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1. (WO2019030250) FLAME-RETARDANT POLYAMIDE COMPOSITIONS AND USE THEREOF
Latest bibliographic data on file with the International BureauSubmit observation

Pub. No.: WO/2019/030250 International Application No.: PCT/EP2018/071443
Publication Date: 14.02.2019 International Filing Date: 08.08.2018
Chapter 2 Demand Filed: 04.03.2019
IPC:
C08K 3/32 (2006.01) ,C08K 5/3492 (2006.01) ,C08K 5/5313 (2006.01) ,C08K 5/5317 (2006.01) ,C08K 7/14 (2006.01) ,C08L 77/06 (2006.01) ,C08L 67/02 (2006.01) ,C08L 77/02 (2006.01) ,C08K 5/134 (2006.01) ,C08K 5/526 (2006.01) ,C08K 5/5393 (2006.01)
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
K
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
3
Use of inorganic ingredients
32
Phosphorus-containing compounds
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
K
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5
Use of organic ingredients
16
Nitrogen-containing compounds
34
Heterocyclic compounds having nitrogen in the ring
3467
having more than two nitrogen atoms in the ring
3477
Six-membered rings
3492
Triazines
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
K
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5
Use of organic ingredients
49
Phosphorus-containing compounds
51
Phosphorus bound to oxygen
53
bound to oxygen and to carbon only
5313
Phosphinic compounds, e.g. R2P(:O)OR'
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
K
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5
Use of organic ingredients
49
Phosphorus-containing compounds
51
Phosphorus bound to oxygen
53
bound to oxygen and to carbon only
5317
Phosphonic compounds, e.g. R-P(:O)(OR')2
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
K
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
7
Use of ingredients characterised by shape
02
Fibres or whiskers
04
inorganic
14
Glass
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
L
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
77
Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
06
Polyamides derived from polyamines and polycarboxylic acids
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
L
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
67
Compositions of polyesters obtained by reactions forming a carboxylic ester link in the main chain; Compositions of derivatives of such polymers
02
Polyesters derived from dicarboxylic acids and dihydroxy compounds
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
L
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
77
Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain; Compositions of derivatives of such polymers
02
Polyamides derived from omega-amino carboxylic acids or from lactams thereof
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
K
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5
Use of organic ingredients
04
Oxygen-containing compounds
13
Phenols; Phenolates
134
Phenols containing ester groups
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
K
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5
Use of organic ingredients
49
Phosphorus-containing compounds
51
Phosphorus bound to oxygen
52
bound to oxygen only
524
Esters of phosphorous acids, e.g. of H3PO3
526
with hydroxyaryl compounds
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
K
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
5
Use of organic ingredients
49
Phosphorus-containing compounds
51
Phosphorus bound to oxygen
53
bound to oxygen and to carbon only
5393
Phosphonous compounds, e.g. R-P(OR')2
Applicants:
CLARIANT PLASTICS & COATINGS LTD [CH/CH]; Rothausstr. 61 4132 Muttenz, CH
Inventors:
BAUER, Harald; DE
HÖROLD, Sebastian; DE
SICKEN, Martin; DE
Agent:
JACOBI, Carola; DE
Priority Data:
10 2017 214 045.311.08.2017DE
Title (DE) FLAMMHEMMENDE POLYAMIDZUSAMMENSETZUNGEN UND DEREN VERWENDUNG
(EN) FLAME-RETARDANT POLYAMIDE COMPOSITIONS AND USE THEREOF
(FR) COMPOSITIONS DE POLYAMIDE IGNIFUGES ET LEUR UTILISATION
Abstract:
(DE) Die Erfindung betrifft flammhemmende Polyamidzusammensetzungen enthaltend - Polyamid mit einem Schmelzpunkt von kleiner gleich 290 °C als Komponente A, - Füllstoffe und/oder Verstärkungsstoffe als Komponente B, - Phosphinsäuresalz der Formel (I) als Komponente C, worin R1 und R2 Ethyl bedeuten, M AI, Fe, TiOp oder Zn ist, m 2 bis 3 bedeutet, und p = (4 - m) / 2 ist - Verbindung ausgewählt aus der Gruppe der AI-, Fe-, TiOp- oder Zn-Salze der Ethylbutylphosphinsäure, der Dibutylphosphinsäure, der Ethylhexylphosphinsäure, der Butylhexylphosphinsäure und/oder der Dihexylphosphinsäure als Komponente D, - Phosphonsäuresalz der Formel (II) als Komponente E, worin R3 Ethyl bedeutet, Met AI, Fe, TiOq oder Zn ist, n 2 bis 3 bedeutet, und q = (4 - n) / 2 ist, - Melaminpolyphosphat mit einem mittleren Kondensationsgrad von 2 bis 100 als Komponente F, - sterisch gehindertes phenolisches Antioxidans als Komponente G, und/oder - organisches Phosphit und/oder organisches Phosphonit als Komponente H. Die Polyamidzusammensetzungen lassen sich zur Herstellung von Fasern, Folien und Formkörpern, insbesondere für Anwendungen im Elektro- und Elektronikbereich einsetzen.
(EN) The invention relates to flame-retardant polyamide compositions containing a polyamide having a melting point of less than or equal to 290 °C as component A, fillers and/or reinforcing materials as component B, phosphinic acid salt of formula (I) as component C, wherein R1 and R2 represent ethyl, M represents Al, Fe, TiOp or Zn, m represents 2 to 3, and p = (4 – m) / 2, a compound selected from the group of Al, Fe, TiOp or Zn salts of ethyl butylphosphinic acid, dibutylphosphinic acid, ethylhexylphosphinic acid, butylhexylphosphinic acid and/or dihexylphosphinic acid as component D, phosphonic acid salt of formula (II) as component E, wherein R3 represents ethyl, Met represents Al, Fe, TiOq or Zn, n represents 2 to 3, and q = (4 – n) / 2, a melamine polyphosphate having an average degree of condensation of between 2 to 100 as component F, a sterically hindered phenolic antioxidant as component G, and/or an organic phosphite and/or organic phosphonite as component H. The polyamide compositions can be used to produce fibers, films, and moulded bodies, in particular for applications in the electrical and electronics fields.
(FR) L'invention concerne des compositions de polyamide ignifuges contenant du polyamide ayant un point de fusion inférieur ou égal à 290 °C en tant que constituant A, des substances de charge et/ou des substances de renfort en tant que constituant B; un sel d'acide phosphinique de formule (I) en tant que constituant C, où R1 et R2 sont éthyle, M est Al, Fe, TiOp ou Zn, m vaut de 2 à 3 et p = (4 - m) / 2; un composé choisi dans le groupe des sels d'Al, de Fe, de TiOp ou de Zn de l'acide éthylbutylphosphinique, de l'acide dibutylphosphinique, de l'acide éthylhexylphosphinique, de l'acide butylhexylphosphinique et/ou de l'acide dihexylphosphinique en tant que constituant D; un sel d'acide phosphonique de formule (II) en tant que constituant E, où R3 est éthyle, Met est Al, Fe, TiOq ou Zn, n vaut de 2 à 3 et q = (4 - n) / 2; un polyphosphate de mélamine ayant un degré de condensation moyen de 2 à 100 en tant que constituant F; un antioxydant phénolique à empêchement stérique en tant que constituant G et/ou un phosphite organique et/ou un phosphonite organique en tant que constituant H. Ces compositions de polyamide peuvent être employées pour la production de fibres, de films et de corps moulés, notamment pour des applications dans le domaine électrique et électronique.
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Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Organization (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: German (DE)
Filing Language: German (DE)