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1. (WO2019044863) CURED PRODUCT, OPTICAL MEMBER, LENS, COMPOUND AND CURABLE COMPOSITION
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Pub. No.: WO/2019/044863 International Application No.: PCT/JP2018/031850
Publication Date: 07.03.2019 International Filing Date: 29.08.2018
IPC:
C08F 20/10 (2006.01) ,C07D 277/82 (2006.01) ,C07D 339/06 (2006.01) ,C07D 409/04 (2006.01) ,C07D 417/04 (2006.01) ,G02B 1/04 (2006.01)
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
20
Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
02
Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10
Esters
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
D
HETEROCYCLIC COMPOUNDS
277
Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
60
condensed with carbocyclic rings or ring systems
62
Benzothiazoles
68
with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
82
Nitrogen atoms
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
D
HETEROCYCLIC COMPOUNDS
339
Heterocyclic compounds containing rings having two sulfur atoms as the only ring hetero atoms
02
Five-membered rings
06
having the hetero atoms in positions 1 and 3, e.g. cyclic dithiocarbonates
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
D
HETEROCYCLIC COMPOUNDS
409
Heterocyclic compounds containing two or more hetero rings, at least one ring having sulfur atoms as the only ring hetero atoms
02
containing two hetero rings
04
directly linked by a ring-member-to-ring- member bond
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
D
HETEROCYCLIC COMPOUNDS
417
Heterocyclic compounds containing two or more hetero rings, at least one ring having nitrogen and sulfur atoms as the only ring hetero atoms, not provided for by group C07D415/196
02
containing two hetero rings
04
directly linked by a ring-member-to-ring- member bond
G PHYSICS
02
OPTICS
B
OPTICAL ELEMENTS, SYSTEMS, OR APPARATUS
1
Optical elements characterised by the material of which they are made; Optical coatings for optical elements
04
made of organic materials, e.g. plastics
Applicants:
富士フイルム株式会社 FUJIFILM CORPORATION [JP/JP]; 東京都港区西麻布2丁目26番30号 26-30, Nishiazabu 2-chome, Minato-ku, Tokyo 1068620, JP
Inventors:
師岡 直之 MOROOKA Naoyuki; JP
白岩 直澄 SHIRAIWA Naozumi; JP
Agent:
特許業務法人特許事務所サイクス SIKS & CO.; 東京都中央区京橋一丁目8番7号 京橋日殖ビル8階 8th Floor, Kyobashi-Nisshoku Bldg., 8-7, Kyobashi 1-chome, Chuo-ku, Tokyo 1040031, JP
Priority Data:
2017-16614930.08.2017JP
2018-10850006.06.2018JP
Title (EN) CURED PRODUCT, OPTICAL MEMBER, LENS, COMPOUND AND CURABLE COMPOSITION
(FR) PRODUIT DURCI, ÉLÉMENT OPTIQUE, LENTILLE, COMPOSÉ ET COMPOSITION DURCISSABLE
(JA) 硬化物、光学部材、レンズ、化合物、及び硬化性組成物
Abstract:
(EN) The present invention provides a cured product which is obtained by curing a curable composition that contains a compound represented by general formula 1, and which has a birefringence ∆n (587 nm) satisfying 0.00 ≤ ∆n (587 nm) ≤ 0.01 and is suitable for the production of an optical member. In general formula 1, Ar represents an aromatic ring group represented by general formula 2-2 or the like; each of L1 and L2 represents a single bond, -O-, -OC(=O)-, -OC(=O)O-, -OC(=O)NH- or the like; each of Sp1 and Sp2 represents a single bond or a divalent linking group; and each of Pol1 and Pol2 represents a hydrogen atom or a polymerizable group, provided that the compound represented by general formula 1 has at least one polymerizable group. In general formula 2-2, each of Z1 and Z2 represents a hydrogen atom, a methyl group or the like; each of A1 and A2 represents -S- or the like; and X represents C(Rz)2 (wherein Rz represents a substituent, and the two Rz moieties may form a ring) or the like.
(FR) La présente invention concerne un produit durci qui est obtenu par durcissement d'une composition durcissable qui contient un composé représenté par la formule générale 1, et qui a une biréfringence ∆n (587 nm) satisfaisant 0,00 ≤ ∆n (587 nm) ≤ 0,01 et est approprié pour la production d'un élément optique. Dans la formule générale 1, Ar représente un groupe cyclique aromatique représenté par la formule générale 2-2 ou similaire ; chacun de L1 et L2 représente une liaison simple ,-O-, -OC(=O)-, -OC(=O)O-, -OC(=O)NH- ou similaire ; chacun de Sp1 et Sp2 représente une liaison simple ou un groupe de liaison divalent ; et chacun de Po1 et Po2 représente un atome d'hydrogène ou un groupe polymérisable, à condition que le composé représenté par la formule générale 1 ait au moins un groupe polymérisable. Dans la formule générale 2-2, chacun de Z1 et Z2 représente un atome d'hydrogène, un groupe méthyle ou similaire ; chacun de A1 et A2 représente -S- ou similaire ; et X représente C(Rz)2 (où Rz représente un substituant, et les deux fractions Rz peuvent former un cycle) ou similaire.
(JA) 本発明により、一般式1で表される化合物を含む硬化性組成物を硬化させた硬化物であって、複屈折Δn(587nm)が0.00≦Δn(587nm)≦0.01である、光学部材の製造に適した硬化物が提供される;式中、Arは一般式2-2等で表される芳香環基であり、 式中、Z及びZは、水素原子又はメチル基等を表し、A及びAは-S-等を表し、XはC(Rz)等(Rzは置換基であり、2つのRzは環を形成していてもよい)を表し、L、Lは単結合、-O-、-OC(=O)-、-OC(=O)O-、-OC(=O)NH-等を表し、Sp、Spは単結合又は2価の連結基を表し、Pol、Polは水素原子又は重合性基を表し、一般式1で表される化合物は、少なくとも一つの重合性基を有する。
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Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Japanese (JA)
Filing Language: Japanese (JA)