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1. (WO2017205041) HIGH CHARGE DENSITY METALLOPHOSPHATE MOLECULAR SIEVES

Pub. No.:    WO/2017/205041    International Application No.:    PCT/US2017/031555
Publication Date: Fri Dec 01 00:59:59 CET 2017 International Filing Date: Tue May 09 01:59:59 CEST 2017
IPC: B01J 27/18
B01J 29/84
B01J 31/02
C01B 39/54
C10G 11/05
C10G 35/095
Applicants: UOP LLC
Inventors: LEWIS, Gregory J.
MOSCOSO, Jaime G.
KNIGHT, Lisa M.
NICHOLAS, Christopher P.
SEO, Seungwan
LEE, Junghwan
HONG, Suk Bong
Title: HIGH CHARGE DENSITY METALLOPHOSPHATE MOLECULAR SIEVES
Abstract:
A new family of highly charged crystalline microporous metallophosphate molecular sieves has been synthesized. These metallophosphates are represented by the empirical formula of: Rp+rA+mM2+xEyPOz where A is an alkali metal cation, R is at least one quaternary organoammonium cation, M is a divalent metal such as zinc and E is a trivalent framework element such as aluminum or gallium. This family of high charge density metallophosphate materials are among the first metalloalumino(gallo)phosphate-type molecular sieves to be stabilized by combinations of alkali and quaternary organoammonium cations, enabling unique compositions. This family of high charge density metallophosphate molecular sieves has catalytic properties for carrying out various hydrocarbon conversion processes and separation properties for separating at least one component.