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1. (WO2017098952) METHOD FOR PRODUCING POLYMERIZABLE COMPOUND
Latest bibliographic data on file with the International Bureau

Pub. No.: WO/2017/098952 International Application No.: PCT/JP2016/085300
Publication Date: 15.06.2017 International Filing Date: 29.11.2016
IPC:
C07D 277/82 (2006.01) ,C08F 16/30 (2006.01) ,C08F 16/32 (2006.01) ,C08F 20/22 (2006.01) ,C08F 20/38 (2006.01)
C CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
D
HETEROCYCLIC COMPOUNDS
277
Heterocyclic compounds containing 1,3-thiazole or hydrogenated 1,3-thiazole rings
60
condensed with carbocyclic rings or ring systems
62
Benzothiazoles
68
with hetero atoms or with carbon atoms having three bonds to hetero atoms with at the most one bond to halogen, e.g. ester or nitrile radicals, directly attached in position 2
82
Nitrogen atoms
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
16
Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical
12
by an ether radical
14
Monomers containing only one unsaturated aliphatic radical
30
Monomers containing sulfur
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
16
Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by an alcohol, ether, aldehydo, ketonic, acetal, or ketal radical
12
by an ether radical
32
Monomers containing two or more unsaturated aliphatic radicals
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
20
Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
02
Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10
Esters
22
Esters containing halogen
C CHEMISTRY; METALLURGY
08
ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
F
MACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
20
Homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
02
Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10
Esters
38
Esters containing sulfur
Applicants:
DIC株式会社 DIC CORPORATION [JP/JP]; 東京都板橋区坂下三丁目35番58号 35-58, Sakashita 3-chome, Itabashi-ku, Tokyo 1748520, JP
Inventors:
堀口 雅弘 HORIGUCHI Masahiro; JP
間宮 純一 MAMIYA Junichi; JP
Agent:
河野 通洋 KONO Michihiro; JP
Priority Data:
2015-23853507.12.2015JP
Title (EN) METHOD FOR PRODUCING POLYMERIZABLE COMPOUND
(FR) PROCÉDÉ DE PRODUCTION D'UN COMPOSÉ POLYMÉRISABLE
(JA) 重合性化合物の製造方法
Abstract:
(EN) The present invention provides: a method for producing a polymerizable compound having a hydrazone moiety in which a substituent such as an alkyl group has been introduced on a nitrogen atom, and a benzothiazole moiety; and a composition containing said compound. The present invention further provides a polymerizable composition which is less prone to discoloration and lowering of orientation when a film-shaped polymer, which is obtained by polymerizing a polymerizable composition containing a polymerizable compound obtained by said production method, is irradiated with ultraviolet light for a long period of time. Further provided are: a polymer obtained by polymerizing the polymerizable composition containing a compound obtained by said production method; and an optically anisotropic body using said polymer. The present invention provides a method for producing a polymerizable compound, the method including a step in which a compound represented by general formula (I-B-a) and a compound represented by general formula (I-B-b) are reacted to obtain a compound represented by general formula (I-C), and provides a composition containing the compound obtained by the production method.
(FR) La présente invention concerne : un procédé de production d'un composé polymérisable ayant une fraction hydrazone dans laquelle un substituant tel qu'un groupe alkyle a été introduit sur un atome d'azote, et une fraction benzothiazole; et une composition contenant ledit composé. La présente invention concerne également une composition polymérisable qui est moins sujette à la décoloration et à la baisse d'orientation lorsqu'un polymère en forme de film, qui est obtenu en polymérisant une composition polymérisable contenant un composé polymérisable obtenu par ledit procédé de production, est exposé à la lumière ultraviolette pendant une longue durée. L'invention concerne en outre : un polymère obtenu en polymérisant la composition polymérisable contenant un composé obtenu par ledit procédé de production; et un corps optiquement anisotrope utilisant ledit polymère. La présente invention concerne un procédé de production d'un composé polymérisable, le procédé comprenant une étape dans laquelle un composé de formule générale (I-B-a) et un composé de formule générale (I-B-b) sont mis à réagir pour obtenir un composé de formule générale (I-C), et concerne également une composition contenant le composé obtenu au moyen dudit procédé de production.
(JA) 本発明は窒素原子上にアルキル基等の置換基を導入したヒドラゾン部位と、ベンゾチアゾール部位とを有する重合性化合物の製造方法、当該化合物を含有する組成物を提供する。また、当該製造方法により得られた重合性化合物を含有する重合性組成物を重合して得られるフィルム状の重合物に対し長期間紫外光を照射した際に、変色及び配向性の低下が生じにくい重合性組成物を提供することである。更に、当該製造方法により得られた化合物を含有する重合性組成物を重合させることで得られる重合体及び当該重合体を用いた光学異方体を提供する。本願発明は一般式(I-B-a)で表される化合物と一般式(I-B-b)で表される化合物とを反応させ、一般式(I-C)で表される化合物を得る工程を含む、重合性化合物の製造方法を提供し、当該製造方法により得られた化合物を含有する組成物を提供する。
Designated States: AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW
African Regional Intellectual Property Organization (ARIPO) (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Organization (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG)
Publication Language: Japanese (JA)
Filing Language: Japanese (JA)
Also published as:
JPWO2017098952CN108290850KR1020180090820US20180354922