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1. WO2018132648 - PHYSICAL PROPERTY IMPROVEMENT OF POLYURETHANES

Publication Number WO/2018/132648
Publication Date 19.07.2018
International Application No. PCT/US2018/013471
International Filing Date 12.01.2018
IPC
C08G 18/48 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
40High-molecular-weight compounds
48Polyethers
C08G 18/62 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
40High-molecular-weight compounds
62Polymers of compounds having carbon-to-carbon double bonds
C08G 18/76 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
70characterised by the isocyanates or isothiocyanates used
72Polyisocyanates or polyisothiocyanates
74cyclic
76aromatic
C08G 18/20 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
16Catalysts
18containing secondary or tertiary amines or salts thereof
20Heterocyclic amines; Salts thereof
C09D 175/08 2006.1
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
175Coating compositions based on polyureas or polyurethanes; Coating compositions based on derivatives of such polymers
04Polyurethanes
08from polyethers
C09J 175/08 2006.1
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
JADHESIVES; NON-MECHANICAL ASPECTS OF ADHESIVE PROCESSES IN GENERAL; ADHESIVE PROCESSES NOT PROVIDED FOR ELSEWHERE; USE OF MATERIALS AS ADHESIVES
175Adhesives based on polyureas or polyurethanes; Adhesives based on derivatives of such polymers
04Polyurethanes
08from polyethers
CPC
C08G 18/2027
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
16Catalysts
18containing secondary or tertiary amines or salts thereof
20Heterocyclic amines; Salts thereof
2009containing one heterocyclic ring
2027having two nitrogen atoms in the ring
C08G 18/4816
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
40High-molecular-weight compounds
48Polyethers
4804Two or more polyethers of different physical or chemical nature
4816mixtures of two or more polyetherpolyols having at least three hydroxy groups
C08G 18/4829
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
40High-molecular-weight compounds
48Polyethers
4829Polyethers containing at least three hydroxy groups
C08G 18/485
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
40High-molecular-weight compounds
48Polyethers
4833Polyethers containing oxyethylene units
4837and other oxyalkylene units
485containing mixed oxyethylene-oxypropylene or oxyethylene-higher oxyalkylene end groups
C08G 18/6225
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
40High-molecular-weight compounds
62Polymers of compounds having carbon-to-carbon double bonds
6216Polymers of alpha-beta ethylenically unsaturated carboxylic acids or of derivatives thereof
622Polymers of esters of alpha-beta ethylenically unsaturated carboxylic acids
6225Polymers of esters of acrylic or methacrylic acid
C08G 18/73
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
70characterised by the isocyanates or isothiocyanates used
72Polyisocyanates or polyisothiocyanates
73acyclic
Applicants
  • BASF SE [DE]/[DE]
Inventors
  • MAY, Micheal, C.
  • PRAW, Michael
Agents
  • KULKARNI, Sima, Singadia
  • TAUFER, Paul, A.
  • CHRISTENBURY, T., Daniel
  • CRUZ, Richaqrd, L.
  • KULKARNI, Sima, Singadia
Priority Data
62/445,44712.01.2017US
Publication Language English (en)
Filing Language English (EN)
Designated States
Title
(EN) PHYSICAL PROPERTY IMPROVEMENT OF POLYURETHANES
(FR) AMÉLIORATION DES PROPRIÉTÉS PHYSIQUES DE POLYURÉTHANES
Abstract
(EN) 100% solids polyurethanes having improved physical properties in terms of Shore hardness, tear strength, elongation at break and/or tensile strength are realized through the introduction of 100% solids hydroxyl-functional acrylics in combination with the hydroxyl-functional polyether and 100% solids isocyanate-functional compounds. When an aromatic isocyanate is used, the isocyanate-reactive component includes from 5 to 70% by weight of a hydroxyl-functional polyether having a weight average molecular weight ranging from 180 to 6,500 g/mol, and 30 to 95% by weight of a hydroxyl-functional acrylic. When an aliphatic isocyanate is used, the isocyanate-reactive component includes from 40 to 70% by weight of a hydroxyl-functional polyether having a weight average molecular weight ranging from 180 to 6,500 g/mol, and 30 to 60% by weight of a hydroxyl-functional acrylic.
(FR) La présente invention concerne des polyuréthanes solides à 100% présentant des propriétés physiques améliorées en termes de dureté Shore, de résistance à la déchirure, d'allongement à la rupture et/ou de force de traction réalisées par l'introduction de composés acryliques à fonctionnalité hydroxyle à 100% solides avec le polyéther à fonctionnalité hydroxyle et des composés à fonctionnalité isocyanate à 100% solides. Lorsqu'un isocyanate aromatique est utilisé, le composant réactif avec les groupes isocyanate comprend de 5 à 70 % en poids d'un polyéther à fonctionnalité hydroxyle ayant un poids moléculaire moyen en poids s'étendant de 180 à 6 500 g/mole, et de 30 à 95 % en poids d'un composé acrylique à fonctionnalité hydroxyle. Lorsqu'un isocyanate aliphatique est utilisé, le composant réactif avec les groupes isocyanate comprend de 40 à 70 % en poids d'un polyéther à fonctionnalité hydroxyle ayant un poids moléculaire moyen en poids s'étendant de 180 à 6 500 g/mole, et de 30 à 60 % en poids d'un composé acrylique à fonctionnalité hydroxyle.
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