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1. (WO2019027572) BRIDGED BIPHENYL PHENOL TRANSITION METAL COMPLEXES, PRODUCTION, AND USE THEREOF
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Pub. No.: WO/2019/027572 International Application No.: PCT/US2018/036847
Publication Date: 07.02.2019 International Filing Date: 11.06.2018
IPC:
C07F 7/00 (2006.01) ,C08F 210/02 (2006.01) ,C08F 2/38 (2006.01) ,C08F 4/64 (2006.01) ,C08F 4/642 (2006.01) ,C08F 4/659 (2006.01) ,C08F 4/6592 (2006.01)
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
7
Compounds containing elements of the 4th Group of the Periodic System
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
210
Copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond
02
Ethene
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2
Processes of polymerisation
38
Polymerisation using regulators, e.g. chain terminating agents
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
4
Polymerisation catalysts
42
Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
44
selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides
60
together with refractory metals, iron group metals, platinum group metals, manganese, technetium, rhenium, or compounds thereof
62
Refractory metals or compounds thereof
64
Titanium, zirconium, hafnium, or compounds thereof
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
4
Polymerisation catalysts
42
Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
44
selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides
60
together with refractory metals, iron group metals, platinum group metals, manganese, technetium, rhenium, or compounds thereof
62
Refractory metals or compounds thereof
64
Titanium, zirconium, hafnium, or compounds thereof
642
Component covered by group C08F4/6455
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
4
Polymerisation catalysts
42
Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
44
selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides
60
together with refractory metals, iron group metals, platinum group metals, manganese, technetium, rhenium, or compounds thereof
62
Refractory metals or compounds thereof
64
Titanium, zirconium, hafnium, or compounds thereof
659
Component covered by group C08F4/6455
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
4
Polymerisation catalysts
42
Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
44
selected from light metals, zinc, cadmium, mercury, copper, silver, gold, boron, gallium, indium, thallium, rare earths, or actinides
60
together with refractory metals, iron group metals, platinum group metals, manganese, technetium, rhenium, or compounds thereof
62
Refractory metals or compounds thereof
64
Titanium, zirconium, hafnium, or compounds thereof
659
Component covered by group C08F4/6455
6592
containing at least one cyclopentadienyl ring, condensed or not, e.g. an indenyl or a fluorenyl ring
Applicants:
EXXONMOBIL CHEMICAL PATENTS INC. [US/US]; 5200 Bayway Drive Baytown, TX 77520, US
Inventors:
FALER, Catherine A.; US
HARLAN, Charles J.; US
Agent:
BELL, Catherine L.; US
ARECHEDERRA, Leandro; US
CROMWELL, Michael, A.; US
CHEN, Siwen; US
FAULKNER, Kevin, M.; US
Priority Data:
17193036.526.09.2017EP
62/540,45502.08.2017US
Title (EN) BRIDGED BIPHENYL PHENOL TRANSITION METAL COMPLEXES, PRODUCTION, AND USE THEREOF
(FR) COMPLEXES MÉTAL DE TRANSITION-BIPHÉNYL PHÉNOL PONTÉS, PRODUCTION ET UTILISATION ASSOCIÉES
Abstract:
(EN) The present disclosure provides catalysts having a homoallylic bridge (and/or naphthyl moieties) located at a certain position on the catalysts which provides catalyst productivity values of 10,000 gPgcat-1hr-1 or greater and polyolefins, such as polyethylene, having an Mn of 100,000 g/mol or greater, Mw of 500,000 g/mol or greater, and an Mw/Mn value of about 1.5 to about 5. Catalyst systems including the catalysts, polymerization processes using the catalysts, and polymers made using the catalysts are also described.
(FR) La présente invention concerne des catalyseurs ayant un pont homoallylique (et/ou des fractions naphtyle) situés à une certaine position sur les catalyseurs fournissant des valeurs de productivité de catalyseur de 10 000 gPgcat-1hr-1 ou plus et des polyoléfines , tel que le polyéthylène, ayant un Mn de 100 000 g/mol ou plus, Mw de 500 000 g/mol ou plus, et une valeur Mw/Mn d'environ 1,5 à environ 5. L'invention concerne également des systèmes de catalyseur comprenant des catalyseurs, des procédés de polymérisation utilisant les catalyseurs, et des polymères fabriqués à l'aide des catalyseurs.
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Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)