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1. (WO2018160217) ISOCYANATE-MODIFIED POLYESTER-EPOXIDE POLYMER COMPOSITIONS
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Pub. No.: WO/2018/160217 International Application No.: PCT/US2017/045865
Publication Date: 07.09.2018 International Filing Date: 08.08.2017
IPC:
C08G 18/00 (2006.01) ,C08G 18/42 (2006.01) ,C08G 18/18 (2006.01) ,C09D 175/06 (2006.01) ,C08L 75/06 (2006.01) ,C09J 175/06 (2006.01) ,C08G 18/76 (2006.01)
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18
Polymeric products of isocyanates or isothiocyanates
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18
Polymeric products of isocyanates or isothiocyanates
06
with compounds having active hydrogen
28
characterised by the compounds used containing active hydrogen
40
High-molecular-weight compounds
42
Polycondensates having carboxylic or carbonic ester groups in the main chain
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18
Polymeric products of isocyanates or isothiocyanates
06
with compounds having active hydrogen
08
Processes
16
Catalysts
18
containing secondary or tertiary amines or salts thereof
C CHEMISTRY; METALLURGY
09
DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
D
COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
175
Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
04
Polyurethanes
06
from polyesters
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
L
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
75
Compositions of polyureas or polyurethanes; Compositions of derivatives of such polymers
04
Polyurethanes
06
from polyesters
C CHEMISTRY; METALLURGY
09
DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
J
ADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
175
Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
04
Polyurethanes
06
from polyesters
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18
Polymeric products of isocyanates or isothiocyanates
06
with compounds having active hydrogen
70
characterised by the isocyanates or isothiocyanates used
72
Polyisocyanates or polyisothiocyanates
74
cyclic
76
aromatic
Applicants:
STEPAN COMPANY [US/US]; 22 W. Frontage Road Northfield, IL 60093, US
Inventors:
KAPLAN, Warren, A.; US
WESTFALL, Jennifer, S.; US
Agent:
SCHUCHARDT, Jonathan, L.; US
Priority Data:
62/466,03402.03.2017US
Title (EN) ISOCYANATE-MODIFIED POLYESTER-EPOXIDE POLYMER COMPOSITIONS
(FR) COMPOSITIONS DE POLYMÈRE DE POLYESTER-ÉPOXYDE MODIFIÉ PAR ISOCYANATE
Abstract:
(EN) Isocyanate-modified polyester-epoxide polymer (i-PEEP) compositions are disclosed. The i-PEEP compositions comprise a reaction product of a polyepoxide compound, a polyisocyanate, and a polyester polyol composition. The ratio of epoxy equivalents to hydroxyl equivalents is within the range of 0.2 to 2. The i-PEEP index as defined herein is within the range of 100 to 200. The i-PEEP composition has a Tg within the range of -30°C to 35°C. Low- and elevated-temperature processes catalyzed by bases or Lewis acids for making the i-PEEP compositions are also disclosed. In a simple yet innovative approach, a new class of polymers useful for coatings, elastomers, adhesives, sealants, and other valuable products is assembled from readily available starting materials without reliance on the polyamines typically used to cure epoxy systems.
(FR) L'invention concerne des compositions de polymère de polyester-époxyde modifié par isocyanate (i-PEEP). Les compositions d'i-PEEP comprennent un produit de réaction d'un composé de type polyépoxyde, d'un polyisocyanate et d'une composition de polyester-polyol. Le rapport des équivalents époxy aux équivalents hydroxyle se situe dans la plage de 0,2 à 2. L'indice i-PEEP tel que défini dans la description se situe dans la plage de 100 à 200. La composition d'i-PEEP présente une Tg dans la plage de -30°C à 35°C. Des procédés à basse température et à température élevée catalysés par des bases ou des acides de Lewis pour préparer les compositions d'i-PEEP sont également décrits. Selon une approche simple mais innovante, une nouvelle classe de polymères, utile pour des revêtements, des élastomères, des adhésifs, des agents d'étanchéité et d'autres produits de valeur, est assemblée à partir de matières de départ aisément disponibles, sans avoir à recourir aux polyamines habituellement utilisées pour le durcissement de systèmes époxy.
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)