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1. (WO2018159599) METHOD FOR PRODUCING TRANSITION METAL-ISOCYANIDE COMPLEX

Pub. No.:    WO/2018/159599    International Application No.:    PCT/JP2018/007216
Publication Date: Sat Sep 08 01:59:59 CEST 2018 International Filing Date: Wed Feb 28 00:59:59 CET 2018
IPC: C07F 15/00
C07C 291/10
C07F 15/02
C07F 15/04
C07F 15/06
Applicants: KYUSHU UNIVERSITY, NATIONAL UNIVERSITY CORPORATION
国立大学法人九州大学
SHIN-ETSU CHEMICAL CO., LTD.
信越化学工業株式会社
Inventors: NAGASHIMA Hideo
永島 英夫
SANAGAWA Atsushi
真川 敦嗣
NODA Daisuke
野田 大輔
SAKUTA Koji
作田 晃司
Title: METHOD FOR PRODUCING TRANSITION METAL-ISOCYANIDE COMPLEX
Abstract:
This method is for producing a transition metal complex represented by formula (2), the method comprising reacting a compound containing a transition metal selected from V, Cr, Mo, W, Fe, Ru, Co, Rh, Ni, Pd, and Pt with an isocyanide compound represented by formula (1) in the presence of an alkali metal supported by a solid substance which is insoluble in an organic solvent. This production method can be used to easily and efficiently produce a transition metal complex that includes a predetermined transition metal having an oxidation number of 0 and that has the same or different isocyanide compounds, without using a compound harmful to the human body. (1): (CN)x-R1 {R1 represents a mono- to tri-valent organic group having 1-30 carbon atoms, and x represents an integer of 1-3}. (2): M1a(L)b {M1 represents V, Cr, Mo, W, Fe, Ru, Co, Rh, Ni, Pd, or Pt, and is a zero-valent transition metal, L represents an isocyanide compound represented by formula (1), M1 and L may be the same or different from each other, "a" represents an integer of 1-8, and b represents an integer of 2-12}.