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1. (WO2019044814) METHOD FOR PRODUCING PENTAFLUOROSULFANYL AROMATIC COMPOUND
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Pub. No.: WO/2019/044814 International Application No.: PCT/JP2018/031732
Publication Date: 07.03.2019 International Filing Date: 28.08.2018
IPC:
C07C 381/00 (2006.01) ,C07D 213/71 (2006.01) ,C07B 61/00 (2006.01)
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
381
Compounds containing carbon and sulfur and having functional groups not covered by groups C07C301/-C07C337/142
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
D
HETEROCYCLIC COMPOUNDS
213
Heterocyclic compounds containing six-membered rings, not condensed with other rings, with one nitrogen atom as the only ring hetero atom and three or more double bonds between ring members or between ring members and non-ring members
02
having three double bonds between ring members or between ring members and non-ring members
04
having no bond between the ring nitrogen atom and a non-ring member or having only hydrogen or carbon atoms directly attached to the ring nitrogen atom
60
with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached to ring carbon atoms
62
Oxygen or sulfur atoms
70
Sulfur atoms
71
to which a second hetero atom is attached
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
B
GENERAL METHODS OF ORGANIC CHEMISTRY; APPARATUS THEREFOR
61
Other general methods
Applicants:
宇部興産株式会社 UBE INDUSTRIES, LTD. [JP/JP]; 山口県宇部市大字小串1978-96 1978-96, Oaza Kogushi, Ube-shi, Yamaguchi 7558633, JP
国立大学法人 名古屋工業大学 NAGOYA INSTITUTE OF TECHNOLOGY [JP/JP]; 愛知県名古屋市昭和区御器所町字木市29番 29, Aza Kiichi, Gokiso-cho, Showa-ku, Nagoya-shi, Aichi 4660061, JP
Inventors:
柴田 哲男 SHIBATA, Norio; JP
齋藤 記庸 SAITO, Norimichi; JP
Agent:
小野 新次郎 ONO, Shinjiro; JP
山本 修 YAMAMOTO, Osamu; JP
宮前 徹 MIYAMAE, Toru; JP
中西 基晴 NAKANISHI, Motoharu; JP
新井 規之 ARAI, Noriyuki; JP
Priority Data:
2017-16425329.08.2017JP
Title (EN) METHOD FOR PRODUCING PENTAFLUOROSULFANYL AROMATIC COMPOUND
(FR) PROCÉDÉ DE FABRICATION DE COMPOSÉ AROMATIQUE PENTAFLUOROSULFANYLE
(JA) ペンタフルオロスルファニル芳香族化合物の製造方法
Abstract:
(EN) A method for producing a pentafluorosulfanyl aromatic compound represented by general formula (2): Ar-(SF5)k (in the formula, Ar is a substituted or unsubstituted aryl group or a heteroaryl group, k is an integer of 1-3) that includes reacting a halotetrafluorosulfanyl aromatic compound represented by general formula (1): Ar-(SF4Hal)k (in the formula, Ar and k are as defined above, Hal is a Cl group, Br group, or I group) and a fluorine ion-free silver salt.
(FR) L'invention concerne le procédé de fabrication d'un composé aromatique pentafluorosulfanyle représenté par la formule générale (2):Ar-(SF5k (dans la formule, Ar représente un groupe aryle ou un groupe hétéroaryle substitué ou non substitué, et k représente un nombre entier compris entre 1 et 3). Lequel procédé de fabrication inclut une étape au cours de laquelle un sel d'argent exempt d'ions fluor est mis en réaction avec un composé aromatique halotétrafluorosulfanyle représenté par la formule générale. (1):Ar-(SF4Hal)k (dans la formule, Hal représente un groupe Cl, Br ou I, et Ar et k sont tels que définis ci-dessus).
(JA) 一般式(1):Ar-(SF4Hal)k (式中、Arは置換または非置換のアリール基またはヘテロアリール基であり、 HalはCl基、Br基、またはI基であり、 kは1~3の整数であり) で表されるハロテトラフルオロスルファニル芳香族化合物と、 フッ素イオンを含まない銀塩を反応させることを含む、 一般式(2):Ar-(SF5k (式中、Ar、kは前述のとおり定義される) で表されるペンタフルオロスルファニル芳香族化合物の製造方法。
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Japanese (JA)
Filing Language: Japanese (JA)