygen and to carbon only
5317Phosphonic compounds, e.g. R-P(:O)(OR')2
C08K 7/14 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUSE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
7Use of ingredients characterised by shape
02Fibres or whiskers
04inorganic
14Glass
C08L 77/06 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
77Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
06Polyamides derived from polyamines and polycarboxylic acids
CPC
C08K 13/02
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUse of inorganic or non-macromolecular organic substances as compounding ingredients
13Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
02Organic and inorganic ingredients
C08K 13/04
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUse of inorganic or non-macromolecular organic substances as compounding ingredients
13Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
04Ingredients characterised by their shape and organic or inorganic ingredients
C08K 3/32
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUse of inorganic or non-macromolecular organic substances as compounding ingredients
3Use of inorganic substances as compounding ingredients
32Phosphorus-containing compounds
C08K 5/34924
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUse of inorganic or non-macromolecular organic substances as compounding ingredients
5Use of organic ingredients
16Nitrogen-containing compounds
34Heterocyclic compounds having nitrogen in the ring
3467having more than two nitrogen atoms in the ring
3477Six-membered rings
3492Triazines
34924containing cyanurate groups; Tautomers thereof
C08K 5/5313
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUse of inorganic or non-macromolecular organic substances as compounding ingredients
5Use of organic ingredients
49Phosphorus-containing compounds
51Phosphorus bound to oxygen
53bound to oxygen and to carbon only
5313Phosphinic compounds, e.g. R2=P(:O)OR'
C08K 5/5317
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
KUse of inorganic or non-macromolecular organic substances as compounding ingredients
5Use of organic ingredients
49Phosphorus-containing compounds
51Phosphorus bound to oxygen
53bound to oxygen and to carbon only
5317Phosphonic compounds, e.g. R—P(:O)(OR')2
Applicants
  • CLARIANT PLASTICS & COATINGS LTD [CH]/[CH]
Inventors
  • BAUER, Harald
  • HÖROLD, Sebastian
  • SICKEN, Martin
Agents
  • JACOBI, Carola
Priority Data
10 2017 215 779.807.09.2017DE
Publication Language German (DE)
Filing Language German (DE)
Designated States
Title
(DE) FLAMMSCHUTZMITTELKOMBINATIONEN FÜR POLYMERZUSAMMENSETZUNGEN UND DEREN VERWENDUNG
(EN) FLAME RETARDANT COMBINATIONS FOR POLYMER COMPOSITIONS AND USE THEREOF
(FR) COMBINAISONS D’AGENTS IGNIFUGES POUR COMPOSITIONS POLYMÈRES ET LEUR UTILISATION
Abstract
(DE)
Die Erfindung betrifft Flammschutzmittelkombinationen enthaltend - Phosphinsäuresalz der Formel (I) als Komponente A worin R1 und R2 Ethyl bedeuten, M Al, Fe, TiOp oder Zn ist, m 2 bis 3 bedeutet, und p = (4 – m) / 2 ist - Verbindung ausgewählt aus der Gruppe der Al-, Fe-, TiOp- oder Zn-Salze der Ethylbutylphosphinsäure, der Dibutylphosphinsäure, der Ethylhexylphosphinsäure, der Butylhexylphosphinsäure und/oder der Dihexylphosphinsäure als Komponente B - Phosphonsäuresalz der Formel (II) als Komponente C worin R3 Ethyl bedeutet, Met Al, Fe, TiOq oder Zn ist, n 2 bis 3 bedeutet, und q = (4 – n) / 2 ist - Melamincyanurat als Komponente D, wobei das Röntgenpulverdiffraktrogramm der Flammschutzmittelkombinationen folgende Reflexe enthält: im Winkelbereich 2θ von 9,099° bis 9,442°, von 10,802° bis 11,004°, von 11,775 bis 11,990, von 18,619° bis 18,984° und von 26,268° bis 26,679° und/oder im Winkelbereich 2θ von 5,112° bis 5,312°, von 6,097° bis 6,297°, von 10,082° bis 10,282°, von 10,350° bis 10,550°, von 10,802° bis 11,004°, von 11,775° 5 bis 11,990° und von 12,308° bis 12,508° und/oder im Winkelbereich 2θ von 9,117° bis 9,317°, von 10,802° bis 11,004°, von 11,775° bis 11,990° und von 18,537° bis 18,737° und/oder im Winkelbereich 2θ von 8,300° bis 8,500°, von 10,802° bis 11,004° und von 11,775° bis 11,990°. Die Polymerzusammensetzungen lassen sich zur Herstellung von Fasern, Folien und Formkörpern, insbesondere für Anwendungen im Elektro- und Elektronikbereich einsetzen.
(EN)
The invention relates to flame retardant combinations containing - phosphinic acid salt of the formula (I) as component A, wherein R1 and R2 represent ethyl, M represents Al, Fe, TiOp or Zn, m is 2 to 3, and p = (4 - m) /2, a compound selected from the group consisting of Al-, Fe-, TiOp- or Zn salts of ethylbutylphosphinic acid, dibutylphosphinic acid, ethylhexylphosphinic acid, butylhexylphosphinic acid and/or dihexylphosphinic acid as component B, phosphonic acid salt of formula (II) as component C, wherein R3 represents ethyl, Met represents Al, Fe, TiOq or Zn, n is 2 to 3, and q = (4 - n) /2, melamine cyanurate as component D, wherein the x-ray powder diffractogram of the flame retardant combinations contain the following reflections: in the angle range 2θ from 9.099° to 9.442°, from 10.802° to 11.004°, from 11.775 to 11.990, from 18.619° to 18.984° and from 26.268° to 26.679° and/or in the angle range 2θ from 5.112° to 5.312°, from 6.097° to 6.297°, from 10.082° to 10.282°, from 10.350° to 10.550°, from 10.802° to 11.004°, from 11.775° 5 to 11.990° and from 12.308° to 12.508° and/or in the angle range 2θ from 9.117° to 9.317°, from 10.802° to 11.004°, from 11.775° to 11.990° and from 18.537° to 18.737° and/or in the angle range 2θ from 8.300° to 8.500°, from 10.802° to 11.004° and from 11.775° to 11.990°. The polymer compositions can be used to produce fibres, films and moulded bodies, in particular for electrical and electronic applications.
(FR)
L'invention concerne des combinaisons d'agents ignifuges contenant un sel d'acide phosphinique de formule (I) en tant que constituant A, où R1 et R2 sont éthyle, M est Al, Fe, TiOp ou Zn, m vaut de 2 à 3 et p = (4 - m) / 2, un composé choisi dans le groupe des sels d’Al, de Fe, de TiOp ou de Zn de l'acide éthylbutylphosphinique, de l’acide dibutylphosphinique, de l’acide éthylhexylphosphinique, de l’acide butylhexylphosphinique et/ou de l'acide dihexylphosphinique en tant que constituant B, un sel d'acide phosphonique de formule (II) en tant que constituant C, où R3 est éthyle, Met est Al, Fe, TiOq ou Zn, n vaut de 2 à 3 et q = (4 - n) / 2, et du cyanurate de mélamine en tant que constituant D, le diagramme de diffraction X sur poudre de ces combinaisons d'agents ignifuges présentant les réflexions suivantes : dans le domaine angulaire 2θ de 9,099° à 9,442°, de 10,802° à 11,004°, de 11,775 à 11,990, de 18,619° à 18,984° et de 26,268° à 26,679° et/ou dans le domaine angulaire 2θ de 5,112° à 5,312°, de 6,097° à 6,297°, de 10,082° à 10,282°, de 10,350° à 10,550°, de 10,802° à 11,004°, de 11,775° à 11,990° et de 12,308° à 12,508° et/ou dans le domaine angulaire 2θ de 9,117° à 9,317°, de 10,802° à 11,004°, de 11,775° à 11,990° et de 18,537° à 18,737° et/ou dans le domaine angulaire 2θ de 8,300° à 8,500°, de 10,802° à 11,004° et de 11,775° à 11,990°. Les compositions polymères peuvent être employées pour la production de fibres, de films et de corps moulés, notamment pour des applications dans les domaines électrique et électronique.
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