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1. (WO2017154846) METHOD FOR PRODUCING SILYL COMPOUND BY MEANS OF HYDROSILYLATION OF ALLYL COMPOUND USING IRIDIUM COMPLEX OR LIKE

Pub. No.:    WO/2017/154846    International Application No.:    PCT/JP2017/008820
Publication Date: Fri Sep 15 01:59:59 CEST 2017 International Filing Date: Tue Mar 07 00:59:59 CET 2017
IPC: C07F 7/18
B01J 31/16
B01J 31/22
B01J 37/04
C07F 7/08
C07F 15/00
Applicants: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY
国立研究開発法人産業技術総合研究所
Inventors: NAKAJIMA, Yumiko
中島 裕美子
SHIMADA, Shigeru
島田 茂
SATO, Kazuhiko
佐藤 一彦
MATSUMOTO, Kazuhiro
松本 和弘
Title: METHOD FOR PRODUCING SILYL COMPOUND BY MEANS OF HYDROSILYLATION OF ALLYL COMPOUND USING IRIDIUM COMPLEX OR LIKE
Abstract:
According to the present invention, a silyl compound represented by formula (C) is efficiently produced by having an allyl compound represented by formula (A) and a hydrosilane compound represented by formula (B) react with each other in the presence of an iridium complex and/or an iridium salt. (In formulae (A)-(C), X represents a chlorine atom, a bromine atom, an iodine atom or an acyloxy group having 1-10 carbon atoms, which may contain at least one atom selected from the group consisting of an oxygen atom and halogen atoms; each of R1, R2 and R3 independently represents a hydrogen atom or a hydrocarbon group having 1-20 carbon atoms, which may contain at least one atom selected from the group consisting of an oxygen atom, a nitrogen atom, a boron atom and a silicon atom; and each R4 independently represents a hydrogen atom, a halogen atom, a (poly)siloxy group having 1-20 silicon atoms or a hydrocarbon group having 1-20 carbon atoms, which may contain at least one atom selected from the group consisting of an oxygen atom and halogen atoms.)