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1. (WO2018079876) HYDROCRACKING CATALYST FOR PREPARING LIGHT AROMATIC HYDROCARBON, METHOD FOR PREPARING SAME, AND METHOD FOR PREPARING LIGHT AROMATIC HYDROCARBON BY USING SAME
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Pub. No.: WO/2018/079876 International Application No.: PCT/KR2016/012151
Publication Date: 03.05.2018 International Filing Date: 27.10.2016
IPC:
B01J 29/72 (2006.01) ,B01J 29/78 (2006.01) ,B01J 29/46 (2006.01) ,B01J 29/48 (2006.01) ,B01J 37/02 (2006.01) ,B01J 37/00 (2006.01) ,C07C 4/18 (2006.01)
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
70
of types characterised by their specific structure not provided for in groups B01J29/08-B01J29/65130
72
containing iron group metals, noble metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
70
of types characterised by their specific structure not provided for in groups B01J29/08-B01J29/65130
78
containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
40
of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
42
containing iron group metals, noble metals or copper
46
Iron group metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
40
of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
48
containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
02
Impregnation, coating or precipitation
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
4
Preparation of hydrocarbons from hydrocarbons containing a larger number of carbon atoms
08
by splitting-off an aliphatic or cycloaliphatic part from the molecule
12
from hydrocarbons containing a six-membered aromatic ring, e.g. propyltoluene to vinyltoluene
14
splitting taking place at an aromatic-aliphatic bond
18
Catalytic processes
Applicants:
에쓰대시오일 주식회사 S-OIL CORPORATION [KR/KR]; 서울시 마포구 백범로 192 192, Baekbeom-ro, Mapo-gu, Seoul 04196, KR
동아대학교 산학협력단 DONG-A UNIVERSITY RESEARCH FOUNDATION FOR INDUSTRY-ACADEMY COOPERATION [KR/KR]; 부산시 사하구 낙동대로550번길 37 37, Nakdong-daero 550beon-gil Saha-gu Busan 49315, KR
Inventors:
이정규 LEE, Jung Kyoo; KR
신재욱 SHIN, Jaeuk; KR
최예슬 CHOI, Yeseul; KR
장순철 CHANG, Soon Cheol; KR
강흥중 KANG, Heung Jung; KR
강동일 KANG, Dong Il; KR
Agent:
특허법인 충현 CHUNG HYUN PATENT & LAW FIRM; 서울시 서초구 동산로 23 베델회관 8층 Bethel Bldg. 8F., 23, Dongsan-ro Seocho-gu Seoul 06779, KR
Priority Data:
10-2016-014012926.10.2016KR
Title (EN) HYDROCRACKING CATALYST FOR PREPARING LIGHT AROMATIC HYDROCARBON, METHOD FOR PREPARING SAME, AND METHOD FOR PREPARING LIGHT AROMATIC HYDROCARBON BY USING SAME
(FR) CATALYSEUR D'HYDROCRAQUAGE POUR PRÉPARER UN HYDROCARBURE AROMATIQUE LÉGER, SON PROCÉDÉ DE PRÉPARATION, ET PROCÉDÉ DE PRÉPARATION D'HYDROCARBURE AROMATIQUE LÉGER À L'AIDE DE CELUI-CI
(KO) 경방향족 탄화수소 제조용 수소화 분해 반응 촉매, 이의 제조방법 및 이를 이용한 경방향족 탄화수소의 제조방법
Abstract:
(EN) The present invention relates to: a hydrocracking catalyst for preparing a C6-C9 light aromatic hydrocarbon, having an increased BTX content, from a polycyclic aromatic hydrocarbon; a method for preparing the same; and a method for preparing a C6-C9 light aromatic hydrocarbon, having an increased BTX content, by using the same and, more specifically, an effect of obtaining, in a high yield, a C6-C9 light aromatic hydrocarbon, having an increased BTX content, from the by-products, containing polycyclic aromatic hydrocarbons such as naphthalene and alkyl-naphthalene, of petroleum refining and petrochemical processes can be achieved by using a catalyst in which one or more metals selected from group VIII and one or more metals selected from group VIB are supported on a composite zeolite support of zeolite beta and zeolite ZSM-5.
(FR) La présente invention concerne : un catalyseur d'hydrocraquage pour préparer un hydrocarbure aromatique léger C6-C9, ayant une teneur en BTX augmentée, à partir d'un hydrocarbure aromatique polycyclique; un procédé de préparation de celui-ci; et un procédé de préparation d'un hydrocarbure aromatique léger en C6-C9, ayant un contenu en BTX augmenté, obtenu à l'aide de ce catalyseur. Plus spécifiquement, l'obtention, avec un rendement élevé, d'un hydrocarbure aromatique léger en C6-C9, ayant une teneur en BTX augmentée, à partir de sous-produits, contenant des hydrocarbures aromatiques polycycliques tels que le naphtalène et l'alkyl-naphtalène, de raffinage de pétrole et de processus pétrochimiques peut être obtenu en utilisant un catalyseur dans lequel un ou plusieurs métaux choisis dans le groupe VIII et un ou plusieurs métaux sélectionnés dans le groupe VIB sont supportés sur un support de zéolite composite de zéolite bêta et de zéolite ZSM-5.
(KO) 본 발명은 다환 방향족 탄화수소로부터 BTX 함량이 증가된 C6-C9 범위의 경방향족 탄화수소를 제조하는 수소화 분해 반응용 촉매, 이의 제조방법 및 이를 이용한 BTX 함량이 증가된 C6-C9 범위의 경방향족 탄화수소의 제조방법에 관한 것으로, 보다 상세하게는 제올라이트 베타 및 제올라이트 ZSM-5의 복합 제올라이트 담체에 VIII족에서 선택되는 하나 이상의 금속, 및 VIB족에서 선택되는 하나 이상의 금속이 담지된 촉매를 사용함으로써, 나프탈렌, 알킬-나프탈렌 등과 같은 다환 방향족 탄화수소가 포함되어 있는 정유 및 석유화학 공정의 부산물로부터 BTX 함량이 증가된 C6-C9 범위의 경방향족 탄화수소를 높은 수율로 얻는 효과를 달성할 수 있다.
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Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Korean (KO)
Filing Language: Korean (KO)