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1. (WO2018159505) DISSIMILAR-METAL SALT ASSEMBLY WHICH IS DENDRIMER HAVING FOUR OR MORE TYPES OF DISSIMILAR-METAL SALT COMPOUNDS PRECISELY INTEGRATED THEREIN, AND PRODUCTION METHOD FOR SUBNANO METAL PARTICLES
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Pub. No.: WO/2018/159505 International Application No.: PCT/JP2018/006789
Publication Date: 07.09.2018 International Filing Date: 23.02.2018
IPC:
C07C 251/24 (2006.01) ,C08G 73/00 (2006.01) ,C07F 1/12 (2006.01) ,C07F 5/00 (2006.01) ,C07F 7/22 (2006.01) ,C07F 9/90 (2006.01) ,C07F 9/94 (2006.01) ,C07F 15/00 (2006.01) ,C07F 15/02 (2006.01)
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
251
Compounds containing nitrogen atoms doubly- bound to a carbon skeleton
02
containing imino groups
24
having carbon atoms of imino groups bound to carbon atoms of six-membered aromatic rings
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
73
Macromolecular compounds obtained by reactions forming in the main chain of the macromolecule a linkage containing nitrogen, with or without oxygen or carbon, not provided for in groups C08G12/-C08G71/238
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
1
Compounds containing elements of the 1st Group of the Periodic System
12
Gold compounds
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
5
Compounds containing elements of the 3rd Group of the Periodic System
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
7
Compounds containing elements of the 4th Group of the Periodic System
22
Tin compounds
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
9
Compounds containing elements of the 5th Group of the Periodic System
90
Antimony compounds
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
9
Compounds containing elements of the 5th Group of the Periodic System
94
Bismuth compounds
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
15
Compounds containing elements of the 8th Group of the Periodic System
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
15
Compounds containing elements of the 8th Group of the Periodic System
02
Iron compounds
Applicants:
国立大学法人東京工業大学 TOKYO INSTITUTE OF TECHNOLOGY [JP/JP]; 東京都目黒区大岡山2丁目12番1号 2-12-1 Ookayama, Meguro-ku, Tokyo 1528550, JP
Inventors:
山元 公寿 YAMAMOTO Kimihisa; JP
塚本 孝政 TSUKAMOTO Takamasa; JP
神戸 徹也 KAMBE Tetsuya; JP
春田 直毅 HARUTA Naoki; JP
今岡 享稔 IMAOKA Takane; JP
Agent:
西澤 利夫 NISHIZAWA Toshio; JP
安藤 拓 ANDO Taku; JP
Priority Data:
2017-03838901.03.2017JP
2017-22898529.11.2017JP
Title (EN) DISSIMILAR-METAL SALT ASSEMBLY WHICH IS DENDRIMER HAVING FOUR OR MORE TYPES OF DISSIMILAR-METAL SALT COMPOUNDS PRECISELY INTEGRATED THEREIN, AND PRODUCTION METHOD FOR SUBNANO METAL PARTICLES
(FR) ENSEMBLE DE SELS MÉTALLIQUES DISSEMBLABLES QUI EST UN DENDRIMÈRE AYANT QUATRE TYPES OU PLUS DE COMPOSÉS DE SELS MÉTALLIQUES DISSEMBLABLES INTÉGRÉS DE MANIÈRE PRÉCISE EN SON SEIN, ET PROCÉDÉ DE PRODUCTION DE PARTICULES MÉTALLIQUES DE TAILLE SOUS-NANOMÉTRIQUE
(JA) 4種以上の異種金属塩化合物を精密集積したデンドリマーの異種金属塩集積体とサブナノ金属粒子の製造方法
Abstract:
(EN) Provided are: a dissimilar-metal salt assembly which is a dendrimer capable of having a large number of, i.e., four or more types, particularly five or more types of dissimilar-metal salt compounds having dissimilar metals precisely integrated therein at respective sites with different environments, such that the total number of metal atoms is smaller than 60; a production method for the dissimilar-metal salt assembly; and a production method for subnano metal particles using the dissimilar-metal salt assembly which is a dendrimer. According to the present invention, four or more types of dissimilar-metal salt compounds having dissimilar metal species are integrated in respective sites with different environments in a dendrimer in which the core is a group represented by formula (I): (in the formula, n-number of X's each independently represent a 6-membered ring aromatic heterocyclic compound having, as a heteroatom, at least one selected from nitrogen, phosphorus, and arsenic, a derivative thereof, or a divalent group which is a residue of a benzene derivative having an electron-donating functional group, Ph represents a phenylene group, and n represents an integer of 1-3).
(FR) La présente invention concerne : un ensemble de sels métalliques dissemblables qui est un dendrimère capable de présenter un grand nombre, soit quatre types ou plus, particulièrement cinq types ou plus de composés de sels métalliques dissemblables ayant des métaux dissemblables intégrés précisément en son sein à des sites respectifs avec différents environnements, de sorte que le nombre total d’atomes de métaux est inférieur à 60 ; un procédé de production de l’ensemble de sels métalliques dissemblables ; et un procédé de production de particules métalliques de taille sous-nanométrique utilisant l’ensemble de sels métalliques dissemblables qui est un dendrimère. Selon la présente invention, quatre types ou plus de composés de sels métalliques dissemblable ayant des espèces métalliques dissemblables sont intégrés dans des sites respectifs avec différents environnements dans un dendrimère dans lequel le noyau est un groupe représenté par la formule (I) : (dans la formule, un nombre n de X représentent chacun indépendamment un composé hétérocyclique aromatique cyclique à 6 chaînons ayant, comme hétéroatome, au moins un constituant sélectionné parmi l’azote, le phosphore, et l’arsenic, son dérivé, ou un groupe divalent qui est un résidu d’un dérivé benzène ayant un groupe fonctionnel donneur d’électrons, Ph représente un groupe phénylène, et n représente un nombre entier d’une valeur de 1 à 3).
(JA) 4種以上、特に5種以上の多数種の異種金属の異種金属塩化合物を、合計の金属原子数が60より少なくなるように、環境の異なる部位ごとに精密集積可能なデンドリマーの異種金属塩集積体とその製造方法、およびこのデンドリマーの異種金属塩集積体を用いたサブナノ金属粒子の製造方法を提供する。 互いに金属種が異なる4種以上の異種金属塩化合物が、次式(I): (式中、n個のXはそれぞれ独立に、ヘテロ原子として窒素、リン、ヒ素から選ばれる少なくとも1種を有する六員環芳香族ヘテロ環化合物およびその誘導体、または電子供与性の官能基を有するベンゼン誘導体の残基である2価の基を示し、Phはフェニレン基を示し、nは1~3の整数を示す。)で表される基をコアとするデンドリマーの環境の異なる部位ごとに集積される。
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Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Japanese (JA)
Filing Language: Japanese (JA)