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1. (WO2018157817) SELECTIVE HYDROGENATION CATALYST, PREPARATION METHOD THEREFOR, AND EVALUATION METHOD FOR CATALYTIC PREPARATION OF 2-METHYLALLYL ALCOHOL
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Pub. No.: WO/2018/157817 International Application No.: PCT/CN2018/077562
Publication Date: 07.09.2018 International Filing Date: 28.02.2018
IPC:
B01J 29/03 (2006.01) ,B01J 23/46 (2006.01) ,B01J 23/652 (2006.01) ,C07C 29/157 (2006.01) ,C07C 29/141 (2006.01)
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
03
not having base-exchange properties
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
38
of noble metals
40
of the platinum group metals
46
Ruthenium, rhodium, osmium or iridium
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
38
of noble metals
54
combined with metals, oxides or hydroxides provided for in groups B01J23/02-B01J23/36118
56
Platinum group metals
64
with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
652
Chromium, molybdenum or tungsten
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
29
Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
15
by reduction of oxides of carbon exclusively
151
with hydrogen or hydrogen-containing gases
153
characterised by the catalyst used
156
containing iron group metals, platinum group metals, or compounds thereof
157
containing platinum group metals or compounds thereof
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
29
Preparation of compounds having hydroxy or O-metal groups bound to a carbon atom not belonging to a six-membered aromatic ring
132
by reduction of an oxygen-containing functional group
136
of CO containing groups, e.g. -COOH
14
of a -CHO group
141
with hydrogen or hydrogen-containing gases
Applicants:
武汉凯迪工程技术研究总院有限公司 WUHAN KAIDI ENGINEERING TECHNOLOGY RESEARCH INSTITUTE CO., LTD. [CN/CN]; 中国湖北省武汉市 江夏区庙山开发区江夏大道特一号 T1 Jiangxia Avenue Miaoshan Development Zone, Jiangxia District Wuhan, Hubei 430212, CN
Inventors:
张然 ZHANG, Ran; CN
王杰华 WANG, Jiehua; CN
冯春峰 FENG, Chunfeng; CN
明卫星 MING, Weixing; CN
杨伟光 YANG, Weiguang; CN
苑颖 YUAN, Ying; CN
Agent:
武汉开元知识产权代理有限公司 WUHAN KAIYUAN INTELLECTUAL PROPERTY AGENT LTD.; 中国湖北省武汉市 江岸区香港路145号远洋大厦14层 14th Floor, Yuanyang Building No. 145, Xianggang Road, Jiang'an District Wuhan, Hubei 430015, CN
Priority Data:
201710117225.901.03.2017CN
Title (EN) SELECTIVE HYDROGENATION CATALYST, PREPARATION METHOD THEREFOR, AND EVALUATION METHOD FOR CATALYTIC PREPARATION OF 2-METHYLALLYL ALCOHOL
(FR) CATALYSEUR D'HYDROGÉNATION SÉLECTIVE, SON PROCÉDÉ DE PRÉPARATION ET PROCÉDÉ D'ÉVALUATION POUR LA PRÉPARATION CATALYTIQUE D'ALCOOL 2-MÉTHYLALLYLE
(ZH) 选择性加氢催化剂、其制备方法及催化制备2-甲基烯丙醇的评价方法
Abstract:
(EN) Provided are a selective hydrogenation catalyst, a preparation method therefor, and an evaluation method for a catalytic preparation of 2-methylallyl alcohol. The selective hydrogenation catalyst consists of two parts, namely, a carrier and an active component, wherein the active component comprises a precious metal material and a non-precious metal material, and the carrier is a mesoporous silicon material, wherein the precious metal material is the precious metal Ir, and the non-precious metal material is any one of the non-precious metals Mo, W, Ni and Co, and the atomic ratio of the non-precious metal material to the precious metal material is 0.1-1. The catalyst can catalytically reduce an unsaturated aldehyde into an unsaturated alcohol under relatively mild reaction conditions and in water.
(FR) Catalyseur d'hydrogénation sélective, son procédé de préparation et procédé d'évaluation pour la préparation catalytique d'alcool 2-méthylallyle. Le catalyseur d'hydrogénation sélective est constitué de deux parties, à savoir un support et un composant actif, selon lesquelles le composant actif comprend un matériau de métal précieux et un matériau métallique non précieux, et le support est un matériau de silicium mésoporeux, où le matériau de métal précieux est le métal précieux Ir, et le matériau de métal non précieux est l'un des métaux non précieux Mo, W, Ni et Co, et le rapport atomique du matériau de métal non précieux sur le matériau de métal précieux est de 0,1-1. Le catalyseur peut réduire catalytiquement un aldéhyde insaturé en un alcool insaturé dans des conditions de réaction relativement modérées et dans de l'eau.
(ZH) 一种选择性加氢催化剂、其制备方法及催化制备2-甲基烯丙醇的评价方法。该选择性加氢催化剂由载体和活性组分两部分组成,其中,活性组分包括贵金属材料和非贵金属材料,载体为介孔硅材料,其中,贵金属材料为贵金属Ir,非贵金属材料为非贵金属Mo、W、Ni、Co中的任意一种,所述非贵金属材料与所述贵金属材料的原子比为0.1~1。该催化剂能在较温和的反应条件及水中将不饱和醛催化还原为不饱和醇。
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Chinese (ZH)
Filing Language: Chinese (ZH)