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1. (WO2018104471) CATALYST COMPOSITION
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Pub. No.: WO/2018/104471 International Application No.: PCT/EP2017/081875
Publication Date: 14.06.2018 International Filing Date: 07.12.2017
IPC:
B01J 29/18 (2006.01) ,B01J 29/40 (2006.01) ,B01J 29/80 (2006.01) ,B01J 35/02 (2006.01) ,B01J 35/00 (2006.01) ,C01B 39/26 (2006.01) ,C01B 39/38 (2006.01) ,C07C 6/12 (2006.01) ,C07C 15/06 (2006.01)
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
18
of the mordenite type
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
40
of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
80
Mixtures of different zeolites
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35
Catalysts, in general, characterised by their form or physical properties
02
Solids
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35
Catalysts, in general, characterised by their form or physical properties
C CHEMISTRY; METALLURGY
01
INORGANIC CHEMISTRY
B
NON-METALLIC ELEMENTS; COMPOUNDS THEREOF
39
Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
02
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants: After-treatment thereof
26
Mordenite type
C CHEMISTRY; METALLURGY
01
INORGANIC CHEMISTRY
B
NON-METALLIC ELEMENTS; COMPOUNDS THEREOF
39
Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
02
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants: After-treatment thereof
36
Pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
38
Type ZSM-5
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
6
Preparation of hydrocarbons from hydrocarbons containing a different number of carbon atoms by redistribution reactions
08
by conversion at a saturated carbon-to-carbon bond
12
of exclusively hydrocarbons containing a six-membered aromatic ring
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
15
Cyclic hydrocarbons containing only six-membered aromatic rings as cyclic part
02
Monocyclic hydrocarbons
06
Toluene
Applicants:
SHELL INTERNATIONALE RESEARCH MAATSCHAPPIJ B.V. [NL/NL]; Carel van Bylandtlaan 30 2596 HR THE HAGUE, NL (AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BE, BF, BG, BH, BJ, BN, BR, BW, BY, BZ, CA, CF, CG, CH, CI, CL, CM, CN, CO, CR, CU, CY, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, FR, GA, GB, GD, GE, GH, GM, GN, GQ, GR, GT, GW, HN, HR, HU, ID, IE, IL, IN, IR, IS, IT, JO, JP, KE, KG, KH, KM, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LT, LU, LV, LY, MA, MC, MD, ME, MG, MK, ML, MN, MR, MT, MW, MX, MY, MZ, NA, NE, NG, NI, NL, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SI, SK, SL, SM, SN, ST, SV, SY, SZ, TD, TG, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, UZ, VC, VN, ZA, ZM, ZW)
SHELL OIL COMPANY [US/US]; SHELL PLAZA 1 HOUSTON, Texas 77252-2463, US (US)
Inventors:
LI, Hong-Xin; US
MAUER, Richard, Berend; NL
SABATER PUJADAS, Gisela; NL
Agent:
MATTHEZING, Robert, Maarten; NL
Priority Data:
62/431,86009.12.2016US
Title (EN) CATALYST COMPOSITION
(FR) COMPOSITION DE CATALYSEUR
Abstract:
(EN) A catalyst composition comprising (a) carrier comprising (i) 5 to 95 wt% mordenite type zeolite having a mean crystallite length parallel to the direction of the 12-ring channels of 60 nm or less and a mesopore volume of at least 0.10 cc/gram, (ii) 5 to 95 wt% ZSM-5 type zeolite; and (iii) 10 to 60 wt% inorganic binder; and (b) 0.001 to 10 wt% of one or more catalytically active metals, wherein the inorganic binder comprises titania, its preparation and its use in alkylaromatic conversion.
(FR) Une composition de catalyseur comprenant (a) un support comprenant (i) 5 à 95 % en poids de zéolite de type mordénite ayant une longueur moyenne de cristallite parallèle à la direction des canaux à 12-anneaux de 60 nm ou moins et un volume mésoporeux d'au moins 0,10 cc/gramme, (ii) 5 à 95 % en poids de zéolite de type ZSM-5; et (iii) 10 à 60 % en poids de liant inorganique; et (b) 0,001 à 10 % en poids d'un ou de plusieurs métaux catalytiquement actifs, le liant inorganique comprenant du dioxyde de titane, sa préparation et son utilisation dans la conversion alkylaromatique.
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)