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1. (WO2017141873) THERMOPLASTIC RESIN FILM AND PRODUCTION METHOD THREREFOR, AND LAMINATE
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Pub. No.: WO/2017/141873 International Application No.: PCT/JP2017/005152
Publication Date: 24.08.2017 International Filing Date: 13.02.2017
IPC:
C08J 5/18 (2006.01) ,B29C 47/14 (2006.01) ,B29C 47/88 (2006.01) ,B32B 7/02 (2006.01) ,B32B 27/18 (2006.01) ,B32B 27/30 (2006.01) ,C08F 265/06 (2006.01) ,B29K 33/00 (2006.01) ,B29L 7/00 (2006.01) ,C08L 33/04 (2006.01) ,C08L 101/00 (2006.01)
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
J
WORKING-UP; GENERAL PROCESSES OF COMPOUNDING; AFTER-TREATMENT NOT COVERED BY SUBCLASSES C08B, C08C, C08F, C08G or C08H142
5
Manufacture of articles or shaped materials containing macromolecular substances
18
Manufacture of films or sheets
B PERFORMING OPERATIONS; TRANSPORTING
29
WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
C
SHAPING OR JOINING OF PLASTICS; SHAPING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL; AFTER- TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
47
Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
08
Component parts, details or accessories; Auxiliary operations
12
Extrusion nozzles or dies
14
with broad opening, e.g. for sheets
B PERFORMING OPERATIONS; TRANSPORTING
29
WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
C
SHAPING OR JOINING OF PLASTICS; SHAPING OF SUBSTANCES IN A PLASTIC STATE, IN GENERAL; AFTER- TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
47
Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
08
Component parts, details or accessories; Auxiliary operations
78
Heating or cooling the material to be extruded or the stream of extruded material
88
Heating or cooling the stream of extruded material
B PERFORMING OPERATIONS; TRANSPORTING
32
LAYERED PRODUCTS
B
LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
7
Layered products characterised by the relation between layers, i.e. products essentially comprising layers having different physical properties or products characterised by the interconnection of layers
02
in respect of physical properties, e.g. hardness
B PERFORMING OPERATIONS; TRANSPORTING
32
LAYERED PRODUCTS
B
LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
27
Layered products essentially comprising synthetic resin
18
characterised by the use of special additives
B PERFORMING OPERATIONS; TRANSPORTING
32
LAYERED PRODUCTS
B
LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
27
Layered products essentially comprising synthetic resin
30
comprising vinyl resin; comprising acrylic resin
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
265
Macromolecular compounds obtained by polymerising monomers on to polymers of unsaturated monocarboxylic acids or derivatives thereof as defined in group C08F20/181
04
on to polymers of esters
06
Polymerisation of acrylate or methacrylate esters on to polymers thereof
B PERFORMING OPERATIONS; TRANSPORTING
29
WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
K
INDEXING SCHEME ASSOCIATED WITH SUBCLASSES B29B, B29C OR B29D103
33
Use of polymers of unsaturated acids or derivatives thereof, as moulding material 
B PERFORMING OPERATIONS; TRANSPORTING
29
WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
L
INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C59
7
Flat articles, e.g. films or sheets
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
L
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
33
Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Compositions of derivatives of such polymers
04
Homopolymers or copolymers of esters
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
L
COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
101
Compositions of unspecified macromolecular compounds
Applicants:
株式会社クラレ KURARAY CO., LTD. [JP/JP]; 岡山県倉敷市酒津1621番地 1621, Sakazu, Kurashiki-shi, Okayama 7100801, JP
Inventors:
辻 和尊 TSUJI, Wataru; JP
干場 孝男 HOSHIBA, Takao; JP
藤井 就明 FUJII, Nariaki; JP
萩原 正明 HAGIWARA, Masaaki; JP
Agent:
家入 健 IEIRI Takeshi; JP
Priority Data:
2016-02575115.02.2016JP
Title (EN) THERMOPLASTIC RESIN FILM AND PRODUCTION METHOD THREREFOR, AND LAMINATE
(FR) FILM DE RÉSINE THERMOPLASTIQUE ET SON PROCÉDÉ DE PRODUCTION, ET STRATIFIÉ
(JA) 熱可塑性樹脂フィルムとその製造方法、および積層体
Abstract:
(EN) Provided is a thermoplastic resin film of which at least one film surface has excellent printability, and which has sufficiently low internal haze and is capable of exhibiting good matte appearance. The thermoplastic resin film according to the present invention comprises a thermoplastic resin composition (C) containing at least one thermoplastic resin (R), and fine particles (P) that has a volume-average particle size of 0.5-15 μm and of which the difference in refractive index from the thermoplastic resin (R) is 0.02 or more. At least one film surface of the thermoplastic resin film satisfies formulae (1) and (2). GL≥60 ··· (1), GL-35≤GH≤GL-10 ··· (2) (In formulae (1) and (2), GL represents the 60° gloss (%) at 20°C, and GH represents the 60° gloss (%) as measured after being heated at a temperature which is higher than the glass transition temperature of the thermoplastic resin composition (C) by 10°C for 30 minutes and then being cooled to 20°C.)
(FR) L'invention concerne un film de résine thermoplastique dont au moins une surface de film présente une excellente imprimabilité, et qui présente un trouble interne suffisamment faible et qui est susceptible de présenter une bonne apparence mate. Le film de résine thermoplastique selon la présente invention comprend une composition de résine thermoplastique (C) contenant au moins une résine thermoplastique (R), et des particules fines (P) qui présentent une taille de particule moyenne en volume de 0,5 à 15 µm et dont la différence d'indices de réfraction par rapport à celui de la résine thermoplastique (R) est supérieure ou égale à 0,02. Au moins une surface de film du film de résine thermoplastique satisfait aux formules (1) et (2). GL≥60 ··· (1), GL-35≤GH≤GL-10 ··· (2) (Dans les formules (1) et (2), GL représente la brillance à 60° (%) à 20 °C, et GH représente la brillance à 60° (%) telles que mesurées après chauffage à une température qui est supérieure à la température de transition vitreuse de la composition de résine thermoplastique (C) de 10 °C pendant 30 minutes et puis refroidissement à 20 °C).
(JA) 少なくとも一方のフィルム面は印刷性に優れ、内部ヘイズが充分に小さく、かつ、良好な艶消し外観を発現することが可能な熱可塑性樹脂フィルムを提供する。本発明の熱可塑性樹脂フィルムは、少なくとも1種の熱可塑性樹脂(R)と、体積平均粒子径が0.5~15μmであり、熱可塑性樹脂(R)との屈折率差が0.02以上である微粒子(P)とを含む熱可塑性樹脂組成物(C)からなり、少なくとも一方のフィルム面が下記式(1)および(2)を充足するものである。G≧60・・・(1)、G-35≦G≦G-10・・・(2)(但し、上記式(1)、(2)中、Gは20℃での60°グロス(%)であり、Gは熱可塑性樹脂組成物(C)のガラス転移温度より10℃高い温度で30分加熱した後、20℃まで冷却した後の60°グロス(%)である。)
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Office (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (EPO) (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Japanese (JA)
Filing Language: Japanese (JA)