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1. (WO2018146277) PROCESS FOR PRODUCING A FISCHER-TROPSCH SYNTHESIS CATALYST
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Pub. No.: WO/2018/146277 International Application No.: PCT/EP2018/053350
Publication Date: 16.08.2018 International Filing Date: 09.02.2018
IPC:
C10G 2/00 (2006.01) ,B01J 37/08 (2006.01) ,B01J 37/16 (2006.01) ,B01J 37/18 (2006.01) ,B01J 23/75 (2006.01) ,B01J 23/889 (2006.01) ,B01J 37/00 (2006.01) ,B01J 37/02 (2006.01)
C CHEMISTRY; METALLURGY
10
PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
G
CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
2
Production of liquid hydrocarbon mixtures of undefined composition from oxides of carbon
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
08
Heat treatment
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
16
Reducing
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
16
Reducing
18
with gases containing free hydrogen
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
70
of the iron group metals or copper
74
Iron group metals
75
Cobalt
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
70
of the iron group metals or copper
76
combined with metals, oxides or hydroxides provided for in groups B01J23/02-B01J23/36118
84
with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
889
Manganese, technetium or rhenium
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
02
Impregnation, coating or precipitation
Applicants:
BP P.L.C. [GB/GB]; 1 St James's Square London SW1Y 4PD, GB
Inventors:
OJEDA PINEDA, Manuel; GB
PATERSON, Alexander, James; GB
Agent:
HILL, SIMON STEPHEN ET AL; BP INTERNATIONAL LIMITED BP Legal Technology, Chertsey Road Sunbury on Thames Middlesex TW16 7LN, GB
Priority Data:
1702251.810.02.2017GB
Title (EN) PROCESS FOR PRODUCING A FISCHER-TROPSCH SYNTHESIS CATALYST
(FR) PROCÉDÉ DE PRODUCTION D'UN CATALYSEUR DE SYNTHÈSE DE FISCHER-TROPSCH
Abstract:
(EN) The present invention relates to a process for conveniently preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst having improved activity and selectivity for C5+ hydrocarbons. In one aspect, the present invention provides a process for preparing a supported cobalt-containing Fischer-Tropsch synthesis catalyst, said process comprising the steps of: (a) impregnating a support material with: i) a cobalt-containing compound and ii) acetic acid, or a manganese salt of acetic acid, in a single impregnation step to form an impregnated support material; and (b) drying and calcining the impregnated support material; wherein the support material impregnated in step (a) has not previously been modified with a source of metal other than cobalt; and wherein when the cobalt-containing compound is cobalt hydroxide, a manganese salt of acetic acid is not used in step (a) of the process.
(FR) La présente invention concerne un procédé de préparation commode d'un catalyseur de synthèse de Fischer-Tropsch contenant du cobalt supporté ayant une activité améliorée et une sélectivité pour les hydrocarbures en C5+. Dans un aspect, la présente invention concerne un procédé de préparation d'un catalyseur de synthèse de Fischer-Tropsch contenant du cobalt supporté, ledit procédé comprenant les étapes suivantes : (a) imprégnation d'un matériau de support avec : i) un composé contenant du cobalt et ii) de l'acide acétique, ou un sel de manganèse de l'acide acétique, dans une étape d'imprégnation unique pour former un matériau de support imprégné ; et (b) séchage et calcination du matériau de support imprégné ; le matériau de support imprégné à l'étape (a) n'ayant pas été préalablement modifié avec une source de métal autre que le cobalt ; et aucun sel de manganèse de l'acide acétique n'étant utilisé à l'étape (a) du procédé lorsque le composé contenant du cobalt est l'hydroxyde de cobalt.
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)