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1. (WO2017170646) METHOD FOR FORMING FILM ON METAL SURFACE
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Pub. No.: WO/2017/170646 International Application No.: PCT/JP2017/012822
Publication Date: 05.10.2017 International Filing Date: 29.03.2017
IPC:
C23C 14/12 (2006.01) ,B32B 15/082 (2006.01) ,C23C 14/02 (2006.01) ,C23C 14/06 (2006.01)
C CHEMISTRY; METALLURGY
23
COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
C
COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
14
Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
06
characterised by the coating material
12
Organic material
B PERFORMING OPERATIONS; TRANSPORTING
32
LAYERED PRODUCTS
B
LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
15
Layered products essentially comprising metal
04
comprising metal as the main or only constituent of a layer, next to another layer of a specific substance
08
of synthetic resin
082
comprising vinyl resins; comprising acrylic resins
C CHEMISTRY; METALLURGY
23
COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
C
COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
14
Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
02
Pretreatment of the material to be coated
C CHEMISTRY; METALLURGY
23
COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; CHEMICAL SURFACE TREATMENT; DIFFUSION TREATMENT OF METALLIC MATERIAL; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL; INHIBITING CORROSION OF METALLIC MATERIAL OR INCRUSTATION IN GENERAL
C
COATING METALLIC MATERIAL; COATING MATERIAL WITH METALLIC MATERIAL; SURFACE TREATMENT OF METALLIC MATERIAL BY DIFFUSION INTO THE SURFACE, BY CHEMICAL CONVERSION OR SUBSTITUTION; COATING BY VACUUM EVAPORATION, BY SPUTTERING, BY ION IMPLANTATION OR BY CHEMICAL VAPOUR DEPOSITION, IN GENERAL
14
Coating by vacuum evaporation, by sputtering or by ion implantation of the coating forming material
06
characterised by the coating material
Applicants:
株式会社東亜電化 TOADENKA CORPORATION [JP/JP]; 岩手県盛岡市渋民字岩鼻20番地の7 20-7,Aza-Iwahana,Shibutami,Morioka-shi, Iwate 0284132, JP
Inventors:
三浦 修平 MIURA Shuhei; JP
千葉 裕 CHIBA Hiroshi; JP
粕谷 昌弘 KASUYA Masahiro; JP
鈴木 一孝 SUZUKI Kazutaka; JP
村松 真希 MURAMATSU Maki; JP
Agent:
田村 爾 TAMURA Chikashi; JP
杉村 純子 SUGIMURA Junko; JP
Priority Data:
2016-07263531.03.2016JP
Title (EN) METHOD FOR FORMING FILM ON METAL SURFACE
(FR) PROCÉDÉ DE FORMATION DE FILM SUR UNE SURFACE MÉTALLIQUE
(JA) 金属表面の被膜形成方法
Abstract:
(EN) The present invention provides a method for forming a film on a metal surface with which it is possible to form on the metal surface a uniform, thin polymer film which has excellent durability and high detaching properties, and which withstands long-term use while retaining the functionality of the surface of the thin film. This method for forming a film on a metal surface is characterized by: irradiating a resin surface with particle beams and then immersing the resin irradiated with particle beams into a solution in which a triazinethiol derivative represented by chemical formula 1 or 2 is dissolved at a concentration of higher than 5 g/l and not higher than 13 g/l, thereby preparing a modified resin having a resin surface decorated with the triazinethiol derivative; and forming a film of the modified resin on a metal surface by vacuum deposition and then forming on the modified resin film a film of the same resin as the resin used for decoration with the triazinethiol derivative by vacuum deposition, thereby providing a resin layer laminate.
(FR) La présente invention concerne un procédé de formation d'un film sur une surface métallique au moyen duquel il est possible de former sur la surface métallique un film polymère mince uniforme qui présente une excellente durabilité et des propriétés de détachement élevées, et qui résiste à une utilisation à long terme tout en conservant la fonctionnalité de la surface du film mince. Ce procédé de formation d'un film sur une surface métallique est caractérisé par : l'irradiation d'une surface de résine par des faisceaux de particules, puis par l'immersion de la résine irradiée par des faisceaux de particules dans une solution dans laquelle un dérivé de triazinethiol représenté par la formule chimique 1 ou 2 est dissous à une concentration supérieure à 5 g/l et inférieure ou égale à 13 g/l, ce qui permet de préparer une résine modifiée présentant une surface décorée avec le dérivé de triazinethiol; et la formation d'un film de la résine modifiée sur une surface métallique par dépôt sous vide, puis la formation sur le film de résine modifiée d'un film de la même résine que la résine utilisée pour la décoration avec le dérivé de triazinethiol par dépôt sous vide, ce qui permet d'obtenir un stratifié de couches de résine.
(JA) 本発明は、金属表面に耐久性に優れる高分子薄膜の均一な被膜が形成でき、離型性が高く、かつ薄膜表面の機能性を維持しつつ薄膜を長時間の使用に耐えるようにした、金属表面被膜形成方法を提供する。 金属表面の被膜形成方法は、樹脂表面に量子ビームを照射し、次いで、次の化1又は化2で表わされるトリアジンチオール誘導体が5g/lを超えて13g/l以下の濃度で溶解した溶液に、量子ビームが照射された樹脂を浸漬させることにより、樹脂の表面が前記トリアジンチオール誘導体で加飾された改質樹脂を調製し、該改質樹脂を、金属表面上に真空蒸着法によって成膜し、次いで、改質樹脂の成膜上に、トリアジンチオール誘導体で加飾するのに用いた前記樹脂と同じ樹脂を、真空蒸着法によって成膜して、積層樹脂層を形成することを特徴とする。
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Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Japanese (JA)
Filing Language: Japanese (JA)