Search International and National Patent Collections
Some content of this application is unavailable at the moment.
If this situation persists, please contact us atFeedback&Contact
1. (WO2017131226) N,N-BIS(2-DIALKYLPHOSPHINOETHYL)AMINE-BORANE COMPLEX AND PRODUCTION METHOD THEREFOR, AND METHOD FOR PRODUCING RUTHENIUM COMPLEX CONTAINING N,N-BIS(2-DIALKYLPHOSPHINOETHYL)AMINE AS LIGAND
Latest bibliographic data on file with the International Bureau

Pub. No.: WO/2017/131226 International Application No.: PCT/JP2017/003116
Publication Date: 03.08.2017 International Filing Date: 30.01.2017
IPC:
C07F 9/50 (2006.01) ,C07F 15/00 (2006.01)
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
9
Compounds containing elements of the 5th Group of the Periodic System
02
Phosphorus compounds
28
with one or more P-C bonds
50
Organo-phosphines
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
F
ACYCLIC, CARBOCYCLIC, OR HETEROCYCLIC COMPOUNDS CONTAINING ELEMENTS OTHER THAN CARBON, HYDROGEN, HALOGEN, OXYGEN, NITROGEN, SULFUR, SELENIUM OR TELLURIUM
15
Compounds containing elements of the 8th Group of the Periodic System
Applicants:
高砂香料工業株式会社 TAKASAGO INTERNATIONAL CORPORATION [JP/JP]; 東京都大田区蒲田五丁目37番1号 37-1, Kamata 5-chome, Ohta-ku, Tokyo 1448721, JP
Inventors:
中山 裕治 NAKAYAMA, Yuji; JP
中島 光 Nakajima, Hikaru; JP
Agent:
佐伯 拓郎 SAEKI, Takuro; JP
中村 正展 NAKAMURA, Masanobu; JP
佐伯 裕子 SAEKI, Hiroko; JP
牛山 直子 USHIYAMA, Naoko; JP
Priority Data:
2016-01645529.01.2016JP
Title (EN) N,N-BIS(2-DIALKYLPHOSPHINOETHYL)AMINE-BORANE COMPLEX AND PRODUCTION METHOD THEREFOR, AND METHOD FOR PRODUCING RUTHENIUM COMPLEX CONTAINING N,N-BIS(2-DIALKYLPHOSPHINOETHYL)AMINE AS LIGAND
(FR) COMPLEXE DE N,N-BIS(2-DIALKYLPHOSPHINOÉTHYL)AMINE-BORANE ET SON PROCÉDÉ DE PRODUCTION, ET PROCÉDÉ DE PRODUCTION DE COMPLEXE DE RUTHÉNIUM CONTENANT LA N,N-BIS(2-DIALKYLPHOSPHINOÉTHYL) AMINE COMME LIGAND
(JA) N,N-ビス(2-ジアルキルホスフィノエチル)アミン-ボラン錯体及びその製造法、並びにN,N-ビス(2-ジアルキルホスフィノエチル)アミンを配位子とするルテニウム錯体の製造方法
Abstract:
(EN) The purpose of the present invention is to provide an N,N-bis(2-dialkylphosphinoethyl)amine-borane complex which is a ruthenium complex that exhibits excellent catalytic activity in a hydrogenation reaction, etc., and a production method therefor, and a method for efficiently producing a ruthenium complex containing N,N-bis(2-dialkylphosphinoethyl)amine as a ligand. The present invention is capable of efficiently producing an amine-borane complex (3) by reacting an oxazolidinone compound (1) with a dialkylphosphine-borane compound (2) in the presence of a base. The present invention is also capable of efficiently producing a ruthenium complex (5) by reacting the amine-borane complex (3) with a ruthenium compound (4) in the presence of an amine. (In the formula, a solid line, a dashed line, B, C, H, L1-L3, LG, n, N, O, P, Ru, X, and R1-R10 are as defined in the description.)
(FR) La présente invention vise à fournir un complexe de N,N-bis(2-dialkylphosphinoéthyl)amine-borane qui est un complexe de ruthénium qui présente une excellente activité catalytique dans une réaction d'hydrogénation, etc., son procédé de production, ainsi qu'un procédé de production efficace d'un complexe de ruthénium contenant de la N,N-bis(2-dialkylphosphinoéthyl)amine en tant que ligand. La présente invention permet la production efficace d'un complexe d'amine-borane (3) par la réaction d'un composé oxazolidinone (1) avec un composé dialkylphosphine-borane (2) en présence d'une base. La présente invention est également apte à produire efficacement un complexe de ruthénium (5) par réaction du complexe d'amine-borane (3) avec un composé ruthénium (4) en présence d'une amine. (Dans la formule, une ligne continue, une ligne pointillée, B, C, H, L1 à L3, LG, n, N, O, P, Ru, X, et R1 à R10 sont tels que définis dans la description.)
(JA) 本発明は、水素添加反応等において優れた触媒活性を示すルテニウム錯体の一種である、N,N-ビス(2-ジアルキルホスフィノエチル)アミン-ボラン錯体及びその製造法、並びにN,N-ビス(2-ジアルキルホスフィノエチル)アミンを配位子とするルテニウム錯体の効率的な製造方法を提供することを目的とする。 オキサゾリジノン化合物(1)とジアルキルホスフィン-ボラン化合物(2)を塩基の存在下で反応させることにより、アミン-ボラン錯体(3)を効率的に製造することが出来る。 また、アミン-ボラン錯体(3)とルテニウム化合物(4)をアミン類の存在下で反応させることによりルテニウム錯体(5)の効率的な製造することが出来る。 (式中、実線、破線、B、C、H、L~L、LG、n、N、O、P、Ru、X、及びR~R10は明細書中に定義された意味を有する)
front page image
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Organization (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Japanese (JA)
Filing Language: Japanese (JA)
Also published as:
CA3012962CN108290910EP3409681US20190040090