Some content of this application is unavailable at the moment.
If this situation persist, please contact us atFeedback&Contact
1. (WO2017221073) A PROCESS FOR SELECTIVE DEEP HYDRODESULFURIZATION OF A HYDROCARBON FEEDSTOCK USING AN UNSUPPORTED NANOCATALYST MADE BY LASER PYROLYSIS
Latest bibliographic data on file with the International BureauSubmit observation

Pub. No.: WO/2017/221073 International Application No.: PCT/IB2017/000947
Publication Date: 28.12.2017 International Filing Date: 22.06.2017
IPC:
B01J 37/08 (2006.01) ,B01J 37/20 (2006.01) ,B01J 37/34 (2006.01) ,B01J 27/051 (2006.01) ,C10G 45/00 (2006.01) ,C10G 45/08 (2006.01)
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
08
Heat treatment
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
20
Sulfiding
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
37
Processes, in general, for preparing catalysts; Processes, in general, for activation of catalysts
34
Irradiation by, or application of, electric, magnetic or wave energy, e.g. ultrasonic waves
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
27
Catalysts comprising the elements or compounds of halogens, sulfur, selenium, tellurium, phosphorus or nitrogen; Catalysts comprising carbon compounds
02
Sulfur, selenium or tellurium; Compounds thereof
04
Sulfides
047
with chromium, molybdenum, tungsten or polonium
051
Molybdenum
C CHEMISTRY; METALLURGY
10
PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
G
CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
45
Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
C CHEMISTRY; METALLURGY
10
PETROLEUM, GAS OR COKE INDUSTRIES; TECHNICAL GASES CONTAINING CARBON MONOXIDE; FUELS; LUBRICANTS; PEAT
G
CRACKING HYDROCARBON OILS; PRODUCTION OF LIQUID HYDROCARBON MIXTURES, e.g. BY DESTRUCTIVE HYDROGENATION, OLIGOMERISATION, POLYMERISATION; RECOVERY OF HYDROCARBON OILS FROM OIL-SHALE, OIL-SAND, OR GASES; REFINING MIXTURES MAINLY CONSISTING OF HYDROCARBONS; REFORMING OF NAPHTHA; MINERAL WAXES
45
Refining of hydrocarbon oils using hydrogen or hydrogen-generating compounds
02
to eliminate hetero atoms without changing the skeleton of the hydrocarbon involved and without cracking into lower boiling hydrocarbons; Hydrofinishing
04
characterised by the catalyst used
06
containing nickel or cobalt metal, or compounds thereof
08
in combination with chromium, molybdenum, or tungsten metals, or compounds thereof
Applicants:
KING FAHD UNIVERSITY OF PETROLEUM AND MINERALS [SA/SA]; P.O. Box 5041 Intellectual Assets Office, Innovation Center Dhahran, 31261, SA
COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES [FR/FR]; 25 Rue Leblanc Batiment "le Ponant D" 75115 Paris, FR
Inventors:
YAMANI, Zain, Hassan; SA
TABET, Nouar; SA
ALI, Syed, Ahmed; SA
LECONTE, Yann; FR
SCHUSTER, Frederic; FR
QUINSAC, Axelle; FR
Priority Data:
15/190,43523.06.2016US
Title (EN) A PROCESS FOR SELECTIVE DEEP HYDRODESULFURIZATION OF A HYDROCARBON FEEDSTOCK USING AN UNSUPPORTED NANOCATALYST MADE BY LASER PYROLYSIS
(FR) PROCÉDÉ D'HYDRODÉSULFURISATION SÉLECTIVE EN PRODONDEUR D'UNE CHARGE D'HYDROCARBURES À L'AIDE D'UN NANOCATALYSEUR NON SUPPORTÉ OBTENU PAR PYROLYSE AU LASER
Abstract:
(EN) A process for producing an unsupported molybdenum sulfide nanocatalyst comprising atomizing a molybdenum oxide solution to form a molybdenum oxide aerosol, pyrolyzing the molybdenum oxide aerosol with a laser beam to form the unsupported molybdenum-based nanocatalyst, and pre-sulfiding at least a portion of the unsupported molybdenum-based nanocatalyst to form an unsupported molybdenum sulfide nanocatalyst, wherein the unsupported molybdenum-based nanocatalyst, the unsupported molybdenum sulfide catalyst or both are in the form of nanoparticles with a diameter of 1-10 nm and in a distorted rutile crystalline structure. A method of selective deep hydrodesulfurization whereby a hydrocarbon feedstock having at least one sulfur-containing component and at least one hydrocarbon is contacted with the unsupported molybdenum sulfide nanocatalyst.
(FR) L'invention porte également sur un procédé de production d'un nanocatalyseur de sulfure de molybdène non supporté comprenant l'atomisation d'une solution d'oxyde de molybdène pour former un aérosol d'oxyde de molybdène, la pyrolyse de l'aérosol d'oxyde de molybdène avec un faisceau laser pour former le nanocatalyseur à base de molybdène non supporté, et présulfurer au moins une partie du nanocatalyseur à base de molybdène non supporté pour former un nanocatalyseur de sulfure de molybdène non supporté, le nanocatalyseur à base de molybdène non supporté, le catalyseur de sulfure de molybdène non supporté ou les deux se présentent sous la forme de nanoparticules ayant un diamètre de 1 à 10 nm et dans une structure cristalline de rutile déformée. L'invention porte également sur un procédé d'hydrodésulfuration sélective en profondeur, dans lequel une charge d'alimentation d'hydrocarbure ayant au moins un composant contenant du soufre et au moins un hydrocarbure est mise en contact avec le nanocatalyseur de sulfure de molybdène non supporté.
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JO, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Organization (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)
Also published as:
EP3474990