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1. (WO2017111691) CONVERSION OF ALCOHOLS TO HYDROCARBONS USING A DUAL CATALYST SYSTEM COMPRISING BASIC OXIDE ON MIXED OXIDE OR MESOPOROUS CARRIER AND ETCHED METAL LOADED ZEOLITE CATALYST
Latest bibliographic data on file with the International Bureau

Pub. No.: WO/2017/111691 International Application No.: PCT/SE2016/051296
Publication Date: 29.06.2017 International Filing Date: 20.12.2016
IPC:
C07C 1/20 (2006.01) ,B01J 21/06 (2006.01) ,B01J 29/42 (2006.01) ,B01J 29/85 (2006.01) ,B01J 21/02 (2006.01) ,B01J 21/10 (2006.01)
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
1
Preparation of hydrocarbons from one or more compounds, none of them being a hydrocarbon
20
starting from organic compounds containing only oxygen atoms as hetero atoms
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21
Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
06
Silicon, titanium, zirconium or hafnium; Oxides or hydroxides thereof
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
04
having base-exchange properties, e.g. crystalline zeolites, pillared clays
06
Crystalline aluminosilicate zeolites; Isomorphous compounds thereof
40
of the pentasil type, e.g. types ZSM-5, ZSM-8 or ZSM-11
42
containing iron group metals, noble metals or copper
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
29
Catalysts comprising molecular sieves
82
Phosphates
84
Aluminophosphates containing other elements, e.g. metals, boron
85
Silicoaluminophosphates (SAPO compounds)
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21
Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
02
Boron or aluminium; Oxides or hydroxides thereof
B PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
21
Catalysts comprising the elements, oxides or hydroxides of magnesium, boron, aluminium, carbon, silicon, titanium, zirconium or hafnium
10
Magnesium; Oxides or hydroxides thereof
Applicants:
ECO-OIL MILJÖBRÄNSLEN I SVERIGE AB [SE/SE]; SE
Inventors:
MIKKOLA, Jyri-Pekka; SE
SAMIKANNU, Ajaikumar; SE
VANKLINT, Kent; SE
SILJEBO, William; SE
Agent:
STRÖM & GULLIKSSON AB; P.O.Box 5275 SE-10246 Stockholm, SE
Priority Data:
1551699-022.12.2015SE
Title (EN) CONVERSION OF ALCOHOLS TO HYDROCARBONS USING A DUAL CATALYST SYSTEM COMPRISING BASIC OXIDE ON MIXED OXIDE OR MESOPOROUS CARRIER AND ETCHED METAL LOADED ZEOLITE CATALYST
(FR) CONVERSION D'ALCOOLS EN HYDROCARBURES À L'AIDE D'UN SYSTÈME CATALYTIQUE DOUBLE COMPRENANT UN OXYDE BASIQUE SUR UN OXYDE MIXTE OU UN SUPPORT MÉSOPOREUX ET CATALYSEUR ZÉOLITHIQUE GRAVÉ CHARGÉ DE MÉTAL
Abstract:
(EN) A method for converting an alcohol to hydrocarbons comprises two serially placed catalysts. The fraction of aromatics is reduced to desired levels. The method comprises: a) contacting the alcohol with a first catalyst on a carrier, said carrier is selected from a mixed oxide and a mesoporous carrier, said first catalyst comprises at least one basic oxide and optionally at least one selected from the group consisting of metals and metal oxides, then b) contacting the resulting mixture from step a) with a second catalyst wherein said second catalyst is an etched metal loaded zeolite catalyst wherein the etched metal loaded zeolite catalyst is manufactured with a method comprising etching with subsequent loading of metal onto the catalyst, wherein the metal is in the form of nanoparticles, and wherein at least two different metals are loaded onto the etched zeolite catalyst. The hydrocarbons are recovered and used for instance for fuel including gasoline, kerosene, diesel, and jet propellant, and jet fuel. Naturally, other uses of hydrocarbons should not be excluded.
(FR) L'invention concerne un procédé de conversion d'un alcool en hydrocarbures comprenant deux catalyseurs placés en série. La fraction de composés aromatiques est réduite à des niveaux souhaités. Le procédé consiste à : a) mettre en contact l'alcool avec un premier catalyseur sur un support, ledit support étant choisi parmi un oxyde mixte et un support mésoporeux, ledit premier catalyseur comprenant au moins un oxyde basique et éventuellement au moins l'un choisi dans le groupe constitué par les métaux et les oxydes métalliques, puis b) mettre en contact le mélange résultant de l'étape a) avec un deuxième catalyseur, ledit deuxième catalyseur étant un catalyseur zéolithique gravé chargé de métal, le catalyseur zéolithique gravé chargé de métal étant fabriqué par un procédé comprenant la gravure avec chargement subséquent de métal sur le catalyseur, le métal étant sous forme de nanoparticules, et au moins deux métaux différents étant chargés sur le catalyseur zéolithique gravé. Les hydrocarbures sont récupérés et utilisés, par exemple pour un carburant comprenant l'essence, le kérosène, le diesel, le carburant pour moteur à réaction et le carburéacteur. Bien entendu, d'autres utilisations d'hydrocarbures ne devraient pas être exclues.
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Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KH, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Organization (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: English (EN)
Filing Language: English (EN)
Also published as:
CA3009145AU2016374791CN108473386KR1020180088677EP3394010US20180371328