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1. WO2016129362 - FLUORINATED COPOLYMER, AND SURFACE MODIFIER CONTAINING SAME AS ACTIVE INGREDIENT

Publication Number WO/2016/129362
Publication Date 18.08.2016
International Application No. PCT/JP2016/051904
International Filing Date 22.01.2016
IPC
C08F 220/24 2006.1
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride, ester, amide, imide, or nitrile thereof
02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10Esters
22Esters containing halogen
24containing perhaloalkyl radicals
C09K 3/18 2006.1
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
KMATERIALS FOR APPLICATIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
3Materials not provided for elsewhere
18for application to surface to minimize adherence of ice, mist or water thereto; Thawing or antifreeze materials for application to surfaces
CPC
C08F 220/24
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
220Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and only one being terminated by only one carboxyl radical or a salt, anhydride ester, amide, imide or nitrile thereof
02Monocarboxylic acids having less than ten carbon atoms; Derivatives thereof
10Esters
22Esters containing halogen
24containing perhaloalkyl radicals
C08F 230/085
CCHEMISTRY; METALLURGY
08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
FMACROMOLECULAR COMPOUNDS OBTAINED BY REACTIONS ONLY INVOLVING CARBON-TO-CARBON UNSATURATED BONDS
230Copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing phosphorus, selenium, tellurium or a metal
04containing a metal
08containing silicon
085the monomer being a polymerisable silane, e.g. (meth)acryloyloxy trialkoxy silanes or vinyl trialkoxysilanes
C09D 133/16
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
133Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by only one carboxyl radical, or of salts, anhydrides, esters, amides, imides, or nitriles thereof; Coating compositions based on derivatives of such polymers
04Homopolymers or copolymers of esters
14of esters containing halogen, nitrogen, sulfur or oxygen atoms in addition to the carboxy oxygen
16Homopolymers or copolymers of esters containing halogen atoms
C09D 143/04
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
143Coating compositions based on homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and containing boron, silicon, phosphorus, selenium, tellurium, or a metal; Coating compositions based on derivatives of such polymers
04Homopolymers or copolymers of monomers containing silicon
C09D 5/08
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
DCOATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
5Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced
08Anti-corrosive paints
C09K 3/18
CCHEMISTRY; METALLURGY
09DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
KMATERIALS FOR MISCELLANEOUS APPLICATIONS, NOT PROVIDED FOR ELSEWHERE
3Materials not provided for elsewhere
18for application to surfaces to minimize adherence of ice, mist or water thereto
Applicants
  • ユニマテック株式会社 UNIMATEC CO.,LTD. [JP]/[JP]
Inventors
  • 島田 匡 SHIMADA Kyou
  • 鈴木 琢海 SUZUKI Takumi
  • 金海 吉山 KANEUMI Yoshiyama
Agents
  • 吉田 俊夫 YOSHIDA Toshio
Priority Data
2015-02620613.02.2015JP
Publication Language Japanese (ja)
Filing Language Japanese (JA)
Designated States
Title
(EN) FLUORINATED COPOLYMER, AND SURFACE MODIFIER CONTAINING SAME AS ACTIVE INGREDIENT
(FR) COPOLYMÈRE FLUORÉ, ET AGENT DE MODIFICATION DE SURFACE LE CONTENANT EN TANT QUE PRINCIPE ACTIF
(JA) 含フッ素共重合体およびこれを有効成分とする表面改質剤
Abstract
(EN) A fluorinated copolymer which is a copolymer of a polyfluoroalkyl alcohol (meth)acrylate represented by general formula [I]: CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR=CH2 (wherein R: a hydrogen atom or a methyl group; n: 1 to 6; a: 1 to 4; b: 1 to 3; c: 1 to 3), benzyl (meth)acrylate or styrene, and an Si group-containing crosslinkable (meth)acrylate represented by general formula [II]: CH2=CRCOO(CH2)dSi(OR1)eR23-e (wherein R: a hydrogen atom or a methyl group; R1 and R2: independently an alkyl group having 1 to 10 carbon atoms; d: 1 to 3; e: 1 to 3). A surface modifier containing the fluorinated copolymer as an active ingredient can exhibit an excellent dynamic sliding angle and excellent anti-corrosive properties after washing with hexadecane.
(FR) L'invention concerne un copolymère fluoré qui est un copolymère d'un (méth)acrylate d'alcool polyfluoroalkylique représenté par la formule générale [I] : CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR=CH2 (dans laquelle R : un atome d'hydrogène ou un groupe méthyle; n : 1 à 6; a : 1 à 4; b : 1 à 3; c : 1 à 3), (méth)acrylate de benzyle ou styrène, et un (méth)acrylate réticulable contenant un groupe Si représenté par la formule générale [II] : CH2=CRCOO(CH2)dSi(OR1)eR2 3-e (dans laquelle R : un atome d'hydrogène ou un groupe méthyle; R1 et R2 : indépendamment un groupe alkyle ayant 1 à 10 atomes de carbone; d : 1 à 3; e : 1 à 3). Un modificateur de surface contenant le copolymère fluoré en tant que principe actif peut présenter un excellent angle de glissement dynamique et d'excellentes propriétés anti-corrosion après lavage avec de l'hexadécane.
(JA)  一般式 CnF2n+1(CH2CF2)a(CF2CF2)b(CH2CH2)cOCOCR=CH2〔I〕(R:水素原子、メチル基、n:1~6、a:1~4、b:1~3、c:1~3)で表わされるポリフルオロアルキルアルコール(メタ)アクリルレート、ベンジル(メタ)アクリレートまたはスチレンおよび一般式 CH2=CRCOO(CH2)dSi(OR1)eR23-e〔II〕(R:水素原子、メチル基、R1、R2:炭素数1~10のアルキル基、d:1~3、e:1~3)で表わされるSi基含有架橋性(メタ)アクリレートの共重合体である含フッ素共重合体。この含フッ素共重合体を有効成分とする表面改質剤は、ヘキサデカン洗浄後における動的滑落角および防錆性にすぐれる。
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