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1. (WO2018189945) CURABLE COMPOSITION, CURED PRODUCT, AND HARDCOAT FILM
Latest bibliographic data on file with the International BureauSubmit observation

Pub. No.: WO/2018/189945 International Application No.: PCT/JP2017/042027
Publication Date: 18.10.2018 International Filing Date: 22.11.2017
IPC:
C08G 59/32 (2006.01) ,B32B 27/00 (2006.01) ,C08G 59/68 (2006.01) ,C08J 7/04 (2006.01) ,C08K 9/06 (2006.01) ,C08L 63/00 (2006.01) ,C09D 163/00 (2006.01)
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
59
Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by reaction of epoxy polycondensates with monofunctional low-molecular-weight compounds; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
18
Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
20
characterised by the epoxy compounds used
32
Epoxy compounds containing three or more epoxy groups
B PERFORMING OPERATIONS; TRANSPORTING
32
LAYERED PRODUCTS
B
LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
27
Layered products essentially comprising synthetic resin
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
59
Polycondensates containing more than one epoxy group per molecule; Macromolecules obtained by reaction of epoxy polycondensates with monofunctional low-molecular-weight compounds; Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
18
Macromolecules obtained by polymerising compounds containing more than one epoxy group per molecule using curing agents or catalysts which react with the epoxy groups
68
characterised by the catalysts used
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
J
WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H142
7
Chemical treatment or coating of shaped articles made of macromolecular substances
04
Coating
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
K
USE OF INORGANIC OR NON-MACROMOLECULAR ORGANIC SUBSTANCES AS COMPOUNDING INGREDIENTS
9
Use of pretreated ingredients
04
Ingredients treated with organic substances
06
with silicon-containing compounds
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
L
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
63
Compositions of epoxy resins; Compositions of derivatives of epoxy resins
C CHEMISTRY; METALLURGY
09
DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
D
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
163
Coating compositions based on epoxy resins; Coating compositions based on derivatives of epoxy resins
Applicants:
株式会社ダイセル DAICEL CORPORATION [JP/JP]; 大阪府大阪市北区大深町3番1号 3-1, Ofuka-cho, Kita-ku, Osaka-shi, Osaka 5300011, JP
Inventors:
菊地慎二 KIKUCHI, Shinji; JP
Agent:
特許業務法人後藤特許事務所 GOTO & CO.; 大阪府大阪市北区紅梅町2番18号 2-18, Kobai-cho, Kita-ku, Osaka-shi, Osaka 5300038, JP
Priority Data:
2017-07916612.04.2017JP
Title (EN) CURABLE COMPOSITION, CURED PRODUCT, AND HARDCOAT FILM
(FR) COMPOSITION DURCISSABLE, PRODUIT DURCI ET COUCHE DE REVÊTEMENT DUR
(JA) 硬化性組成物、硬化物及びハードコートフィルム
Abstract:
(EN) The purpose of the present invention is to provide a curable composition that makes it possible to form a hardcoat layer that has a favorable appearance, e.g., favorable surface smoothness (uniformity of thickness), that has high surface hardness, and that has substantial abrasion resistance and antifouling properties (contamination resistance). The present invention is a curable composition that includes a polyorganosilsesquioxane and a silicon acrylate. The polyorganosilsesquioxane includes structural units represented by formula (1) and has a number average molecular weight of 1,000–3,000 and a molecular weight dispersity of 1.0–3.0, the molar ratio of structural units represented by formula (I) and structural units represented by formula (II) being at least 5, and structural units represented by formula (1) and structural units represented by formula (4) being 55–100 mol% of the total amount of siloxane structural units.
(FR) Le but de la présente invention est de fournir une composition durcissable qui permet de former une couche de revêtement dur qui a un aspect favorable, par exemple un lissé de surface (uniformité d'épaisseur) favorable, qui a une dureté de surface élevée, et qui a une résistance à l'abrasion et des propriétés antisalissure (résistance à la contamination) importantes. La présente invention concerne une composition durcissable qui comprend un polyorganosilsesquioxane et un acrylate de silicium. Le polyorganosilsesquioxane comprend des unités structurales représentées par la formule (1) et a un poids moléculaire moyen en nombre de 1 000 à 3 000 et une dispersité de poids moléculaire de 1,0 à 3,0, le rapport molaire des unités structurales représentées par la formule (I) et des unités structurales représentées par la formule (II) étant d'au moins 5, et les unités structurales représentées par la formule (1) et les unités structurales représentées par la formule (4) constituant de 55 à 100 % en moles de la quantité totale d'unités structurales de siloxane.
(JA) 本発明の目的は、表面の平滑性(厚みの均一性)など外観が良く、表面硬度が高く、十分な耐擦傷性及び防汚性(耐汚染性)を有するハードコート層を形成することができる硬化性組成物を提供することにある。 本発明は、下記ポリオルガノシルセスキオキサンと、シリコンアクリレートとを含む硬化性組成物である。 ポリオルガノシルセスキオキサン:下記式(1)で表される構成単位を有し、下記式(I)で表される構成単位と、下記式(II)で表される構成単位のモル比が5以上であり、シロキサン構成単位の全量に対する、下記式(1)で表される構成単位、及び下記式(4)で表される構成単位の割合が55~100モル%であり、数平均分子量が1000~3000、分子量分散度が1.0~3.0である
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Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Organization (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Japanese (JA)
Filing Language: Japanese (JA)