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1. (WO2018204602) METAL ORGANIC FRAMEWORKS, THEIR SYNTHESIS AND USE
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Pub. No.: WO/2018/204602 International Application No.: PCT/US2018/030825
Publication Date: 08.11.2018 International Filing Date: 03.05.2018
IPC:
C07F 9/38 (2006.01) ,C07C 5/22 (2006.01) ,G01N 30/50 (2006.01) ,B01J 20/22 (2006.01)
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
9
Compounds containing elements of the 5th Group of the Periodic System
02
Phosphorus compounds
28
with one or more P-C bonds
38
Phosphonic acids (R-P(:O)(OH)2); Thiophosphonic acids
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
5
Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
22
by isomerisation
G PHYSICS
01
MEASURING; TESTING
N
INVESTIGATING OR ANALYSING MATERIALS BY DETERMINING THEIR CHEMICAL OR PHYSICAL PROPERTIES
30
Investigating or analysing materials by separation into components using adsorption, absorption or similar phenomena or using ion-exchange, e.g. chromatography
02
Column chromatography
50
Conditioning of the sorbent material or stationary liquid
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
20
Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
22
comprising organic material
Applicants:
EXXONMOBIL RESEARCH AND ENGINEERING COMPANY [US/US]; 1545 Route 22 East P.O. Box 900 Annandale, NJ 08801-0900, US
Inventors:
FALKOWSKI, Joseph, M.; US
ABDULKARIM, Mary, S.; US
AFEWORKI, Mobae; US
MEYER, Randall, J.; US
WESTON, Simon, C.; US
Agent:
NEGRON, Liza; US
LEAVITT, Kristina, M.; US
MIGLIORINI, Robert, A.; US
BARRETT, Glenn T.; US
YARNELL, Scott, F.; US
Priority Data:
15/969,18202.05.2018US
62/501,15404.05.2017US
62/610,59027.12.2017US
Title (EN) METAL ORGANIC FRAMEWORKS, THEIR SYNTHESIS AND USE
(FR) STRUCTURES ORGANOMÉTALLIQUES, LEUR SYNTHÈSE ET LEUR UTILISATION
Abstract:
(EN) A novel metal organic framework, EMM-39, is described having the structure of UiO-66 and comprising bisphosphonate linking ligands. EMM-39 has acid activity and is useful as a catalyst in olefin isomerization. Also disclosed is a process of making metal organic frameworks, such as EMM-39, by heterogeneous ligand exchange, in which linking ligands having a first bonding functionality in a host metal organic framework are exchanged with linking ligands having a second different bonding functionality in the framework.
(FR) L'invention concerne une nouvelle structure organométallique, EMM-39, ayant la structure d'UiO-66 et comprenant des ligands de liaison bisphosphonates. EMM-39 présente une activité acide et est utile en tant que catalyseur en isomérisation d'oléfines. L'invention concerne également un procédé de fabrication de structures organométalliques, telles que EMM-39, par échange hétérogène de ligands, dans lequel des ligands de liaison ayant une première fonctionnalité de liaison dans une structure organométallique hôte sont échangés avec des ligands de liaison ayant une seconde fonctionnalité de liaison différente dans la structure.
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Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)