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1. WO2016179131 - REACTIVE POLYURETHANE PLASTICIZERS AND ADHESIVES MADE THEREFROM

Publication Number WO/2016/179131
Publication Date 10.11.2016
International Application No. PCT/US2016/030494
International Filing Date 03.05.2016
IPC
C08G 18/48 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
40High-molecular-weight compounds
48Polyethers
C08G 18/76 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
70characterised by the isocyanates or isothiocyanates used
72Polyisocyanates or polyisothiocyanates
74cyclic
76aromatic
C08G 18/12 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
12using two or more compounds having active hydrogen in the first polymerisation step
C08G 18/16 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
16Catalysts
C08G 18/20 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
16Catalysts
18containing secondary or tertiary amines or salts thereof
20Heterocyclic amines; Salts thereof
C08G 18/22 2006.01
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
16Catalysts
22containing metal compounds
CPC
C08G 18/12
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
10Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
12using two or more compounds having active hydrogen in the first polymerisation step
C08G 18/168
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
16Catalysts
166Catalysts not provided for in the groups C08G18/18 - C08G18/26
168Organic compounds
C08G 18/2081
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
16Catalysts
18containing secondary or tertiary amines or salts thereof
20Heterocyclic amines; Salts thereof
2081containing at least two non-condensed heterocyclic rings
C08G 18/227
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
16Catalysts
22containing metal compounds
227of antimony, bismuth or arsenic
C08G 18/244
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
08Processes
16Catalysts
22containing metal compounds
24of tin
244tin salts of carboxylic acids
C08G 18/283
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
GMACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
18Polymeric products of isocyanates or isothiocyanates
06with compounds having active hydrogen
28characterised by the compounds used containing active hydrogen
2805Compounds having only one group containing active hydrogen
2815Monohydroxy compounds
283Compounds containing ether groups, e.g. oxyalkylated monohydroxy compounds
Applicants
  • DOW GLOBAL TECHNOLOGIES LLC [US]/[US]
Inventors
  • SOPHIEA, Daniel P.
  • YOUNG, Caitlin E.
  • ZHOU, Lirong
Agents
  • XU, Hong J.
Priority Data
62/157,05505.05.2015US
Publication Language English (EN)
Filing Language English (EN)
Designated States
Title
(EN) REACTIVE POLYURETHANE PLASTICIZERS AND ADHESIVES MADE THEREFROM
(FR) PLASTIFIANTS À BASE DE POLYURÉTHANNE RÉACTIF ET ADHÉSIFS FABRIQUÉS À PARTIR DE CEUX-CI
Abstract
(EN)
A reactive plasticizer is comprised of a reaction product of an isocyanate having two isocyanate groups and a linear polyether monol. The monol has a weight average molecular weight of about 500 to about 2000 grams/mole. The amount of isocyanate and linear polyether monol are such that the isocyanate groups are in molar excess of the amount of alcohol groups and the reaction product has an isocyanate content of 0.1% to 1% by weight of the reaction product. The reactive plasticizer is particularly useful for formulating one part moisture cured polyurethane adhesives comprised of the reactive filler, an isocyanate terminated prepolymer, filler and a catalyst.
(FR)
La présente invention concerne un plastifiant réactif constitué d'un produit réactionnel d'un isocyanate ayant deux groupes isocyanate et un monol de polyéther linéaire. Ce monol a une masse moléculaire moyenne en poids d'environ 500 à environ 2000 grammes/mole. La quantité d'isocyanate et de monol de polyéther linéaire est telle que les groupes isocyanate sont en excès molaire par rapport à la quantité de groupes alcool et le produit réactionnel a une teneur en isocyanate de 0,1 % à 1 % en poids du produit réactionnel. Le plastifiant réactif est particulièrement utile pour formuler des adhésifs de polyuréthane durcissant à l'humidité à un composant constitués de la charge réactive, d'un prépolymère à terminaison isocyanate, d'une charge et d'un catalyseur.
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