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1. (WO2018046928) CATALYST AND PROCESS USING THE CATALYST FOR MANUFACTURING FLUORINATED HYDROCARBONS
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Pub. No.: WO/2018/046928 International Application No.: PCT/GB2017/052618
Publication Date: 15.03.2018 International Filing Date: 07.09.2017
IPC:
B01J 23/26 (2006.01) ,B01J 23/86 (2006.01) ,B01J 35/10 (2006.01) ,B01J 37/04 (2006.01) ,B01J 37/03 (2006.01) ,B01J 37/26 (2006.01) ,B01J 37/08 (2006.01) ,B01J 37/02 (2006.01) ,B01J 27/12 (2006.01) ,B01J 27/132 (2006.01) ,B01J 35/02 (2006.01) ,C07C 17/25 (2006.01) ,C07C 21/18 (2006.01) ,C07C 17/087 (2006.01)
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
16
of arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
24
Chromium, molybdenum or tungsten
26
Chromium
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
23
Catalysts comprising metals or metal oxides or hydroxides, not provided for in group B01J21/113
70
of the iron group metals or copper
76
combined with metals, oxides or hydroxides provided for in groups B01J23/02-B01J23/36118
84
with arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
85
Chromium, molybdenum, or tungsten
86
Chromium
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35
Catalysts, in general, characterised by their form or physical properties
02
Solids
10
characterised by their surface properties or porosity
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
04
Mixing
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
02
Impregnation, coating or precipitation
03
Precipitation; Co-precipitation
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
22
Halogenating
26
Fluorinating
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
08
Heat treatment
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
02
Impregnation, coating or precipitation
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
27
Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
06
Halogens; Compounds thereof
08
Halides
12
Fluorides
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
27
Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
06
Halogens; Compounds thereof
132
with chromium, molybdenum, tungsten or polonium
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35
Catalysts, in general, characterised by their form or physical properties
02
Solids
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
17
Preparation of halogenated hydrocarbons
25
by splitting-off hydrogen halides from halogenated hydrocarbons
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
21
Acyclic unsaturated compounds containing halogen atoms
02
containing carbon-to-carbon double bonds
18
containing fluorine
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
17
Preparation of halogenated hydrocarbons
07
by addition of hydrogen halides
087
to unsaturated halogenated hydrocarbons
Applicants: MEXICHEM FLUOR S.A. DE C.V.[MX/MX]; Eje 106 San Luis Potosi, S.L.P., C.P. 78395, MX
MEXICHEM UK LTD[GB/GB]; The Heath Business and Technical Park Runcorn Cheshire WA7 4QX, GB (MG)
Inventors: REES, Claire Nicola; GB
MCGUINNESS, Claire Elizabeth; GB
SHARRATT, Andrew Paul; GB
Agent: CURTIS, Simon Paul; GB
Priority Data:
1615209.207.09.2016GB
Title (EN) CATALYST AND PROCESS USING THE CATALYST FOR MANUFACTURING FLUORINATED HYDROCARBONS
(FR) CATALYSEUR ET PROCÉDÉ UTILISANT LE CATALYSEUR POUR LA FABRICATION D'HYDROCARBURES FLUORÉS
Abstract:
(EN) A catalyst comprising chromia and at least one additional metal or compound thereof and wherein the catalyst has a total pore volume of greater than 0.3 cm3/g and the mean pore diameter is greater than or equal to 90 Å, wherein the total pore volume is measured by N2 adsorption porosimetry and the mean pore diameter is measured by N2 BET adsorption porosimetry, and wherein the at least one additional metal is selected from Li, Na, K, Ca, Mg, Cs, Sc, Al, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Pd, In, Pt, Cu, Ag, Au, Zn, La, Ce and mixtures thereof.
(FR) L'invention concerne un catalyseur comprenant de la chrome et au moins un métal supplémentaire ou un composé de celui-ci. Ledit catalyseur a un volume poreux total supérieur à 0,3 cm3/g et le diamètre moyen des pores est supérieur ou égal à 90 Å, le volume poreux total étant mesuré par porosimétrie par adsorption de N2 et le diamètre moyen des pores étant mesuré par porosimétrie par adsorption BET N2, et l'un ou les métaux supplémentaires étant choisis parmi Li, Na, K, Ca, Mg, Cs, Sc, Al, Y, Ti, Zr, Hf, V, Nb, Ta, Cr, Mo, W, Mn, Re, Fe, Ru, Co, Rh, Ir, Ni, Pd, In, Pt, Cu, Ag, Au, Zn, La, Ce et des mélanges de ceux-ci.
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)