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1. (WO2018105261) SYNTHETIC LEATHER
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Pub. No.: WO/2018/105261 International Application No.: PCT/JP2017/038608
Publication Date: 14.06.2018 International Filing Date: 26.10.2017
IPC:
D06N 3/14 (2006.01) ,C08G 18/44 (2006.01) ,C08G 18/66 (2006.01) ,C08G 18/75 (2006.01)
D TEXTILES; PAPER
06
TREATMENT OF TEXTILES OR THE LIKE; LAUNDERING; FLEXIBLE MATERIALS NOT OTHERWISE PROVIDED FOR
N
WALL, FLOOR, OR LIKE COVERING MATERIALS, e.g. LINOLEUM, OILCLOTH, ARTIFICIAL LEATHER, ROOFING FELT, CONSISTING OF A FIBROUS WEB COATED WITH A LAYER OF MACROMOLECULAR MATERIAL; FLEXIBLE SHEET MATERIAL NOT OTHERWISE PROVIDED FOR
3
Artificial leather, oilcloth, or like material obtained by covering fibrous webs with macromolecular material, e.g. resins, rubber or derivatives thereof
12
with macromolecular compounds obtained otherwise than by reactions only involving carbon-to-carbon unsaturated bonds
14
with polyurethanes
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18
Polymeric products of isocyanates or isothiocyanates
06
with compounds having active hydrogen
28
characterised by the compounds used containing active hydrogen
40
High-molecular-weight compounds
42
Polycondensates having carboxylic or carbonic ester groups in the main chain
44
Polycarbonates
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18
Polymeric products of isocyanates or isothiocyanates
06
with compounds having active hydrogen
28
characterised by the compounds used containing active hydrogen
65
Low-molecular-weight compounds having active hydrogen with high-molecular-weight compounds having active hydrogen
66
Compounds of groups C08G18/42, C08G18/48, or C08G18/52111
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
G
MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18
Polymeric products of isocyanates or isothiocyanates
06
with compounds having active hydrogen
70
characterised by the isocyanates or isothiocyanates used
72
Polyisocyanates or polyisothiocyanates
74
cyclic
75
cycloaliphatic
Applicants:
DIC株式会社 DIC CORPORATION [JP/JP]; 東京都板橋区坂下三丁目35番58号 35-58, Sakashita 3-chome, Itabashi-ku, Tokyo 1748520, JP
Inventors:
千々和 宏之 CHIJIWA Hiroyuki; JP
片上 保之 KATAKAMI Yasuyuki; JP
上口 美和 UEGUCHI Miwa; JP
Agent:
河野 通洋 KONO Michihiro; JP
Priority Data:
2016-23583105.12.2016JP
2016-24544819.12.2016JP
Title (EN) SYNTHETIC LEATHER
(FR) SIMILICUIR
(JA) 合成皮革
Abstract:
(EN) The present invention provides a synthetic leather in which a base fabric (i), a bonding layer (ii), an intermediate layer (iii) and a skin layer (iv) are sequentially laminated, and which is characterized in that the intermediate layer (iii) is formed from a polyurethane resin composition containing a polyurethane resin (X) that is a reaction product of a polyol (A) containing 70% by mass or more of a polycarbonate polyol (a-1), an aliphatic or alicyclic polyisocyanate (B) and a chain extender (C). It is preferable that the bonding layer (ii) is formed from a polyurethane resin composition that contains a polyurethane resin (D-1) having a hydroxyl group and a crosslinking agent (D-2), said polyurethane resin (D-1) being a reaction product of the polyol (A) containing 70% by mass or more of a polycarbonate polyol (a-1), the aliphatic or alicyclic polyisocyanate (B) and the chain extender (C). The present invention provides a synthetic leather which is free from deformation or the like even in cases where a sunscreen cream gets thereon.
(FR) La présente invention concerne un similicuir dans lequel un tissu de base (i), une couche de liaison (ii), une couche intermédiaire (iii) et une couche de peau (iv) sont séquentiellement stratifiées et qui est caractérisé en ce que la couche intermédiaire (iii) est formée à partir d'une composition de résine de polyuréthane contenant une résine de polyuréthane (X) qui est un produit de réaction d'un polyol (A) contenant 70 % en masse ou plus d'un polycarbonate polyol (a-1), d'un polyisocyanate aliphatique ou alicyclique (B) et d'un prolongateur de chaîne (C). Il est préférable que la couche de liaison (ii) soit formée à partir d'une composition de résine de polyuréthane contenant une résine de polyuréthane (D-1) présentant un groupe hydroxyle et un agent de réticulation (D-2), ladite résine de polyuréthane (D-1) étant un produit de réaction du polyol (A) contenant 70 % en masse ou plus d'un polycarbonate polyol (a-1), du polyisocyanate aliphatique ou alicyclique (B) et du prolongateur de chaîne (C). La présente invention concerne un similicuir qui est exempt de déformation ou similaire même dans les cas où une crème solaire se répand sur ce dernier.
(JA) 本発明は、基布(i)、接着層(ii)、中間層(iii)、及び、表皮層(iv)が順次積層された合成皮革であって、前記中間層(iii)が、ポリカーボネートポリオール(a-1)を70質量%以上含有するポリオール(A)、脂肪族又は脂環式ポリイソシアネート(B)、及び、鎖伸長剤(C)の反応物であるポリウレタン樹脂(X)を含むポリウレタン樹脂組成物により形成されたものであることを特徴とする合成皮革を提供する。前記接着層(ii)は、ポリカーボネートポリオール(a-1)を70質量%以上含有するポリオール(A)、脂肪族又は脂環式ポリイソシアネート(B)、及び、鎖伸長剤(C)の反応物である水酸基を有するポリウレタン樹脂(D-1)と架橋剤(D-2)とを含むポリウレタン樹脂組成物により形成されたものであることが好ましい。本発明は、日焼け止めクリームが付着しても、変形等を起こさない合成皮革を提供することである。
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Japanese (JA)
Filing Language: Japanese (JA)