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1. (WO2018000402) APPLICATION OF BIS(Β-DIIMIDE) RARE EARTH AMIDE FOR CATALYZING HYDROBORATION REACTION BETWEEN KETONE AND BORANE
Latest bibliographic data on file with the International Bureau   

Pub. No.: WO/2018/000402 International Application No.: PCT/CN2016/088051
Publication Date: 04.01.2018 International Filing Date: 01.07.2016
IPC:
B01J 31/22 (2006.01) ,C07F 5/04 (2006.01)
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
31
Catalysts comprising hydrides, coordination complexes or organic compounds
16
containing coordination complexes
22
Organic complexes
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
5
Compounds containing elements of the 3rd Group of the Periodic System
02
Boron compounds
04
Esters of boric acids
Applicants:
苏州大学张家港工业技术研究院 ZHANGJIAGANG INSTITUTE OF INDUSTRIAL TECHNOLOGIES SOOCHOW UNIVERSITY [CN/CN]; 中国江苏省苏州市 张家港市长泾路10号 No.10 Changjing Road, Zhangjiagang Suzhou, Jiangsu 215600, CN
Inventors:
薛明强 XUE, Mingqiang; CN
朱章野 ZHU, Zhangye; CN
洪玉标 HONG, Yubiao; CN
沈琪 SHEN, Qi; CN
郑煜 ZHENG, Yu; CN
Agent:
苏州创元专利商标事务所有限公司 SUZHOU CREATOR PATENT AND TRADEMARK AGENCY, LTD; 中国江苏省苏州市 姑苏区干将西路93号5楼陶海锋 TAO, Haifeng 5th Floor, No.93 Ganjiang West Road, Gusu District Suzhou, Jiangsu 215002, CN
Priority Data:
Title (EN) APPLICATION OF BIS(Β-DIIMIDE) RARE EARTH AMIDE FOR CATALYZING HYDROBORATION REACTION BETWEEN KETONE AND BORANE
(FR) APPLICATION DU BIS(Β-DIIMIDE) AMIDE DE TERRE RARE POUR CATALYSER LA REACTION DE HYDROBORATION ENTRE UNE CETONE ET LE BORANE.
(ZH) 二(β-二亚胺基)稀土胺化物在催化酮和硼烷硼氢化反应中的应用
Abstract:
(EN) An application of a bis(β-diimide) rare earth amide for catalyzing a hydroboration reaction between a ketone and a borane. The molecular formula of a catalyst is [2‑Me‑C6H4‑NC(Me)CHC(Me)N‑C6H4‑2‑Me]2LnN(SiMe3)2, wherein Ln represents a rare earth metal selected from either Nd or Pr. The catalyst can achieve an addition reaction between a borane and a ketone within a short period of time (8-10 minutes) under mild conditions (room temperature) and can provide an extremely high yield. The invention is the first embodiment using a rare earth compound for catalyzing a reaction.
(FR) Application du bis(β-diimide) un amide de terre rare pour catalyser une réaction d'hydroboration entre une cétone et le borane. La formule moléculaire d'un catalyseur est [2-Me-C6H4-NC(Me)CHC(Me)N-C6H4-2-Me]2LnN(SiMe3)2, dans laquelle Ln représente un métal des terres rares choisi parmi Nd ou Pr. Le catalyseur peut réaliser une réaction d'addition entre un borane et une cétone en une courte période de temps (8 à 10 minutes) dans des conditions douces (température ambiante) et peut fournir un rendement extrêmement élevé. L'invention est le premier mode de réalisation utilisant un composé des terres rares pour catalyser une réaction.
(ZH) 一种二(β‑二亚胺基)稀土胺化物在催化酮与硼烷硼氢化反应中的应用,催化剂分子式为[2‑Me‑C 6H 4‑NC(Me)CHC(Me)N‑C 6H 4‑2‑Me] 2LnN(SiMe 3) 2,Ln表示稀土金属,选自Nd,Pr中的一种。该催化剂能使硼烷与酮在温和的条件下(室温),以极短的时间(8‑10分钟)发生加成反应,得到极高的产率。为首例采用稀土化合物催化该类反应。
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Chinese (ZH)
Filing Language: Chinese (ZH)