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1. (WO2017202495) A SYNTHETIC ZEOLITE COMPRISING A CATALYTIC METAL
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Pub. No.: WO/2017/202495 International Application No.: PCT/EP2017/000621
Publication Date: 30.11.2017 International Filing Date: 24.05.2017
IPC:
B01J 29/50 (2006.01) ,B01J 29/52 (2006.01) ,B01J 29/54 (2006.01) ,B01J 29/56 (2006.01) ,B01J 29/58 (2006.01) ,B01J 29/70 (2006.01) ,B01J 29/72 (2006.01) ,B01J 29/74 (2006.01) ,B01J 29/76 (2006.01) ,B01J 29/78 (2006.01) ,C01B 39/48 (2006.01) ,B01J 29/84 (2006.01) ,B01J 29/85 (2006.01) ,B01J 29/86 (2006.01) ,B01J 29/87 (2006.01) ,B01J 29/88 (2006.01) ,B01J 29/89 (2006.01) ,B01J 35/00 (2006.01) ,C07C 5/09 (2006.01) ,B01J 20/18 (2006.01)
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
50
of the erionite or offretite type, e.g. zeolite T
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
50
of the erionite or offretite type, e.g. zeolite T
52
containing iron group metals, noble metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
50
of the erionite or offretite type, e.g. zeolite T
52
containing iron group metals, noble metals or copper
54
Noble metals
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
50
of the erionite or offretite type, e.g. zeolite T
52
containing iron group metals, noble metals or copper
56
Iron group metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
50
of the erionite or offretite type, e.g. zeolite T
58
containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
70
of types characterised by their specific structure not provided for in groups B01J29/08-B01J29/65130
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
70
of types characterised by their specific structure not provided for in groups B01J29/08-B01J29/65130
72
containing iron group metals, noble metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
70
of types characterised by their specific structure not provided for in groups B01J29/08-B01J29/65130
72
containing iron group metals, noble metals or copper
74
Noble metals
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
70
of types characterised by their specific structure not provided for in groups B01J29/08-B01J29/65130
72
containing iron group metals, noble metals or copper
76
Iron group metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
70
of types characterised by their specific structure not provided for in groups B01J29/08-B01J29/65130
78
containing arsenic, antimony, bismuth, vanadium, niobium, tantalum, polonium, chromium, molybdenum, tungsten, manganese, technetium or rhenium
C CHEMISTRY; METALLURGY
01
INORGANIC CHEMISTRY
B
NON-METALLIC ELEMENTS; COMPOUNDS THEREOF
39
Compounds having molecular sieve and base-exchange properties, e.g. crystalline zeolites; Their preparation; After-treatment, e.g. ion-exchange or dealumination
02
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof; Direct preparation thereof; Preparation thereof starting from a reaction mixture containing a crystalline zeolite of another type, or from preformed reactants: After-treatment thereof
46
Other types characterised by their X-ray diffraction pattern and their defined composition
48
using at least one organic template directing agent
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
82
Phosphates
84
Aluminophosphates containing other elements, e.g. metals, boron
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
82
Phosphates
84
Aluminophosphates containing other elements, e.g. metals, boron
85
Silicoaluminophosphates (SAPO compounds)
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
86
Borosilicates; Aluminoborosilicates
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
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CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
87
Gallosilicates; Aluminogallosilicates; Galloborosilicates
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
88
Ferrosilicates; Ferroaluminosilicates
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
89
Silicates, aluminosilicates or borosilicates of titanium, zirconium or hafnium
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
35
Catalysts, in general, characterised by their form or physical properties
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
5
Preparation of hydrocarbons from hydrocarbons containing the same number of carbon atoms
02
by hydrogenation
08
of carbon-to-carbon triple bonds
09
to carbon-to-carbon double bonds
B PERFORMING OPERATIONS; TRANSPORTING
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PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
20
Solid sorbent compositions or filter aid compositions; Sorbents for chromatography; Processes for preparing, regenerating or reactivating thereof
02
comprising inorganic material
10
comprising silica or silicate
16
Alumino-silicates
18
Synthetic zeolitic molecular sieves
Applicants:
CORMA CANOS, Avelino [ES/ES]; ES (US)
GUZMAN, Javier [US/US]; US (US)
MOLINER MARIN, Manuel [ES/ES]; ES (US)
SERNA MERINO, Pedro [ES/US]; US (US)
STROHMAIER, Karl G. [US/US]; US (US)
EXXONMOBIL CHEMICAL PATENTS INC. [US/US]; 5200 Bayway Drive Baytown, TX 77520-2101, US (AllExceptUS)
Inventors:
CORMA CANOS, Avelino; ES
GUZMAN, Javier; US
MOLINER MARIN, Manuel; ES
SERNA MERINO, Pedro; US
STROHMAIER, Karl G.; US
Agent:
TROCH, Genevieve; Hermeslaan 2 1831 Machelen, BE
Priority Data:
16183679.611.08.2016EP
62/340,76824.05.2016US
Title (EN) A SYNTHETIC ZEOLITE COMPRISING A CATALYTIC METAL
(FR) ZÉOLITE SYNTHÉTIQUE COMPRENANT UN MÉTAL CATALYTIQUE
Abstract:
(EN) A small pore size synthetic zeolite having a degree of crystallinity of at least 80% and comprising at least 0,01 wt% based on the weight of the zeolite of at least one catalytic metal selected from the group consisting of Ru, Rh, Pd, Ag, Os, Ir, Pt, Au, Mo, W, Re, Co, Ni, Zn, Cr, Mn, Ce, Ga and combinations thereof, wherein at least 80% of the catalytic metal is encapsulated in the zeolite, wherein if the zeolite is an aluminosilicate it has a SiO2:Al2O3 molar ratio of greater than 6:1.
(FR) La présente invention concerne une zéolite synthétique à petite taille de pores ayant un degré de cristallinité d'au moins 80 % et comprenant au moins 0,01 % en poids sur la base du poids de la zéolite d'au moins un métal catalytique choisi dans le groupe constitué par Ru, Rh, Pd, Ag, Os, Ir, Pt, Au, Mo, W, Re, Co, Ni, Zn, Cr, Mn, Ce, Ga et leurs combinaisons, au moins 80 % du métal catalytique étant encapsulé dans la zéolite. Si la zéolite est un aluminosilicate, elle a un rapport molaire SiO2:Al2O3 supérieur à 6:1.
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)