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1. (WO2018140987) TITANIUM-ORGANIC FRAMEWORK MATERIAL
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Pub. No.: WO/2018/140987 International Application No.: PCT/VN2018/000002
Publication Date: 02.08.2018 International Filing Date: 24.01.2018
IPC:
C07F 7/28 (2006.01) ,C07C 251/24 (2006.01) ,C08F 2/50 (2006.01) ,C08F 4/76 (2006.01)
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
7
Compounds containing elements of the 4th Group of the Periodic System
28
Titanium compounds
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
251
Compounds containing nitrogen atoms doubly- bound to a carbon skeleton
02
containing imino groups
24
having carbon atoms of imino groups bound to carbon atoms of six-membered aromatic rings
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
2
Processes of polymerisation
46
Polymerisation initiated by wave energy or particle radiation
48
by ultra-violet or visible light
50
with sensitising agents
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
4
Polymerisation catalysts
42
Metals; Metal hydrides; Metallo-organic compounds; Use thereof as catalyst precursors
72
selected from metals not provided for in group C08F4/4475
74
selected from refractory metals
76
selected from titanium, zirconium, hafnium, vanadium, niobium, or tantalum
Applicants:
CENTER FOR INNOVATIVE MATERIALS & ARCHITECTURES [VN/VN]; Quater 6, Linh Trubg Ward, Thu Duc District, Ho Chi Minch City 721337, VN
Inventors:
HA, Lac Nguyen; VN
THANH, Vu Trong; VN
DINH, Quoc Le; VN
TAN, le Hoang Doan; VN
VIET, Quoc Nguyen; VN
NAM, Thanh SOn Phan; VN
Common
Representative:
CENTER FOR INNOVATIVE MATERIALS & ARCHITECTURES; Quater 6, Linh Trubg Ward, Thu Duc District, Ho Chi Minch City 721337, VN
Priority Data:
1-2017-0035125.01.2017VN
Title (EN) TITANIUM-ORGANIC FRAMEWORK MATERIAL
(FR) MATÉRIAU DE STRUCTURE À BASE DE TITANE-ORGANIQUE
Abstract:
(EN) This patent mentioned the synthesis of new metal-organic framework based on hexameric titanium-oxo cluster. The novel material, termed MOF-902, was successfully synthesized and its crystal structure uncovered the 2-Dimensional (2D) layer structure generated by the link of trigonal prism Ti6O6(OMe)(-COO)6 clusters and imine linear linking units. The permanent porosity of MOF-902 is 400 m2 g-1. The band gap energy of this material was found to be 2.5 eV which is suitable to catalyze the polymerization reaction of methacrylate monomers under visible irradiation.
(FR) La présente invention concerne la synthèse d'une nouvelle structure métallo-organique à base de cluster hexamère de titane-oxo. Selon l'invention, le nouveau matériau, appelé MOF-902, a été synthétisé avec succès et sa structure cristalline a découvert la structure de couche bidimensionnelle (2D) générée par la liaison des clusters à prisme trigonal Ti6O6(OMe)(-COO)6 et des unités de liaison linéaires imines. La porosité permanente du MOF-902 de la présente invention est de 400 m2 g-1. L'énergie de bande interdite du matériau de l'invention s'est avérée être de 2,5 eV qui est appropriée pour catalyser la réaction de polymérisation des monomères de méthacrylate sous rayonnement visible.
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)