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1. (WO2018122510) FUNCTIONALISED CYCLIC DITHIOCARBAMATE SYNTHESIS METHOD

Pub. No.:    WO/2018/122510    International Application No.:    PCT/FR2017/053781
Publication Date: Fri Jul 06 01:59:59 CEST 2018 International Filing Date: Fri Dec 22 00:59:59 CET 2017
IPC: C12P 17/16
C07D 277/16
Applicants: ARKEMA FRANCE
Inventors: FREMY, Georges
MASSELIN, Arnaud
Title: FUNCTIONALISED CYCLIC DITHIOCARBAMATE SYNTHESIS METHOD
Abstract:
The invention relates to a method for synthetising functionalised cyclic dithiocarbamates of formula (I), in which the various substituents are as defined in the description, by reacting a compound of formula (II): G-(CH2)n-C*H(NHR1)-X-R2 with at least one inorganic trithiocarbamate in the presence of an enzyme of the sulfhydrylase family. The invention also relates to functionalised cyclic dithiocarbamates of formula (I) obtained by the method of the invention, and to their use as radical precursors, organic synthesis intermediate compounds, vulcanising agents, chelators or enzyme inhibitors.