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1. (WO2019043060) BINAPHTHYL COMPOUNDS
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Pub. No.: WO/2019/043060 International Application No.: PCT/EP2018/073245
Publication Date: 07.03.2019 International Filing Date: 29.08.2018
IPC:
C07C 43/23 (2006.01) ,C08G 64/06 (2006.01) ,G02B 1/04 (2006.01) ,C07C 69/736 (2006.01) ,C07D 333/76 (2006.01) ,C07D 307/91 (2006.01) ,C07C 59/66 (2006.01)
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
43
Ethers; Compounds having groups, groups or groups
02
Ethers
20
having an ether-oxygen atom bound to a carbon atom of a six-membered aromatic ring
23
containing hydroxy or O-metal groups
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
64
Macromolecular compounds obtained by reactions forming a carbonic ester link in the main chain of the macromolecule
04
Aromatic polycarbonates
06
not containing aliphatic unsaturation
G PHYSICS
02
OPTICS
B
OPTICAL ELEMENTS, SYSTEMS, OR APPARATUS
1
Optical elements characterised by the material of which they are made; Optical coatings for optical elements
04
made of organic materials, e.g. plastics
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
69
Esters of carboxylic acids; Esters of carbonic or haloformic acids
66
Esters of carboxylic acids having esterified carboxyl groups bound to acyclic carbon atoms and having any of the groups OH, O-metal, -CHO, keto, ether, acyloxy, groups, groups, or in the acid moiety
73
of unsaturated acids
734
Ethers
736
the hydroxy group of the ester being etherified with a hydroxy compound having the hydroxy group bound to a carbon atom of a six-membered aromatic ring
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
D
HETEROCYCLIC COMPOUNDS
333
Heterocyclic compounds containing five-membered rings having one sulfur atom as the only ring hetero atom
50
condensed with carbocyclic rings or ring systems
76
Dibenzothiophenes
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
D
HETEROCYCLIC COMPOUNDS
307
Heterocyclic compounds containing five-membered rings having one oxygen atom as the only ring hetero atom
77
ortho- or peri-condensed with carbocyclic rings or ring systems
91
Dibenzofurans; Hydrogenated dibenzofurans
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
59
Compounds having carboxyl groups bound to acyclic carbon atoms and containing any of the groups OH, O-metal, -CHO, keto, ether, groups, groups, or groups
40
Unsaturated compounds
58
containing ether groups, groups, groups, or groups
64
containing six-membered aromatic rings
66
the non-carboxylic part of the ether containing six-membered aromatic rings
Applicants:
REUTER CHEMISCHE APPARATEBAU KG [DE/DE]; Engesserstr. 4b 79108 Freiburg, DE
Inventors:
REUTER, Karl; DE
ANDRUSHKO, Vasyl; DE
KANTOR, Mark; DE
STOLZ, Florian; DE
KATO, Noriyuki; JP
KONDO, Mitsuteru; JP
SHIRATAKE, Munenori; JP
ISHIHARA, Kentarou; JP
IKEDA, Shinnya; JP
SUZUKI, Shouko; JP
HIROSE, Kouji; JP
OSHIMA, Kensuke; JP
NAGAYAMA, Shyouya; JP
Agent:
REITSTÖTTER - KINZEBACH; Im Zollhof 1 67061 Ludwigshafen, DE
Priority Data:
17188576.730.08.2017EP
Title (EN) BINAPHTHYL COMPOUNDS
(FR) COMPOSÉS BINAPHTYLE
Abstract:
(EN) The present invention relates to binaphthyl compounds of the formula (I), which are suitable as monomers for preparing polycarbonate resins having beneficial optical properties and which can be used for producing optical lenses: Formula (I) where X is C2-C4-alkandiyl or C1-C4-alkandiyl-C(O)-, where C(O) is bound to the oxygen atom of the hydroxyl group and where C2-C4-alkandiyl or C1-C4-alkandiyl, respectively, are unsubstituted or carry a phenyl ring; R and R' are identical or different and selected from mono or polycyclic aryl having from 6 to 36 carbon atoms and mono- or polycyclic hetaryl having a total of 5 to 36 atoms, which are ring members, where 1, 2, 3 or 4 of these atoms are selected from nitrogen, sulfur and oxygen, while the remainder of these atoms are carbon atoms, where mono- or polycyclic aryl and mono- or polycyclic hetaryl are unsubstituted or carry 1 or 2 radicals Ra, which are selected from the group consisting of CN, CH3, OCH3, O-phenyl, O-naphthyl, S-phenyl, S-naphthyl, CI or F; and, if X is C1-C4-alkandiyl-C(O)-, the esters thereof, in particular the C1-C4-aIkyIesters thereof.
(FR) La présente invention concerne des composés binaphtyle de formule (I), qui sont appropriés en tant que monomères pour préparer des résines de polycarbonate ayant des propriétés optiques avantageuses et qui peuvent être utilisés pour produire des lentilles optiques : formule (I) dans laquelle X représente alcanediyle en C2-C4 ou C1-C4-alcanediyl-C(0)-, C(O) étant lié à l'atome d'oxygène du groupe hydroxyle et l'alcanediyle en C2-C4 ou l'alcandiyle en C1-C4, respectivement, étant non substitués ou portent un cycle phényle; R et R' sont identiques ou différents et sont choisis parmi un aryle mono ou polycyclique ayant de 6 à 36 atomes de carbone et un hétaryle mono ou polycyclique ayant un total de 5 à 36 atomes, qui sont des chaînons de cycle, où 1, 2, 3 ou 4 de ces atomes sont choisis parmi l'azote, le soufre et l'oxygène, tandis que le reste de ces atomes sont des atomes de carbone, un aryle mono ou polycyclique et un hétaryle mono ou polycyclique étant non substitués ou portent 1 ou 2 radicaux Ra, qui sont choisis dans le groupe constitué par CN, CH3, OCH3, O-phényle, O-naphtyle, S-phényle, S-naphtyle, CI ou F; et, si X est C1-C4-alcandiyl-C(O)-, leurs esters, en particulier, leurs alkylesters en C1-C4.
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Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)