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1. (WO2017057320) HIGH-PURITY CARBOXYLIC ACID ESTER AND METHOD FOR PRODUCING SAME
PCT Biblio. Data
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Pub. No.:
WO/2017/057320
International Application No.:
PCT/JP2016/078379
Publication Date:
06.04.2017
International Filing Date:
27.09.2016
IPC:
C07C 67/56
(2006.01),
B01J 39/04
(2017.01),
B01J 39/18
(2017.01),
B01J 41/04
(2017.01),
B01J 41/12
(2017.01),
B01J 47/02
(2017.01),
C07C 69/675
(2006.01),
C07C 69/68
(2006.01)
C
CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
67
Preparation of carboxylic acid esters
48
Separation; Purification; Stabilisation; Use of additives
56
by solid-liquid treatment; by chemisorption
B
PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
39
Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
04
Processes using organic exchangers
B
PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
39
Cation exchange; Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
08
Use of material as cation exchangers; Treatment of material for improving the cation exchange properties
16
Organic material
18
Macromolecular compounds
B
PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
41
Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
04
Processes using organic exchangers
B
PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
41
Anion exchange; Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
08
Use of material as anion exchangers; Treatment of material for improving the anion exchange properties
12
Macromolecular compounds
B
PERFORMING OPERATIONS; TRANSPORTING
01
PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
J
CHEMICAL OR PHYSICAL PROCESSES, e.g. CATALYSIS, COLLOID CHEMISTRY; THEIR RELEVANT APPARATUS
47
Ion-exchange processes in general; Apparatus therefor
02
Column or bed processes
C
CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
69
Esters of carboxylic acids; Esters of carbonic or haloformic acids
66
Esters of carboxylic acids having esterified carboxyl groups bound to acyclic carbon atoms and having any of the groups OH, O-metal, -CHO, keto, ether, acyloxy,
groups,
groups, or
in the acid moiety
67
of saturated acids
675
of saturated hydroxy-carboxylic acids
C
CHEMISTRY; METALLURGY
07
ORGANIC CHEMISTRY
C
ACYCLIC OR CARBOCYCLIC COMPOUNDS
69
Esters of carboxylic acids; Esters of carbonic or haloformic acids
66
Esters of carboxylic acids having esterified carboxyl groups bound to acyclic carbon atoms and having any of the groups OH, O-metal, -CHO, keto, ether, acyloxy,
groups,
groups, or
in the acid moiety
67
of saturated acids
675
of saturated hydroxy-carboxylic acids
68
Lactic acid esters
Applicants:
MITSUBISHI GAS CHEMICAL COMPANY, INC.
[JP/JP]; 5-2, Marunouchi 2-chome, Chiyoda-ku, Tokyo 1008324 (JP)
Inventors:
MUNEYASU Kuniaki
; (JP)
Agent:
KOBAYASHI Hiroshi
; (JP).
SUGIYAMA Tomohisa
; (JP).
SUZUKI Yasuhito
; (JP)
Priority Data:
2015-196769
02.10.2015
JP
Title
(EN)
HIGH-PURITY CARBOXYLIC ACID ESTER AND METHOD FOR PRODUCING SAME
(FR)
ESTER D'ACIDE CARBOXYLIQUE DE GRANDE PURETÉ ET SON PROCÉDÉ DE PRODUCTION
(JA)
高純度カルボン酸エステルおよびその製造方法
Abstract:
(EN)
The present invention makes it possible to provide a high-purity carboxylic acid ester in which the Ag, Al, Au, Ca, Cr, Cu, Fe, K, Mg, Na, Sn, and Zn contents as metal impurity contents are each less than 1 ppb and the anionic impurity content is less than 1 ppm. The present invention also makes it possible to provide a method for producing a high-purity carboxylic acid ester, the method including a step for bringing a crude carboxylic acid ester that contains anionic impurities and Ag, Al, Au, Ca, Cr, Cu, Fe, K, Mg, Na, Sn, and Zn as metal impurities into contact with a cation-exchange resin (II), followed by a step for bringing the high-purity carboxylic acid ester into contact with an anion-exchange resin (III).
(FR)
La présente invention permet de fournir un ester d'acide carboxylique de grande pureté, les impuretés métalliques de chacun des métaux Ag, Al, Au, Ca, Cr, Cu, Fe, K, Mg, Na, Sn et Zn étant présentes en une quantité inférieure à 1 ppb et la teneur en impuretés anioniques étant inférieure à 1 ppm. La présente invention permet également de fournir un procédé de production d'un ester d'acide carboxylique de grande pureté, le procédé comprenant une étape consistant à mettre en contact un ester d'acide carboxylique brut qui contient des impuretés anioniques et des impuretés métalliques de Ag, Al, Au, Ca, Cr, Cu, Fe, K, Mg, Na, Sn et Zn avec une résine échangeuse de cations (II), suivie d'une étape consistant à mettre en contact l'ester d'acide carboxylique de grande pureté avec une résine échangeuse d'anions (III).
(JA)
本発明によれば、金属不純物として、Ag,Al,Au,Ca,Cr,Cu,Fe,K,Mg,Na,Sn,およびZnのそれぞれの含有率が1ppb未満であり、アニオン性不純物の含有率が1ppm未満である、高純度カルボン酸エステルを提供することができる。更に、本発明によれば、金属不純物として、Ag,Al,Au,Ca,Cr,Cu,Fe,K,Mg,Na,Sn,およびZnと、アニオン性不純物とを含む粗カルボン酸エステルを、カチオン交換樹脂(II)に接触させる工程と、次いでアニオン交換樹脂(III)に接触させる工程とを含む、高純度カルボン酸エステルの製造方法を提供することができる。
Designated States:
AE, AG, AL, AM, AO, AT, AU, AZ, BA, BB, BG, BH, BN, BR, BW, BY, BZ, CA, CH, CL, CN, CO, CR, CU, CZ, DE, DJ, DK, DM, DO, DZ, EC, EE, EG, ES, FI, GB, GD, GE, GH, GM, GT, HN, HR, HU, ID, IL, IN, IR, IS, JP, KE, KG, KN, KP, KR, KW, KZ, LA, LC, LK, LR, LS, LU, LY, MA, MD, ME, MG, MK, MN, MW, MX, MY, MZ, NA, NG, NI, NO, NZ, OM, PA, PE, PG, PH, PL, PT, QA, RO, RS, RU, RW, SA, SC, SD, SE, SG, SK, SL, SM, ST, SV, SY, TH, TJ, TM, TN, TR, TT, TZ, UA, UG, US, UZ, VC, VN, ZA, ZM, ZW.
African Regional Intellectual Property Organization (BW, GH, GM, KE, LR, LS, MW, MZ, NA, RW, SD, SL, ST, SZ, TZ, UG, ZM, ZW)
Eurasian Patent Organization (AM, AZ, BY, KG, KZ, RU, TJ, TM)
European Patent Office (AL, AT, BE, BG, CH, CY, CZ, DE, DK, EE, ES, FI, FR, GB, GR, HR, HU, IE, IS, IT, LT, LU, LV, MC, MK, MT, NL, NO, PL, PT, RO, RS, SE, SI, SK, SM, TR)
African Intellectual Property Organization (BF, BJ, CF, CG, CI, CM, GA, GN, GQ, GW, KM, ML, MR, NE, SN, TD, TG).
Publication Language:
Japanese (
JA
)
Filing Language:
Japanese (
JA
)