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1. (WO2017019675) HYDROXIDE-CATALYZED FORMATION OF SILICON-OXYGEN BONDS BY DEHYDROGENATIVE COUPLING OF HYDROSILANES AND ALCOHOLS

Pub. No.:    WO/2017/019675    International Application No.:    PCT/US2016/044024
Publication Date: Fri Feb 03 00:59:59 CET 2017 International Filing Date: Wed Jul 27 01:59:59 CEST 2016
IPC: C08J 7/12
C08K 5/5415
C08K 5/5419
C08K 5/549
C08K 3/22
Applicants: CALIFORNIA INSTITUTE OF TECHNOLOGY
Inventors: TOUTOV, Anton
BETZ, Kerry
ROMINE, Andrew, M.
GRUBBS, Robert, H.
Title: HYDROXIDE-CATALYZED FORMATION OF SILICON-OXYGEN BONDS BY DEHYDROGENATIVE COUPLING OF HYDROSILANES AND ALCOHOLS
Abstract:
The present disclosure is directed to methods for dehydrogenatively coupled hydrosilanes and alcohols, the methods comprising contacting an organic substrate having at least one organic alcohol moiety with a mixture of at least one hydrosilane and sodium and/or potassium hydroxide, the contacting resulting in the formation of a dehydrogenatively coupled silyl ether. The disclosure further described associated compositions and methods of using the formed products.